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Vol. 27 No. 8 (2015): Vol 27 Issue 8

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Migration of Bisphenol A and Bisphenol A Diglycidyl-ether from Can Coatings into Food Simulants

https://doi.org/10.14233/ajchem.2015.18790
Qin-Bao Lin
Key Laboratory of Product Packaging and Logistics, Packaging Engineering Institute, Jinan University, P.R. China
Long-Fei Cai
College of Life Science, Shanxi University, P.R. China
Shao-Jing Wu
Shenzhen Border Inspection and Quarantine Bureau, Shenzhen, P.R. China
Zhi-Nan Chen
Shenzhen Border Inspection and Quarantine Bureau, Shenzhen, P.R. China
Zhi-Wei Wang
Key Laboratory of Product Packaging and Logistics, Packaging Engineering Institute, Jinan University, P.R. China

Corresponding Author(s) : Qin-Bao Lin

tlinqb@jnu.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 8 (2015): Vol 27 Issue 8

Abstract

The migration and alteration of the key bisphenol-A-related compounds, bisphenol A and bisphenol A diglycidyl-ether, in food simulants (deionized water, 3 % acetic acid and 50 % ethanol) stored in coated cans were investigated. Quantification and confirmation of the two compounds were performed with ultrahigh-performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS). Recoveries for bisphenol A and bisphenol A diglycidyl-ether at three concentration levels (10, 25, 250 μg L-1) ranged from 81.8 to 101.5 % and RSDs were 2.61 to 12.52 %. The effects of the initial concentration, heat processing (for sterilization), time and temperature of storage on migration and alteration of bisphenol A and bisphenol A diglycidyl-ether were investigated. The results showed that heat processing contributed greatly to bisphenol release. Besides, storage temperature and time had a significant effect on the migration of bisphenol A , with concentrations increasing gradually with time and temperature. Conversely, the concentrations of bisphenol A diglycidyl-ether decreased during storage because of hydrolysis by the food simulants, especially for aqueous acetic acid.

Keywords

Bisphenol A diglycidyl-ether Bisphenol A Can coating Epoxy resins Food simulants Migration
Lin, Q.-B., Cai, L.-F., Wu, S.-J., Chen, Z.-N., & Wang, Z.-W. (2015). Migration of Bisphenol A and Bisphenol A Diglycidyl-ether from Can Coatings into Food Simulants. Asian Journal of Chemistry, 27(8), 3013–3018. https://doi.org/10.14233/ajchem.2015.18790
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