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Kinetic, Thermodynamic and Adsorption Isotherms Studies on Removal of Copper(II) Ions from Aqueous Solutions Using Jumbo Grass (Sorghum Bicolur Sorghum Sudanefe)
Corresponding Author(s) : A. Shajahan
Asian Journal of Chemistry,
Vol. 27 No. 9 (2015): Vol 27 Issue 9
Abstract
The removal of copper(II) ions from aqueous solutions using Jumbo grass (Sorghum Bicolour Sorghum Sudanefe) was studied and to investigate the utilization of this adsorbent. The newly prepared bio sorbent was characterized by FT-IR and scanning electron microscopy. The removal efficiency of copper(II) was carried out by batch mode methods. The adsorption capacity of the bio sorbent was influenced by changing the parameters such as bio sorbent dose, pH, contact time and initial ion concentrations. The maximum removal of copper(II) was 52 % at pH 7 and equilibrium reached at 180 min. From the experimental data the Langmuir, Freundlich and Temkin adsorption isotherm models were arrived and the pseudo first order, pseudo second order, Elovich and intra-particle diffusion kinetic models were also investigated. The monolayer maximum adsorption capacity (Qm) of the biosorbent achived was 10.53 mg/g. Equilibrium data were well fitted to the Langmuir isotherm model and the pseudo second order kinetic model. Desorption of metal ions were also monitored by hydrochloric acid.
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- J.O.M. Bockris, Environmental Chemistry, Plenum Press, New York, pp. 465-466 (1978).
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- V.K. Gupta and I. Ali, Sep. Purif. Technol, 18, 131 (2000); doi:10.1016/S1383-5866(99)00058-1.
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- A.N. Hasanah, F. Rizkiana and D. Rahayu, Res. J. Pharm. Biol. Chem. Sci., 3, 1171 (2012).
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References
C. Clark, Marina Pollution, Oxford University Press, New York, p. 220 (1989).
J.O.M. Bockris, Environmental Chemistry, Plenum Press, New York, pp. 465-466 (1978).
M.H. Kalavathy, T. Karthikeyan, S. Rajgopal and L.R. Miranda, J. Colloid Interf. Sci., 292, 354 (2005); doi:10.1016/j.jcis.2005.05.087.
P.D. Johnson, M.A. Watson, J. Brown and I.A. Jefcoat, Waste Manage., 22, 471 (2002); doi:10.1016/S0956-053X(01)00036-8.
A.A. Ahmed, B.H. Hameed and N. Aziz, J. Hazard. Mater., 141, 70 (2007); doi:10.1016/j.jhazmat.2006.06.094.
I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); doi:10.1021/ja02242a004.
N. Freundlich, Z. Phys. Chem., 57, 384 (1906).
M. Temkin and V. Pyzhev, Acta Phys. Chim. URSS, 12, 327 (1940).
W.S. Wan Ngah, A. Kamari and Y.J. Koay, Int. J. Biol. Macromol., 34, 155 (2004); doi:10.1016/j.ijbiomac.2004.03.001.
N.A. Oladoja, C.O. Aboluwoye and Y.B. Oladimeji, J. Eng. Environ. Sci., 32, 303 (2008).
M. Valix, W.H. Cheung and G. Mckay, Chemosphere, 56, 493 (2004); doi:10.1016/j.chemosphere.2004.04.004.
B. Pendyal, M.M. Johns, W.E. Marshell, M. Ahmedna and R.M. Rao, Bioresour. Technol., 68, 247 (1999); doi:10.1016/S0960-8524(98)00153-9.
N.A. Tauqir, M. Sarwar, M.A. Jabbar and S. Mahmood, Pak. Vet. J., 29, 5 (2009).
O.A. Wahab, Egypt. J. Aquat. Res., 33, 125 (2007).
Y.S. Ho and G. Mckay, Water Air Soil Pollut., 158, 77 (2004); doi:10.1023/B:WATE.0000044830.63767.a3.
S. Nethaji, A. Sivasamy, G. Thennarasu and S. Saravanan, J. Hazard. Mater., 181, 271 (2010); doi:10.1016/j.jhazmat.2010.05.008.
M.M. Al, Rev. Int. Contam. Ambident, 17, 91 (2001).
Z.A. Husoon, M.N.A. Al-Azzawi and S.A.K. Al, Nahrain Univ. Sci., 16, 173 (2013).
R.B. Garcia-Reyes and J.R. Rangel-Mendez, Bioresour. Technol., 101, 8099 (2010); doi:10.1016/j.biortech.2010.06.020.
R.C. Vaishya and S.C. Prasad, Indian J. Environ. Prot., 11, 284 (1991).
K.S. Low, C.K. Lee and K.P. Lee, Bioresour. Technol., 44, 109 (1993); doi:10.1016/0960-8524(93)90183-C.
V.K. Gupta and I. Ali, Sep. Purif. Technol, 18, 131 (2000); doi:10.1016/S1383-5866(99)00058-1.
M.H. Kalavathy, T. Karthikeyan, S. Rajgopal and L.R. Miranda, J. Colloid Interf. Sci., 292, 354 (2005); doi:10.1016/j.jcis.2005.05.087.
S.J. Allen, P. Brown, G. Mckay and O. Flynn, J. Chem. Technol. Biotechnol., 54, 271 (1992); doi:10.1002/jctb.280540310.
M.-W. Wan, C.-C. Kan, C.- H. Lin, D. Buenda and C.- H. Wu, China Annual Bull., 33, 96 (2007).
N. Basci, E. Kocadagistan and B. Kocadagistan, Desalination, 164, 135 (2004); doi:10.1016/S0011-9164(04)00172-9.
Y.-S. Ho, Water Res., 37, 2323 (2003); doi:10.1016/S0043-1354(03)00002-2.
A.N. Hasanah, F. Rizkiana and D. Rahayu, Res. J. Pharm. Biol. Chem. Sci., 3, 1171 (2012).
M. Temkin and V. Pyzhev, Acta Phys. Chim. URSS, 12, 327 (1940).
M. Sekar, V. Sakthi and S. Rengaraj, J. Colloid Interf. Sci., 279, 307 (2004); doi:10.1016/j.jcis.2004.06.042.
S.Y. Lagergren, Handlingar, 24, 1 (1898).
Y.S. Ho and G. Mckay, Process Saf. Environ. Protect., 76, 183 (1998); doi:10.1205/095758298529326.
R.S. Vieira and M.M. Beppu, Colloids Surf. A, 279, 196 (2006); doi:10.1016/j.colsurfa.2006.01.026.
M.J.D. Low, Chem. Rev., 60, 267 (1960); doi:10.1021/cr60205a003.
W.J. Weber and J.C. Morris, J. Sanit. Eng. Div., 89, 31 (1963).
M. Mahramanlioglu and O. Ozgen, Asian J. Chem., 21, 635 (2009).
K. Faizadeh, M.E. Yazdanshenas, M. Montazer, A. Rashidi and R.M.A. Malek, Asian J. Chem., 21, 403 (2009).
A.A. Hussain, S.R. Mohammed, M. Nallu and S. Arivoli, Int. J. Chem. Sci. Appl., 3, 207 (2012).