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Microwave Solid Phase Synthesis and Crystal Structure of Copper(II) Complex with 2-Hydroxy-benzoic acid(amino-pyridin-2-yl-methylene)hydrazide
Corresponding Author(s) : Suo-Ping Xu
Asian Journal of Chemistry,
Vol. 27 No. 8 (2015): Vol 27 Issue 8
Abstract
One mononuclear copper(II) complex [CuLCl]·2H2O has been synthesized by 2-hydroxy-benzoic acid(amino-pyridin-2-yl-methylene)-hydrazide (L) with CuCl2·2H2O in microwave radiation assistance. It crystallizes in the monoclinic system, space group C2/c, with the cell parameters a = 14.8571(13) Å, b = 12.4560(11) Å, c = 16.5409(16) Å, a = g = 90.00°, b = 95.5770(10)°, V = 3046.6(5) Å3 and Z = 8. The Cu atom is surrounded by one O atom and two N atoms from 2-hydroxy-benzoic acid(amino-pyridin-2-yl-methylene)-hydrazide molecule and one Cl from CuCl2 to form a quadrilateral coordination environment.
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- A. Roth, E.T. Spielberg and W. Plass, Inorg. Chem., 46, 4362 (2007); doi:10.1021/ic070088i.
- S.-P. Xu, L. Shi, Y. Pei, Y. Yang, G. Xu and H.-L. Zhu, J. Coord. Chem., 63, 3463 (2010); doi:10.1080/00958972.2010.514338.
- M.R. Wagner and F.A. Walker, Inorg. Chem., 22, 3021 (1983); doi:10.1021/ic00163a009.
- S.-P. Xu, L. Shi, P.-C. Lv, R.-Q. Fang and H.-L. Zhu, J. Coord. Chem., 62, 2048 (2009); doi:10.1080/00958970902741251.
- R.K. Shervedani and S.A. Mozaffari, Anal. Chem., 78, 4957 (2006); doi:10.1021/ac052292y.
- K. Bernardo, S. Leppard, A. Robert, G. Commenges, F. Dahan and B. Meunier, Inorg. Chem., 35, 387 (1996); doi:10.1021/ic950700i.
- S.-P. Xu and Y. Pei, J. Chem. Crystallogr., 42, 330 (2012); doi:10.1007/s10870-011-0247-8.
- C.-H. Li, Q. Wang, Y.-Q. Xu and C.-W. Hu, Chinese J. Struct. Chem., 27, 187 (2009).
- L.L. Koh, J.O. Ranford, W.T. Robinson, J.O. Svensson, A.L.C. Tan and D.-Q. Wu, Inorg. Chem., 35, 6466 (1996); doi:10.1021/ic9606441.
- T. Akitsu and Y. Einaga, Acta Cryst., C60, m640 (2004); doi:10.1107/S0108270104026575.
- G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany (1977).
- S.-P. Xu, Y. Pei, L. Shi, G. Xu, P.-C. Lv and H.-L. Zhu, Chinese J. Struct. Chem., 30, 134 (2011).
References
A. Roth, E.T. Spielberg and W. Plass, Inorg. Chem., 46, 4362 (2007); doi:10.1021/ic070088i.
S.-P. Xu, L. Shi, Y. Pei, Y. Yang, G. Xu and H.-L. Zhu, J. Coord. Chem., 63, 3463 (2010); doi:10.1080/00958972.2010.514338.
M.R. Wagner and F.A. Walker, Inorg. Chem., 22, 3021 (1983); doi:10.1021/ic00163a009.
S.-P. Xu, L. Shi, P.-C. Lv, R.-Q. Fang and H.-L. Zhu, J. Coord. Chem., 62, 2048 (2009); doi:10.1080/00958970902741251.
R.K. Shervedani and S.A. Mozaffari, Anal. Chem., 78, 4957 (2006); doi:10.1021/ac052292y.
K. Bernardo, S. Leppard, A. Robert, G. Commenges, F. Dahan and B. Meunier, Inorg. Chem., 35, 387 (1996); doi:10.1021/ic950700i.
S.-P. Xu and Y. Pei, J. Chem. Crystallogr., 42, 330 (2012); doi:10.1007/s10870-011-0247-8.
C.-H. Li, Q. Wang, Y.-Q. Xu and C.-W. Hu, Chinese J. Struct. Chem., 27, 187 (2009).
L.L. Koh, J.O. Ranford, W.T. Robinson, J.O. Svensson, A.L.C. Tan and D.-Q. Wu, Inorg. Chem., 35, 6466 (1996); doi:10.1021/ic9606441.
T. Akitsu and Y. Einaga, Acta Cryst., C60, m640 (2004); doi:10.1107/S0108270104026575.
G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany (1977).
S.-P. Xu, Y. Pei, L. Shi, G. Xu, P.-C. Lv and H.-L. Zhu, Chinese J. Struct. Chem., 30, 134 (2011).