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Synthesis, Characterization with Photophysical and Ion Binding Properties of Ruthenium Complex
Corresponding Author(s) : Jian-Fei Kong
Asian Journal of Chemistry,
Vol. 27 No. 8 (2015): Vol 27 Issue 8
Abstract
Host-guest chemistry has attracted much attention in the past several decades and the design of highly selective and sensitive receptors for metal ions is of great importance in the area of ion transport, chemosensing, biomedical as well as environmental applications. Herein we report the synthesis, photophysics and ion-binding studies of new ruthenium(II) 2,2'-bipyridine complex containing crown pendants. The binding constants of the complex for different metal ions were determined by UV-visible absorption.
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- C.J. Pedersen, J. Am. Chem. Soc., 89, 7017 (1967); doi:10.1021/ja01002a035.
- (a) J.D. Lamb, R.M. Izatt, J.J. Christensen and D.J. Eatough, in ed. G.A. Melson, Coordination Chemistry of Macrocyclic Compounds, Plenum Press, New York, p. 145 (1979); (b) J.D. Lamb, R.M. Izatt, C.S. Swain and J.J. Christensen, J. Am. Chem. Soc., 102, 475 (1980); doi:10.1021/ja00522a005.
- (a) C.J. Pedersen, Angew. Chem. Int. Ed. Engl., 27, 1021 (1988); doi:10.1002/anie.198810211; (b) J. Simon, M.K. Engel and C. Soulie, New J. Chem., 16, 287 (1992).
- N. Kobayashi and Y. Nishiyama, J. Chem. Soc. Chem. Commun., 1462 (1986); doi:10.1039/c39860001462.
- P.D. Beer, O. Kocian, R.J. Mortimer and C. Ridgway, J. Chem. Soc., Dalton Trans., 2629 (1993); doi:10.1039/dt9930002629.
- T. Lazarides, T.A. Miller, J.C. Jeffery, T.K. Ronson, H. Adams and M.D. Ward, J. Chem. Soc., Dalton Trans., 528 (2005); doi:10.1039/b416293e.
- K. Hanaoka, K. Kikuchi, H. Kojima, Y. Urano and T. Nagano, J. Am. Chem. Soc., 126, 12470 (2004); doi:10.1021/ja0469333.
- B.P. Sullivan, D.J. Salmon and T.J. Meyer, Inorg. Chem., 17, 3334 (1978); doi:10.1021/ic50190a006.
- J. Bourson, J. Pouget and B. Valeur, J. Phys. Chem., 97, 4552 (1993); doi:10.1021/j100119a050.
- G. Topal, N. Demirel, M. Togrul, Y. Turgut and H. Hosgoren, J. Heterocycl. Chem., 38, 281 (2001); doi:10.1002/jhet.5570380142.
- A. Juris, V. Balzani, F. Barigelletti, S. Campagna, P. Belser and A. Von Zelewsky, Coord. Chem. Rev., 84, 85 (1988); doi:10.1016/0010-8545(88)80032-8.
- E.A. Seddon and K.R. Seddon, The Chemistry of Ruthenium, Elsevier, Amsterdam (1984).
- R.A. Krause, Struct. Bonding, 67, 1 (1987); doi:10.1007/3-540-17881-3_1.
- J.V. Caspar and T.J. Meyer, J. Am. Chem. Soc., 105, 5583 (1983); doi:10.1021/ja00355a009.
- Y.L. Pui, Ph.D. Thesis, Syntheses, Luminescence Studies and Host-Guest Chemistry of d10 and d6 Metal Complexes Containing Diimine and/or Chalcogenolate Ligands, The University of Hong Kong (2000).
References
C.J. Pedersen, J. Am. Chem. Soc., 89, 7017 (1967); doi:10.1021/ja01002a035.
(a) J.D. Lamb, R.M. Izatt, J.J. Christensen and D.J. Eatough, in ed. G.A. Melson, Coordination Chemistry of Macrocyclic Compounds, Plenum Press, New York, p. 145 (1979); (b) J.D. Lamb, R.M. Izatt, C.S. Swain and J.J. Christensen, J. Am. Chem. Soc., 102, 475 (1980); doi:10.1021/ja00522a005.
(a) C.J. Pedersen, Angew. Chem. Int. Ed. Engl., 27, 1021 (1988); doi:10.1002/anie.198810211; (b) J. Simon, M.K. Engel and C. Soulie, New J. Chem., 16, 287 (1992).
N. Kobayashi and Y. Nishiyama, J. Chem. Soc. Chem. Commun., 1462 (1986); doi:10.1039/c39860001462.
P.D. Beer, O. Kocian, R.J. Mortimer and C. Ridgway, J. Chem. Soc., Dalton Trans., 2629 (1993); doi:10.1039/dt9930002629.
T. Lazarides, T.A. Miller, J.C. Jeffery, T.K. Ronson, H. Adams and M.D. Ward, J. Chem. Soc., Dalton Trans., 528 (2005); doi:10.1039/b416293e.
K. Hanaoka, K. Kikuchi, H. Kojima, Y. Urano and T. Nagano, J. Am. Chem. Soc., 126, 12470 (2004); doi:10.1021/ja0469333.
B.P. Sullivan, D.J. Salmon and T.J. Meyer, Inorg. Chem., 17, 3334 (1978); doi:10.1021/ic50190a006.
J. Bourson, J. Pouget and B. Valeur, J. Phys. Chem., 97, 4552 (1993); doi:10.1021/j100119a050.
G. Topal, N. Demirel, M. Togrul, Y. Turgut and H. Hosgoren, J. Heterocycl. Chem., 38, 281 (2001); doi:10.1002/jhet.5570380142.
A. Juris, V. Balzani, F. Barigelletti, S. Campagna, P. Belser and A. Von Zelewsky, Coord. Chem. Rev., 84, 85 (1988); doi:10.1016/0010-8545(88)80032-8.
E.A. Seddon and K.R. Seddon, The Chemistry of Ruthenium, Elsevier, Amsterdam (1984).
R.A. Krause, Struct. Bonding, 67, 1 (1987); doi:10.1007/3-540-17881-3_1.
J.V. Caspar and T.J. Meyer, J. Am. Chem. Soc., 105, 5583 (1983); doi:10.1021/ja00355a009.
Y.L. Pui, Ph.D. Thesis, Syntheses, Luminescence Studies and Host-Guest Chemistry of d10 and d6 Metal Complexes Containing Diimine and/or Chalcogenolate Ligands, The University of Hong Kong (2000).