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Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

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Palladium Nanoparticles Stabilized by an Ionic Polymer and Its Application in Heck Reaction

https://doi.org/10.14233/ajchem.2015.17825
Bo Zhou
Department of Chemistry, College of Science, Honghe University, Mengzi 661100, Yunnan Province, P.R. China
Shi Juan Xu
Department of Chemistry, College of Science, Honghe University, Mengzi 661100, Yunnan Province, P.R. China
Gao Zhang Gou
Department of Chemistry, College of Science, Honghe University, Mengzi 661100, Yunnan Province, P.R. China
Na Wu
Department of Chemistry, College of Science, Honghe University, Mengzi 661100, Yunnan Province, P.R. China
Wei Liu
Department of Chemistry, College of Science, Honghe University, Mengzi 661100, Yunnan Province, P.R. China

Corresponding Author(s) : Wei Liu

liuwei4728@126.com

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Abstract

The palladium nanoparticles immobilized on the surface of poly(vinyl chloride)-supported pyridinium (PVC-Py-Pd0) were prepared by using the corresponding functionalized polymer and palladium chloride in ethanol solution. The palladium nanoparticles catalyst (PVC-Py-Pd0) was stable in the air and exhibited significant catalytic activity for Mizoroki-Heck coupling reaction of bromobenzene or iodobenzene with styrene under milder operating conditions. The catalytic system presented here showed several merits such as short reaction time, excellent yields of products, simple experimental and isolated procedure. Furthermore, the catalyst can be easily recycled and reused for at least five times with consistent activities.

Keywords

Palladium nanoparticle Immobilized Heck reaction Poly(vinyl chloride)
Zhou, B., Juan Xu, S., Zhang Gou, G., Wu, N., & Liu, W. (2015). Palladium Nanoparticles Stabilized by an Ionic Polymer and Its Application in Heck Reaction. Asian Journal of Chemistry, 27(7), 2353–2355. https://doi.org/10.14233/ajchem.2015.17825
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