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Vol. 27 No. 8 (2015): Vol 27 Issue 8

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Crystal Structure and Switchable Dielectric Properties of Singly Protonated Homopiperazinium Perchlorate

https://doi.org/10.14233/ajchem.2015.18276
Yan Sui
College of Chemistry and Chemical Engineering, The Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Rong-Hua Hu
College of Chemistry and Chemical Engineering, The Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Zhi-Gang Luo
College of Chemistry and Chemical Engineering, The Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Ji-wu Wen
College of Chemistry and Chemical Engineering, The Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Long-Jin Zhong
College of Chemistry and Chemical Engineering, The Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China

Corresponding Author(s) : Yan Sui

ysui@163.com

Asian Journal of Chemistry, Vol. 27 No. 8 (2015): Vol 27 Issue 8

Abstract

Singly protonated homopiperazinium perchlorate (1) has been synthesized and characterized by single-crystal X-ray diffraction, IR, elemental analysis, DSC and temperature-dependent dielectric analysis. Compound 1 crystallizes in orthorhombic space group Pbca, their homopiperazinium cations are arranged in almost identical orientation by the parallel and nearly ideal linear N-H···N hydrogen bond chains. Very large dielectric change between high and low dielectric states is found at about 400 K due to reversible first-order phase transition. It is the first time that singly protonated homopiperazinium perchlorate is found to be a switchable dielectric material with high phase transition temperature and large dielectric change between high and low dielectric states.

Keywords

Homopiperazine Organic-inorganic hybrid Crystal structure Dielectric property Molecule-based
Sui, Y., Hu, R.-H., Luo, Z.-G., Wen, J.- wu, & Zhong, L.-J. (2015). Crystal Structure and Switchable Dielectric Properties of Singly Protonated Homopiperazinium Perchlorate. Asian Journal of Chemistry, 27(8), 2876–2878. https://doi.org/10.14233/ajchem.2015.18276
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