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Vol. 27 No. 8 (2015): Vol 27 Issue 8

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Dehydration of Fructose into 5-Hydroxymethylfurfural Catalyzed by Phosphorylated Activated Carbon Catalyst

https://doi.org/10.14233/ajchem.2015.18344
Li Yang
Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, P.R. China
Miaofeng Wang
Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, P.R. China
Xiaopei Yan
Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, P.R. China
Yilan Wang
Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, P.R. China
Haian Xia
Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, P.R. China

Corresponding Author(s) : Haian Xia

haxia@dicp.ac.cn

Asian Journal of Chemistry, Vol. 27 No. 8 (2015): Vol 27 Issue 8

Abstract

Surface functionalized activated carbon catalysts with phosphate group were synthesized and used to catalyze dehydration of fructose into 5-hydroxymethylfurfural. The surface oxygen-containing functional groups of phosphorylated activated carbon were characterized and analyzed by XPS, infrared spectroscopy and Boehm titration techniques. The catalysts exhibit high dehydration activity of fructose but low 5-hydroxymethylfurfural selectivity using water as the solvent. Organic solvent can effectively improve the 5-hydroxymethylfurfural selectivity and yield. The highest 5-hydroxymethylfurfural yield of 66.6 % was achieved using DMSO as the solvent at 160 °C for 30 min. It was found that the amount of phosphate group is correlated with the fructose conversion, but higher concentration of phosphate group leads to the decrease of 5-hydroxymethylfurfural selectivity.

Keywords

Phosphorylated activated carbon Fructose dehydration 5-Hydroxymethylfurfural Phosphate
Yang, L., Wang, M., Yan, X., Wang, Y., & Xia, H. (2015). Dehydration of Fructose into 5-Hydroxymethylfurfural Catalyzed by Phosphorylated Activated Carbon Catalyst. Asian Journal of Chemistry, 27(8), 2979–2982. https://doi.org/10.14233/ajchem.2015.18344
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