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Vol. 27 No. 8 (2015): Vol 27 Issue 8

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Isomerization of Glucose into Fructose and Mannose in Presence of Anion-Exchanged Resins

https://doi.org/10.14233/ajchem.2015.18035
Lingjuan Lv
School of Chemical Engineering and Technology, Tianjin University, Tianjin, P.R. China; Key Laboratory of System Bioengineering, Ministry of Education, Tianjin University, Tianjin, P.R. China
Xianghai Guo
School of Chemical Engineering and Technology, Tianjin University, Tianjin, P.R. China; Key Laboratory of System Bioengineering, Ministry of Education, Tianjin University, Tianjin, P.R. China
Peng Bai
School of Chemical Engineering and Technology, Tianjin University, Tianjin, P.R. China; Key Laboratory of System Bioengineering, Ministry of Education, Tianjin University, Tianjin, P.R. China
Shuo Zhao
School of Chemical Engineering and Technology, Tianjin University, Tianjin, P.R. China; Key Laboratory of System Bioengineering, Ministry of Education, Tianjin University, Tianjin, P.R. China

Corresponding Author(s) : Peng Bai

chemeng114_tju@163.com

Asian Journal of Chemistry, Vol. 27 No. 8 (2015): Vol 27 Issue 8

Abstract

Much attention has been paid to the conversion of bio-regenerable glucose into valuable chemicals and liquid fuels, like fructose, 5-hydroxymethyl furfural (5-HMF), mannose and levulinic acid. The isomerization of glucose into fructose and mannose simultaneously was studied in the presence of commercial anion-exchanged resins. An OA16 (45) orthogonal experiment was designed investigating the following four variables i.e., resin types (factor A), reaction temperature (factor B), pH value (factor C) and D-glucose to resin ratio (factor D). Reaction temperature was identified as a prominent factor of this transformation. Ideal conversions and selectivities were obtained even in the case of high glucose concentration. In contrast to other catalysts reported like Tin-beta, anion-exchanged resins highlight by reasonable catalytic activity and selectivity under mild conditions, easy regeneration and separation and low cost. Further efforts were worthwhile in this area.

Keywords

Glucose Isomerization Anion-exchanged resins
Lv, L., Guo, X., Bai, P., & Zhao, S. (2015). Isomerization of Glucose into Fructose and Mannose in Presence of Anion-Exchanged Resins. Asian Journal of Chemistry, 27(8), 2774–2778. https://doi.org/10.14233/ajchem.2015.18035
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