Synthesis and Characterization of Dicobalt-Iron Complex (&mu;3-S)FeCo2(CO)8(Ph2PMe)

Wei Gao

doi:10.14233/ajchem.2015.18388

Issue

Vol. 27 No. 9 (2015): Vol 27 Issue 9

Issue Published : May 26, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Dicobalt-Iron Complex (μ3-S)FeCo2(CO)8(Ph2PMe)

https://doi.org/10.14233/ajchem.2015.18388

Wei Gao

School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450046, P.R. China

Corresponding Author(s) : Wei Gao

weigao415@aliyun.com

Asian Journal of Chemistry, Vol. 27 No. 9 (2015): Vol 27 Issue 9
Article Published : May 26, 2015

Abstract

Treatment of the dicobalt-iron complex (μ₃-S)FeCo₂(CO)₉ (1) with a monophosphine ligand Ph₂PMe in CH₂Cl₂ produced the dicobalt-iron complex (μ₃-S)FeCo₂(CO)₈(Ph₂PMe) (2) in 41 % yield. The new complex 2 was structurally characterized by IR, ¹H NMR, ³¹P{¹H} NMR and ¹³C{¹H} NMR spectroscopy.

Keywords

Dicobalt-iron complex Monophosphine Synthesis Carbonyl substitution

Gao, W. (2015). Synthesis and Characterization of Dicobalt-Iron Complex (μ3-S)FeCo2(CO)8(Ph2PMe). Asian Journal of Chemistry, 27(9), 3517–3518. https://doi.org/10.14233/ajchem.2015.18388

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References

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(a) N. Wang, M. Wang, L. Chen and L.C. Sun, Dalton Trans., 42, 12059 (2013); doi:10.1039/c3dt51371h; (b) X.F. Liu, J. Organomet. Chem., 750, 117 (2014); doi:10.1016/j.jorganchem.2013.11.020; (c) W. Gao, J. Yuan and J. Yang, Asian J. Chem., 25, 9755 (2013); doi:10.14233/ajchem.2013.15310A.

(a) E.S. Donovan, G.S. Nichol and G.A.N. Felton, J. Organomet. Chem., 726, 9 (2013); doi:10.1016/j.jorganchem.2012.12.006; (b) C.G. Li, Y.F. Li, J.Y. Shang and T.J. Lou, Transition Met. Chem., 39, 373 (2014); doi:10.1007/s11243-014-9810-4; (c) X.F. Liu, X.Y. Yu and H.Q. Gao, Mol. Cryst. Liq. Cryst., 592, 229 (2014); doi:10.1080/15421406.2013.858024; (d) P.H. Zhao, M. Zhang and G.Z. Zhao, Asian J. Chem., 25, 5068 (2013); doi:10.14233/ajchem.2013.14513.

(a) C.A. Mebi, D.S. Karr and B.C. Noll, Polyhedron, 50, 164 (2013); doi:10.1016/j.poly.2012.11.001; (b) Y.L. Li, B. Xie, L.K. Zou, X. Lin, Y. Yang, S.S. Zhu and T. Wang, Polyhedron, 67, 490 (2014); doi:10.1016/j.poly.2013.09.041.

(a) P.H. Zhao, X.H. Li, Y.F. Liu and Y.Q. Liu, J. Coord. Chem., 67, 766 (2014); doi:10.1080/00958972.2014.903329; (b) W. Gao, J.Y. Zhang and J. Yang, Asian J. Chem., 26, 2089 (2014); doi:10.14233/ajchem.2014.16183B.

(a) H.G. Cui, N.N. Wu, J.Y. Wang, M.Q. Hu, H.M. Wen and C.N. Chen, J. Organomet. Chem., 767, 46 (2014); doi:10.1016/j.jorganchem.2014.04.026; (b) X.F. Liu, Polyhedron, 72, 66 (2014); doi:10.1016/j.poly.2014.01.034; (c) W. Gao, L.Q. Tian and J. Yang, Asian J. Chem., 26, 2086 (2014); doi:10.14233/ajchem.2014.16183A.

(a) C.G. Li, Y. Zhu, X.X. Jiao and X.Q. Fu, Polyhedron, 67, 416 (2014); doi:10.1016/j.poly.2013.09.027; (b) X.F. Liu, Z.Q. Jiang and Z.J. Jia, Polyhedron, 33, 166 (2012); doi:10.1016/j.poly.2011.11.032; (c) X.F. Liu and H.Q. Gao, J. Cluster Sci., 25, 367 (2014); doi:10.1007/s10876-013-0615-y.

S.A. Khattab, L. Markó, G. Bor and B. Markó, J. Organomet. Chem., 1, 373 (1964); doi:10.1016/S0022-328X(00)80028-5.

(a) X.F. Liu and H.Q. Gao, Polyhedron, 65, 1 (2013); doi:10.1016/j.poly.2013.08.023; (b) X.F. Liu, M.Y. Chen and H.Q. Gao, J. Coord. Chem., 67, 57 (2014); doi:10.1080/00958972.2013.879123.

M. Cowie, R.L. Dekock, T.R. Wagenmaker, D. Seyferth, R.S. Henderson and M.K. Gallagher, Organometallics, 8, 119 (1989); doi:10.1021/om00103a015.