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Vol. 27 No. 8 (2015): Vol 27 Issue 8

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Synthesis, Crystal Structure and Fluorescent Properties of 1D New Double Chain Silver(I) Complex

https://doi.org/10.14233/ajchem.2015.19111
Tian-Jun Ni
School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China
Zhi-Jun Yang
School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China
Guang-Jie He
Department of Forensic Medicine, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China
Ying-Ling Wang
School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China
Qian-Qian Huang
School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China
Qiang-Tao Yuan
School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China

Corresponding Author(s) : Guang-Jie He

guangjiehe@163.com

Asian Journal of Chemistry, Vol. 27 No. 8 (2015): Vol 27 Issue 8

Abstract

A novel silver(I) complex [Ag(btzx)2(NO3)]n [complex 1, where btzx = m-xylylenebis(tetrazole)] is synthesized and characterized by elemental analysis, IR, powder and single crystal X-ray diffraction. The crystal structural analysis shows that silver center is four-coordinated in a distorted tetrahedral geometry by four nitrogen atoms from four different btzx and there are very weak interactions exist between Ag(I) and NO3– anions. This complex displays a 1D ladder-like double chain framework, which is further fabricated into a 2D supramolecular framework via p–p interactions. The fluorescence properties of complex 1 were investigated.

Keywords

m-Xylylenebis(tetrazole) Flexible ligand Silver complex Coordination polymers
Ni, T.-J., Yang, Z.-J., He, G.-J., Wang, Y.-L., Huang, Q.-Q., & Yuan, Q.-T. (2015). Synthesis, Crystal Structure and Fluorescent Properties of 1D New Double Chain Silver(I) Complex. Asian Journal of Chemistry, 27(8), 3117–3120. https://doi.org/10.14233/ajchem.2015.19111
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