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Transesterification of Canola Oil with Methanol using Nano Zinc Oxide Supported Catalysts
Corresponding Author(s) : Nezahat Boz
Asian Journal of Chemistry,
Vol. 27 No. 8 (2015): Vol 27 Issue 8
Abstract
Nano zinc oxide supported catalysts were prepared by an impregnation method with an aqueous solution of K2CO3 (3-10 wt. %) and tested for the transesterification of canola oil with methanol. Several operating variables were used in order to assess their influence on the methyl ester yield, namely, the weight ratio of K2CO3 over ZnO (3-10 %), the reactant feed ratio (alcohol/oil: 6/1-18/1), the reactor temperature (298, 318, 333 and 338 K), reaction time (1-9 h) and the catalyst concentration (varied between 1-7 wt. %). 10 wt. % K2CO3 impregnated on nano particles of zinc oxide were found to be the active catalysts resulting in high conversion of 97.83 ± 1.82 % for transesterification of canola oil at 338 K with methanol/oil ratio of 9/1 and using 5 wt. % catalysts.
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- J. Van Gerpen, Fuel Process. Technol., 86, 1097 (2005); doi:10.1016/j.fuproc.2004.11.005.
- A.A. Kiss, A.C. Dimian and G. Rothenberg, Adv. Synth. Catal., 348, 75 (2006); doi:10.1002/adsc.200505160.
- K.V. Thiruvengadaravi, J. Nandagopal, P. Baskaralingam, V.S. Selva Bala and S. Sivanesan, Fuel, 98, 1 (2012); doi:10.1016/j.fuel.2012.02.047.
- W. Du, Y. Xu, J. Zeng and D. Liu, Biotechnol. Appl. Biochem., 40, 187 (2004); doi:10.1042/BA20030142.
- K.R. Jegannathan, S.S. Abang, D.D. Poncelet, E.S. Chan and P. Ravindra, Crit. Rev. Biotechnol., 28, 253 (2008).
- N. Boz, N. Degirmenbasi and D.M. Kalyon, Appl. Catal. B, 89, 590 (2009); doi:10.1016/j.apcatb.2009.01.026.
- N. Boz and M. Kara, Chem. Eng. Commun., 196, 80 (2008); doi:10.1080/00986440802301438.
- N. Boz, N. Degirmenbasi and D.M. Kalyon, Appl. Catal. B, 138-139, 236 (2013); doi:10.1016/j.apcatb.2013.02.043.
- N. Degirmenbasi, N. Boz and D.M. Kalyon, Appl. Catal. B, 150-151, 147 (2014); doi:10.1016/j.apcatb.2013.12.013.
- N. Degirmenbasi and B. Ozgun, Monatsh. Chem., 134, 1565 (2003); doi:10.1007/s00706-003-0063-8.
- M. Tamura, K. Tokonami, Y. Nakagawa and K. Tomishige, Chem. Commun., 49, 7034 (2013); doi:10.1039/C3CC41526K.
- O. Ilgen, I. Dincer, M. Yildiz, E. Alptekin, N. Boz, M. Canakci and A.N. Akin, Turk. J. Chem., 31, 509 (2007).
- W. Xie and X. Huang, Catal. Lett., 107, 53 (2006); doi:10.1007/s10562-005-9731-0.
- Z. Yang and W. Xie, Fuel Process. Technol., 88, 631 (2007); doi:10.1016/j.fuproc.2007.02.006.
- H. Li and W. Xie, Catal. Lett., 107, 25 (2006); doi:10.1007/s10562-005-9727-9.
- W. Xie, Z. Yang and H. Chun, Ind. Eng. Chem. Res., 46, 7942 (2007); doi:10.1021/ie070597s.
- N. Boz and O. Sunal, J. Fac. Eng. Arch. Gazi Univ., 24, 389 (2009).
- C.R. Venkat Reddy, R. Oshel and J.G. Verkade, Energy Fuels, 20, 1310 (2006); doi:10.1021/ef050435d.
- F. Qiu, Y. Li, D. Yang, X. Li and P. Sun, Bioresour. Technol., 102, 4150 (2011); doi:10.1016/j.biortech.2010.12.071.
- Z. Kesica, I. Lukic, M. Zdujic, H. Liu and D. Skala, Procedia Eng., 42, 1169 (2012); doi:10.1016/j.proeng.2012.07.509.
- R. Madhuvilakku and S. Piraman, Bioresour. Technol., 150, 55 (2013); doi:10.1016/j.biortech.2013.09.087.
- American Oil Chemists’ Society, Official Test Method Cd 3a–63 for Acid Value, In: Official Methods and Recommended Practices of the American Oil Chemists’ Society, Champaign, IL (1998).
