Determination of Spirotetramat in Complex Matrices Combining QuEChERs and Solid Phase Extraction Followed by High Performance Liquid Chromatography

Junxue Wu; Chengju Wang; Kai Wang; Baitao Wang; Yun Zhang; Hongyan Zhang

doi:10.14233/ajchem.2015.18036

Issue

Vol. 27 No. 8 (2015): Vol 27 Issue 8

Issue Published : April 27, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Determination of Spirotetramat in Complex Matrices Combining QuEChERs and Solid Phase Extraction Followed by High Performance Liquid Chromatography

https://doi.org/10.14233/ajchem.2015.18036

Junxue Wu

Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, P.R. China

Chengju Wang

Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, P.R. China

Kai Wang

Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, P.R. China

Baitao Wang

Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, P.R. China

Yun Zhang

Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, P.R. China

Hongyan Zhang

Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, P.R. China

Corresponding Author(s) : Hongyan Zhang

hongyan@cau.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 8 (2015): Vol 27 Issue 8
Article Published : April 27, 2015

Abstract

A new sample preparation procedure combining QuEChERs and solid phase extraction was optimized for the determination at trace levels of spirotetramat in complex matrices by high performance liquid chromatography with ultraviolet detector (HPLC-UVD). Seven foods (tea, agaric, celery, leek, citrus, soybean and walnuts) were selected as complex matrices for validating this new method. The target analyte was extracted with acetonitrile and cleaned up by Cleanert TPH and the recoveries of spirotetramat in seven foods were in range of 76.9 to 106.7 % with relative standard deviation of 1.1 to 10.8 % at three spiking levels. The limit of quantification of spirotetramat in tea, agaric, celery, leek, citrus, soybean and walnuts were 0.1, 0.1, 0.2, 0.2, 0.1, 0.1 and 0.05 mg/kg, respectively. The proposed method was applied to determine the residue of spirotetramat in seven samples from regional retailers in Beijing and no spirotetramat was detected.

Keywords

Spirotetramat QuEChERS Solid phase extraction Complex matrix High performance liquid chromatography

Wu, J., Wang, C., Wang, K., Wang, B., Zhang, Y., & Zhang, H. (2015). Determination of Spirotetramat in Complex Matrices Combining QuEChERs and Solid Phase Extraction Followed by High Performance Liquid Chromatography. Asian Journal of Chemistry, 27(8), 2779–2782. https://doi.org/10.14233/ajchem.2015.18036

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L. Cherta, J. Beltran, F. Lopez and F. Hernandez, Food Anal. Methods, 6, 1170 (2013); doi:10.1007/s12161-012-9524-1.

M.M. Radisic, T.M. Vasiljevic, N.N. Dujakovic and M.D. Lausevic, Food Anal. Methods, 6, 648 (2013); doi:10.1007/s12161-012-9448-9.

M. Anastassiades, S.J. Lehotay, D. Stajnbaher and F.J. Schenck, J. AOAC Int., 86, 412 (2003).

S.J. Lehotay, K.A. Son, H. Kwon, U. Koesukwiwat, W.S. Fu, K. Mastovska, E. Hoh and N. Leepipatpiboon, J. Chromatogr. A, 1217, 2548 (2010); doi:10.1016/j.chroma.2010.01.044.

P.Y. Zhao, L. Wang, L. Zhou, F.Z. Zhang, S. Kang and C.P. Pan, J. Chromatogr. A, 1225, 17 (2012); doi:10.1016/j.chroma.2011.12.070.

D.G. Hayward, J.W. Wong, F. Shi, K. Zhang, N.S. Lee, A.L. DiBenedetto and M.J. Hengel, Anal. Chem., 85, 4686 (2013); doi:10.1021/ac400481w.

C.P. Zhang, H. Zhao, M. Wu, X.Q. Hu, X.M. Cai, L.F. Ping and Z. Li, J. Chromatogr. Sci., 50, 940 (2012); doi:10.1093/chromsci.

R. Fischer and H.C. Weiss, Bayer Crop Sci. J., 61, 127 (2008).

E. Bruck, A. Elbert, R. Fischer, S. Krueger, J. Kühnhold, A.M. Klueken, R. Nauen, J.-F. Niebes, U. Reckmann, H.-J. Schnorbach, R. Steffens and X. van Waetermeulen, Crop Prot., 28, 838 (2009); doi:10.1016/j.cropro.2009.06.015.

J.L. Cheng, X.R. He, Z.C. Wang, J.G. Zhang, J.H. Zhao and N.G. Zhu, Pest Manag. Sci., 69, 1121 (2013); doi:10.1002/ps.3473.

C. McKenna, R. Gaskin, D. Horgan, S. Dobson and Y. Jia, New Zeal J. Crop Hort., 41, 105 (2013); doi:10.1080/01140671.2013.784710.

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S. Mohapatra, M. Deepa and G.K. Jagadish, Bull. Environ. Contam. Toxicol., 88, 124 (2012); doi:10.1007/s00128-011-0494-6.

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Q.M. Lu, L.H. Chen, M.H. Lu, G.N. Chen and L. Zhang, J. Agric. Food Chem., 58, 2763 (2010); doi:10.1021/jf903274z.

Issue

Vol. 27 No. 8 (2015): Vol 27 Issue 8

Determination of Spirotetramat in Complex Matrices Combining QuEChERs and Solid Phase Extraction Followed by High Performance Liquid Chromatography

Corresponding Author(s) : Hongyan Zhang

Abstract

Keywords

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