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Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

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Spectrofluorimetric Study on Inclusion Behaviour of p-Sulfonated Calix[4,6]arene with 1,10-Phenanthroline

https://doi.org/10.14233/ajchem.2015.17897
Qian Du
Analytical and Testing Center, Shanxi Normal University, Linfen 041004, P.R. China
Cai-Ping Chen
Analytical and Testing Center, Shanxi Normal University, Linfen 041004, P.R. China
Hai-Long Liu
Analytical and Testing Center, Shanxi Normal University, Linfen 041004, P.R. China
Li-Ming Du
Analytical and Testing Center, Shanxi Normal University, Linfen 041004, P.R. China
Jun-Chen You
Analytical and Testing Center, Shanxi Normal University, Linfen 041004, P.R. China
Ya-Fen Chang
Analytical and Testing Center, Shanxi Normal University, Linfen 041004, P.R. China

Corresponding Author(s) : Li-Ming Du

lmd@dns.sxnu.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Abstract

The supramolecular interaction of 1,10-phenanthroline (Phen) with p-sulfonated calix[n]arenes (SCnA, n = 4, 6) were studied using spectrofluorimetry, 1H NMR and molecular modeling calculations. The interaction mechanism of the inclusion complex was discussed and the various factors affecting the inclusion process were examined. It was found that the dramatic quenching of the fluorescence intensity of 1,10-phenanthroline was observed with the addition of the SCnA (n = 4, 6). This was due to 1,10-phenanthroline react with SCnA (n = 4, 6) to form stable complex. 1H NMR titration spectra testified that 1,10-phenanthroline was penetrated into the hydrophobic cavity of SCnA (n = 4, 6). This finding was confirmed using molecular dynamics calculations and the thermodynamic parameters of the complex. The calculated stability constant results showed that the SC6A-Phen complex was more stable than SC4A-Phen.

Keywords

1 10-Phenanthroline p-Sulfonated calix[n]arenes Inclusion interaction Host-guest complexation Spectrofluorometry
Du, Q., Chen, C.-P., Liu, H.-L., Du, L.-M., You, J.-C., & Chang, Y.-F. (2015). Spectrofluorimetric Study on Inclusion Behaviour of p-Sulfonated Calix[4,6]arene with 1,10-Phenanthroline. Asian Journal of Chemistry, 27(7), 2431–2436. https://doi.org/10.14233/ajchem.2015.17897
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