- European Standard of EN 14103, Fat and Oil Derivatives – Fatty Acid Methyl Esters (FAME)–Determination of Ester and Linolenic Acid Methyl Ester Contents, April (2003).
- N. Degirmenbasi, Z. Peralta-Inga, U. Olgun, H. Gocmez and D.M. Kalyon, J. Energ. Mater., 24, 103 (2006); doi:10.1080/07370650600672090.
- N. Degirmenbasi, Z. Peralta-Inga, U. Olgun, H. Gocmez and D.M. Kalyon, J. Energ. Mater., 24, 103 (2006); doi:10.1080/07370650600672090.
References
J. Van Gerpen, Fuel Process. Technol., 86, 1097 (2005); doi:10.1016/j.fuproc.2004.11.005.
A.A. Kiss, A.C. Dimian and G. Rothenberg, Adv. Synth. Catal., 348, 75 (2006); doi:10.1002/adsc.200505160.
K.V. Thiruvengadaravi, J. Nandagopal, P. Baskaralingam, V.S. Selva Bala and S. Sivanesan, Fuel, 98, 1 (2012); doi:10.1016/j.fuel.2012.02.047.
W. Du, Y. Xu, J. Zeng and D. Liu, Biotechnol. Appl. Biochem., 40, 187 (2004); doi:10.1042/BA20030142.
K.R. Jegannathan, S.S. Abang, D.D. Poncelet, E.S. Chan and P. Ravindra, Crit. Rev. Biotechnol., 28, 253 (2008).
N. Boz, N. Degirmenbasi and D.M. Kalyon, Appl. Catal. B, 89, 590 (2009); doi:10.1016/j.apcatb.2009.01.026.
N. Boz and M. Kara, Chem. Eng. Commun., 196, 80 (2008); doi:10.1080/00986440802301438.
N. Boz, N. Degirmenbasi and D.M. Kalyon, Appl. Catal. B, 138-139, 236 (2013); doi:10.1016/j.apcatb.2013.02.043.
N. Degirmenbasi, N. Boz and D.M. Kalyon, Appl. Catal. B, 150-151, 147 (2014); doi:10.1016/j.apcatb.2013.12.013.
N. Degirmenbasi and B. Ozgun, Monatsh. Chem., 134, 1565 (2003); doi:10.1007/s00706-003-0063-8.
M. Tamura, K. Tokonami, Y. Nakagawa and K. Tomishige, Chem. Commun., 49, 7034 (2013); doi:10.1039/C3CC41526K.
O. Ilgen, I. Dincer, M. Yildiz, E. Alptekin, N. Boz, M. Canakci and A.N. Akin, Turk. J. Chem., 31, 509 (2007).
W. Xie and X. Huang, Catal. Lett., 107, 53 (2006); doi:10.1007/s10562-005-9731-0.
Z. Yang and W. Xie, Fuel Process. Technol., 88, 631 (2007); doi:10.1016/j.fuproc.2007.02.006.
H. Li and W. Xie, Catal. Lett., 107, 25 (2006); doi:10.1007/s10562-005-9727-9.
W. Xie, Z. Yang and H. Chun, Ind. Eng. Chem. Res., 46, 7942 (2007); doi:10.1021/ie070597s.
N. Boz and O. Sunal, J. Fac. Eng. Arch. Gazi Univ., 24, 389 (2009).
C.R. Venkat Reddy, R. Oshel and J.G. Verkade, Energy Fuels, 20, 1310 (2006); doi:10.1021/ef050435d.
F. Qiu, Y. Li, D. Yang, X. Li and P. Sun, Bioresour. Technol., 102, 4150 (2011); doi:10.1016/j.biortech.2010.12.071.
Z. Kesica, I. Lukic, M. Zdujic, H. Liu and D. Skala, Procedia Eng., 42, 1169 (2012); doi:10.1016/j.proeng.2012.07.509.
R. Madhuvilakku and S. Piraman, Bioresour. Technol., 150, 55 (2013); doi:10.1016/j.biortech.2013.09.087.
American Oil Chemists’ Society, Official Test Method Cd 3a–63 for Acid Value, In: Official Methods and Recommended Practices of the American Oil Chemists’ Society, Champaign, IL (1998).
European Standard of EN 14103, Fat and Oil Derivatives – Fatty Acid Methyl Esters (FAME)–Determination of Ester and Linolenic Acid Methyl Ester Contents, April (2003).
N. Degirmenbasi, Z. Peralta-Inga, U. Olgun, H. Gocmez and D.M. Kalyon, J. Energ. Mater., 24, 103 (2006); doi:10.1080/07370650600672090.
N. Degirmenbasi, Z. Peralta-Inga, U. Olgun, H. Gocmez and D.M. Kalyon, J. Energ. Mater., 24, 103 (2006); doi:10.1080/07370650600672090.