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Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

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Synthesis Process of Amphoteric Polyacrylamide

https://doi.org/10.14233/ajchem.2015.17837
Linlin Zhang
School of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, Anhui Province, P.R. China
Rongchun Nie
School of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, Anhui Province, P.R. China
Shuai Ma
School of Civil Engineering and Architecture, Anhui University of Science and Technology, Huainan 232001, Anhui Province, P.R. China
Yanfen Wang
School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 232001, Anhui Province, P.R. China

Corresponding Author(s) : Rongchun Nie

nancylinlinzhang@126.com

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Abstract

In this work, amphoteric polyacrylamide(AmPAM) was synthesized via copolymerization and homopolymerization cohydrolysis based on photoinitiator as initiator, respectively. The result indicates that monomer ratio, monomer concentration, the amount of the initiator and pH have effects on the intrinsic viscosity of polymer. It achieved the best inherent viscosity when monomer ratio of n(AM):n(NaAA): n(DMC) was 1: 0.65:0.16, the monomer concentration was 35 %, the amount of the initiator was 0.08 % and pH value was adjusted to 7 by using copolymerization. The best intrinsic viscosity of the product was 759 mL/g and acrylamide (AM) conversion rate was 99.97 %. In contrast, it achieved the best inherent viscosity when monomer ratio of n(AM): n(NaOH): n(DMC) was 1: 0.15: 0.18, the monomer concentration was 35 %, the amount of the initiator was 0.06 % and pH value was adjusted to 7 by using homopolymerization cohydrolysis. The result demonstrates that the best intrinsic viscosity of the product was 531 mL/g and acrylamide conversion rate was 99.94 %.

Keywords

Photo-initiation AmPAM Homopolymerization cohydrolysis Copolymerization
Zhang, L., Nie, R., Ma, S., & Wang, Y. (2015). Synthesis Process of Amphoteric Polyacrylamide. Asian Journal of Chemistry, 27(7), 2369–2372. https://doi.org/10.14233/ajchem.2015.17837
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References
  1. F.S. Li, X.Q. Hu, M. Duan and H.J. Guo, Appl. Chem. Ind., 31, 1 (2002).
  2. X. Zhuang, Res. Environ. Sci., 19, 10 (2008).
  3. X.L. Xu, Y.F. Zhou, W.Y. Nie, L.Y. Song, M.D. Dai and C.M. Xia, Appl. Chem. Ind., 41, 819 (2012).
  4. X.H. Peng and Y.H. Jiang, Chinese J. Appl. Chem., 2, 988 (2006).
  5. B.A. Bolto, Prog. Polym. Sci., 20, 987 (1995); doi:10.1016/0079-6700(95)00010-D.
  6. H. Zhang, Y. Yang and S. Liu, Environ. Protect. Chem. Ind., 26, 63 (2006).
  7. Q.C. Wu, Specialty Petrochem., 3, 22 (2003).
  8. X.J. Liu, J. Yu, W. Ding, T. Yu and G.M. Guang, Adv. Fine Petrochem., 8, 10 (2010).
  9. J. Wang, X. Sun, W. Lei, M.Z. Xia and F.Y. Wang, Chem. Ind. Times, 17, 46 (2003).
  10. K.J. Yang, W.Q. Yang and J. Shen, Shanghai Paper Making, 39, 43 (2008).
  11. T. Wan, L. Feng, S.Y. Du, J. Wu and Y. Lu, Technol. Water Treatment, 31, 39 (2005).
  12. Z.W. Liu, R.C. Xiong and G. Wei, J. Beijing Univ. Chem. Technol., 35, 45 (2008).
  13. W.H. Huang and X.P. Ma, Drilling Fluid Completion Fluid, 22, 34 (2005).
  14. C.X. Wang, X.T. Li and Y.M. Wu, Period. Ocean Univ. China, 41, 125 (2011).
  15. K.J. Yang, W.Q. Su and J. Shen, Contemp. Chem. Ind., 35, 14 (2006).
  16. X. Liu, S. Xiang, Y. Yue, X. Su, W. Zhang, C. Song and P. Wang, Colloids Surfaces A, 311, 131 (2007); doi:10.1016/j.colsurfa.2007.06.007.
  17. X.L. Liu and Y.M. Wu, J. Qingdao Univ. Sci. Technol. (Nat. Sci. Ed.), 31, 371 (2010).
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