Preparation of Novel Polystyrene-Layered Hydroxide Zinc Benzoate Nanocomposites by Bulk Polymerization

Xin Li; Honghao Yu; Houfang Zhang; Xiangxin Xue

doi:10.14233/ajchem.2015.18393

Issue

Vol. 27 No. 8 (2015): Vol 27 Issue 8

Issue Published : April 27, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Preparation of Novel Polystyrene-Layered Hydroxide Zinc Benzoate Nanocomposites by Bulk Polymerization

https://doi.org/10.14233/ajchem.2015.18393

Xin Li

School of Material Science and Engineering, Shenyang Ligong University, Shenyang 110159, P.R. China

Honghao Yu

School of Material Science and Engineering, Shenyang Ligong University, Shenyang 110159, P.R. China

Houfang Zhang

School of Material Science and Engineering, Shenyang Ligong University, Shenyang 110159, P.R. China

Xiangxin Xue

Institute of Metallurgical Resource and Environmental Engineering, Northeastern University, Shenyang 110819, P.R. China

Corresponding Author(s) : Honghao Yu

honghaoyu@hotmail.com

Asian Journal of Chemistry, Vol. 27 No. 8 (2015): Vol 27 Issue 8
Article Published : April 27, 2015

Abstract

Novel polystyrene-layered hydroxide zinc benozate nanocomposites were prepared by bulk polymerization with azobisisobutyronitrile initiator. The well dispersion of layered hydroxide zinc benzoate in matrix was observed. The presence of filler shields polystyrene from thermal oxidation and brings to a reduction of 50 % in heat release rate during combustion with 1 wt. % loading. The research sucessfully exemplified the feasibility of layered hydroxide benzoate as fillers in polymeric nanocomposites.

Keywords

Nanocomposite Layed hydroxide salts Polymerization

Li, X., Yu, H., Zhang, H., & Xue, X. (2015). Preparation of Novel Polystyrene-Layered Hydroxide Zinc Benzoate Nanocomposites by Bulk Polymerization. Asian Journal of Chemistry, 27(8), 2987–2990. https://doi.org/10.14233/ajchem.2015.18393

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References

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References

E.P. Giannelis, Adv. Mater., 8, 29 (1996); doi:10.1002/adma.19960080104.

M. Zanetti, G. Camino, D. Canavese, A.B. Morgan, F.J. Lamelas and C.A. Wilkie, Chem. Mater., 14, 189 (2002); doi:10.1021/cm011124t.

R.A. Vaia, S. Vasudevan, W. Krawiec, L.G. Scanlon and E.P. Giannelis, Adv. Mater., 7, 154 (1995); doi:10.1002/adma.19950070210.

W. Chen, L. Feng and B. Qu, Chem. Mater., 16, 368 (2004); doi:10.1021/cm0303484.

M. Albrecht, S. Ehrler and A. Mühlebach, Macromol. Rapid Commun., 24, 382 (2003); doi:10.1002/marc.200390065.

J. Zhu, A.B. Morgan, F.J. Lamelas and C.A. Wilkie, Chem. Mater., 13, 3774 (2001); doi:10.1021/cm000984r.

F.R. Costa, U. Wagenknecht, D. Jehnichen, M.A. Goad and G. Heinrich, Polymer, 47, 1649 (2006); doi:10.1016/j.polymer.2005.12.011.

S. Ogata, I. Miyazaki, Y. Tasaka, H. Tagaya, J.- Kadokawa and K. Chiba, J. Mater. Chem., 8, 2813 (1998); doi:10.1039/a804557g.

A. Kasai and S. Fujihara, Inorg. Chem., 45, 415 (2006); doi:10.1021/ic051528d.

E. Kandare, G. Chigwada, D. Wang, C.A. Wilkie and J.M. Hossenlopp, Polym. Degrad. Stabil., 91, 1781 (2006); doi:10.1016/j.polymdegradstab.2005.11.021.

S. Aisawa, E. Ishida, S. Takahashi, H. Hirahara and E. Narita, Chem. Lett., 34, 630 (2005); doi:10.1246/cl.2005.630.

E. Kandare and J.M. Hossenlopp, J. Phys. Chem. B, 109, 8469 (2005); doi:10.1021/jp0465433.

S.P. Newman and W. Jones, J. Solid State Chem., 148, 26 (1999); doi:10.1006/jssc.1999.8330.

G.G. Arizaga, K.G. Satyanarayana and F. Wypych, Solid State Ion., 178, 1143 (2007); doi:10.1016/j.ssi.2007.04.016.

J.Y. Miao, M. Xue, I. Hiroshi and Q. Feng, J. Mater. Chem., 16, 432 (2006).

S. Ogata, H. Tagaya, M. Karasu and J. Kadokawa, J. Mater. Chem., 10, 321 (2000); doi:10.1039/a905859a.

K.H. Kong, Y. Hu, H.D. Lu, Z.Y. Chen and W. Fan, J. Mater. Sci., 40, 4505 (2005); doi:10.1007/s10853-005-0855-9.

Issue

Vol. 27 No. 8 (2015): Vol 27 Issue 8

Preparation of Novel Polystyrene-Layered Hydroxide Zinc Benzoate Nanocomposites by Bulk Polymerization

Corresponding Author(s) : Honghao Yu

Abstract

Keywords

Full Article

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