Synthesis and Thermal Properties of Two Novel P-N Compounds

Shanshan Wei; Ligong Chen; Yang Li

doi:10.14233/ajchem.2015.17956

Issue

Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Issue Published : March 29, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Thermal Properties of Two Novel P-N Compounds

https://doi.org/10.14233/ajchem.2015.17956

Shanshan Wei

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P.R. China

Ligong Chen

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P.R. China

Yang Li

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P.R. China

Corresponding Author(s) : Yang Li

liyang777@tju.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015
Article Published : March 29, 2015

Abstract

Two novel P-N compounds were synthesized through a two-step reaction including the synthesis of 2-chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane-2-oxide (M) and its reaction with 2,2,6,6-tetramethylpiperidine-4-amine and N-butyl-2,2,6,6-tetramethylpiperidin-4-amine. The structures were confirmed by NMR (¹H, ¹³C, ³¹P), FT-IR and MS. Their thermal properties were also evaluated by thermogravimetric analysis (TGA). The TG curves showed that the two compounds have residues of 4.9 and 1.1 wt % at 600 ºC and the temperature of maximum weight loss rate (T_max) was 292 and 255 ºC, respectively.

Keywords

Synthesis P-N compounds Flame retardants Thermal properties Tmax

Wei, S., Chen, L., & Li, Y. (2015). Synthesis and Thermal Properties of Two Novel P-N Compounds. Asian Journal of Chemistry, 27(7), 2505–2507. https://doi.org/10.14233/ajchem.2015.17956

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References

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References

Y. Halpern, D.M. Mott and R.H. Niswander, Ind. Eng. Chem. Prod. Res. Dev., 23, 233 (1984); doi:10.1021/i300014a011.

M. Minagawa, Polym. Degrad. Stab., 25, 121 (1989); doi:10.1016/S0141-3910(89)81004-3.

W. Yang, R.K.K. Yuen, Y. Hu, H.D. Lu and L. Song, Ind. Eng. Chem. Res., 50, 11975 (2011); doi:10.1021/ie201550z.

D.J. Kind and T.R. Hull, Polym. Degrad. Stab., 97, 201 (2012); doi:10.1016/j.polymdegradstab.2011.12.008.

H. Horacek and S. Pieh, Polym. Int., 49, 1106 (2000); doi:10.1002/1097-0126(200010)49:10<1106::AID-PI539>3.0.CO;2-I.

M.R.L. Paine, P.J. Barker and S.J. Blanksby, Analyst, 136, 904 (2011); doi:10.1039/c0an00656d.

C.H. Ke, J. Li, K.Y. Fang, Q.L. Zhu, J. Zhu, Q. Yan and Y.Z. Wang, Polym. Degrad. Stab., 95, 763 (2010); doi:10.1016/j.polymdegradstab.2010.02.011.

P. Lv, Z.Z. Wang, K.L. Hu and W.C. Fan, Polym. Degrad. Stab., 90, 523 (2005); doi:10.1016/j.polymdegradstab.2005.04.003.

F. Xie, Y.Z. Wang, B. Yang and Y. Liu, Macromol. Mater. Eng., 291, 247 (2006); doi:10.1002/mame.200500356.

G. Camino, L. Costa and L. Trossarelli, Polym. Degrad. Stab., 6, 243 (1984); doi:10.1016/0141-3910(84)90004-1.

W.Y. Xing, L. Song, P. Lv, G.X. Jie, X. Wang, X.Q. Lv and Y. Hu, Mater. Chem. Phys., 123, 481 (2010); doi:10.1016/j.matchemphys.2010.04.044.

S.Q. Zhang, B. Li, M. Lin, Q.F. Li, S.L. Gao and W. Yi, J. Appl. Polym. Sci., 122, 3430 (2011); doi:10.1002/app.34428.

L.G. Lu, X. Wang, S.S. Yang, X.L. Dong, K. Tang and H.J. Yu, Acta Chim. Sin., 70, 190 (2012); doi:10.6023/A1105186.

E.T. Denisov, Polym. Degrad. Stab., 34, 325 (1991); doi:10.1016/0141-3910(91)90126-C.

J.L. Hodgson and M.L. Coote, Macromolecules, 43, 4573 (2010); doi:10.1021/ma100453d.

J.L. Hodgson, L.B. Roskop, M.S. Gordon, C.Y. Lin and M.L. Coote, J. Phys. Chem. A, 114, 10458 (2010); doi:10.1021/jp1064165.

Th. Schmutz, E. Kramer, H. Zweifel and G. Dörner, J. Elastom. Plast., 30, 55 (1998); doi:10.1177/009524439803000105.

D. Zhu, D.Y. Gui and J.P. Liu, Henan Chem. Ind., 22, 14 (2005).

H.Y. Ma, L.F. Tong, Z. Xu, Z. Fang, Y. Jin and F. Lu, Polym. Degrad. Stab., 92, 720 (2007); doi:10.1016/j.polymdegradstab.2006.12.009.

V. Sarannya, P. Sivasamy, N.D. Mathan, T. Rajkumar, D. Ponraju and C.T. Vijayakumar, J. Therm. Anal. Calorim., 102, 1071 (2010); doi:10.1007/s10973-010-0768-y.

W. Ten Hoeve and H. Wynberg, J. Org. Chem., 50, 4508 (1985); doi:10.1021/jo00223a018.

Issue

Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Synthesis and Thermal Properties of Two Novel P-N Compounds

Corresponding Author(s) : Yang Li

Abstract

Keywords

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