Synthesis of Picolines Over Metal Modified HZSM-5 Catalyst

F. Jiang; J.J. Huang; W.Y. Xiao; G.M. Xiao; H.Y. Li

doi:10.14233/ajchem.2015.17883

Issue

Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Issue Published : March 29, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis of Picolines Over Metal Modified HZSM-5 Catalyst

https://doi.org/10.14233/ajchem.2015.17883

F. Jiang

School of Chemistry and Chemical Engineering, Southeast University, Nanjing, P.R. China

J.J. Huang

School of Chemistry and Chemical Engineering, Southeast University, Nanjing, P.R. China

W.Y. Xiao

School of Chemistry and Chemical Engineering, Southeast University, Nanjing, P.R. China

G.M. Xiao

School of Chemistry and Chemical Engineering, Southeast University, Nanjing, P.R. China

H.Y. Li

School of Chemistry and Chemical Engineering, Southeast University, Nanjing, P.R. China

Corresponding Author(s) : G.M. Xiao

xiaogm@seu.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015
Article Published : March 29, 2015

Abstract

A series of metal (i.e. Pb, Cd, Zn, Co, Cr) modified H-ZSM-5 catalysts were prepared by an ion-exchange method and were characterized by XRD, FT-IR, NH₃-TPD and N₂ adsorption techniques. There catalytic activity was evaluated in the Chichibabin condensation of acetaldehyde and ammonia giving 2-picoline, 4-picoline and a small amount of pyridine as the product. The catalyst coking behaviour was also characterized by TG measurement. The characterization results showed that the crystal structure of H-ZSM-5 was well reserved and the active metal ions were evenly spread in the ZSM-5 framework. The surface acidity was enhanced a lot after the metal modification. Catalytic results showed that metal incorporated catalysts greatly increased the total yield of pyridine bases, especially which of 2-picoline and 4-picoline, meanwhile the ratio of 2-picoline/4-picoline was also enhanced.

Keywords

ZSM-5 Ion-exchange 2-Picoline 4-Picoline

Jiang, F., Huang, J., Xiao, W., Xiao, G., & Li, H. (2015). Synthesis of Picolines Over Metal Modified HZSM-5 Catalyst. Asian Journal of Chemistry, 27(7), 2415–2419. https://doi.org/10.14233/ajchem.2015.17883

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Issue

Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Synthesis of Picolines Over Metal Modified HZSM-5 Catalyst

Corresponding Author(s) : G.M. Xiao

Abstract

Keywords

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