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Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

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Synthesis, Characterization and X-Ray Crystal Structure of Dizinc(II) Complex of Pseudo Calixarene Macrocycle Based on 2,2-Methylene-bis[(6-formyl)-4-tert-butylphenol] and 1,3-Diamino-2-propanol

https://doi.org/10.14233/ajchem.2015.18658
Imdad Hussain
Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan
Rubina Gillani
Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan
Vickie McKee
Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan
Muhammet Kose
Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan
Zulfiqar Ali
Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan
Habib Hussain
Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan

Corresponding Author(s) : Imdad Hussain

imdadsahi@gmail.com

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Abstract

[(2+2)Zn2·CH3COO] complex was prepared by refluxing 2,2-methylene-bis[(6-formyl)-4-tert-butylphenol] (H2mftbp) and 1,3-diamino-2-propanol in a round-bottomed flask containing Ca(ClO4)2 in ethanol in the presence of a base. Sample was taken from the refluxing solution and submitted for MS. ESI-MS showed the peak to confirm the formation of calcium complex [(2+2)Ca] but when Zn(CH3COO)2·2H2O was added and refluxed for further 6 h. Zinc replaced calcium metal and a new complex of Zn was formed as [Zn2(2+2)] complex. A yellow powder was filtered after cooling at room temperature. The powder was crystallized by vapour diffusion method. The complex crystallizes in the monoclinic crystal system with space group P2(1)/n. Unit cell parameters are; a = 13.6595(7) Å, b = 18.5216(9) Å, c = 25.0723(12) Å, a = 90°, b = 95.7020(10)°, g = 90°, Z = 8 and V= 6311.8(5) Å3. The complex was characterized by using single crystal X-ray spectroscopy, IR-spectroscopy and ESI-mass spectrophotometery.

Keywords

2 2-Methylene-bis[(6-formyl)-4-tert-butylphenol] 1 3-Diamino-2-propanol Zinc complex Calixarene
Hussain, I., Gillani, R., McKee, V., Kose, M., Ali, Z., & Hussain, H. (2015). Synthesis, Characterization and X-Ray Crystal Structure of Dizinc(II) Complex of Pseudo Calixarene Macrocycle Based on 2,2-Methylene-bis[(6-formyl)-4-tert-butylphenol] and 1,3-Diamino-2-propanol. Asian Journal of Chemistry, 27(7), 2630–2634. https://doi.org/10.14233/ajchem.2015.18658
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References
  1. (a) R.C. Long and D.N. Hendrickson, J. Am. Chem. Soc., 105, 1513 (1983); doi:10.1021/ja00344a018; (b) H. Okawa, J. Nishio, M. Ohba, M. Tadokoro, N. Matsumoto, M. Koikawa, S. Kida and D.E. Fenton, Inorg. Chem., 32, 2949 (1993); doi:10.1021/ic00065a025; (c) M. Yonemura, N. Usuki, Y. Nakamura, M. Ohba and H. Okawa, J. Chem. Soc., Dalton Trans., 3624 (2000); doi:10.1039/b006605m; (d) A. Atkins, D. Black, A.J. Blake, A. Marin-Becerra, S. Parsons, L. Ruiz-Ramirez and M. Schroder, Chem. Commun., 457 (1996); doi:10.1039/cc9960000457.
  2. (a) A. Hori, M. Yonemura, M. Ohba and H. Okawa, Bull. Chem. Soc. Jpn., 74, 495 (2001); doi:10.1246/bcsj.74.495; (b) M.J. Grannas, B.F. Hoskins and R. Robson, Inorg. Chem., 33, 1071 (1994); doi:10.1021/ic00084a017; (c) K.K. Nanda, S. Mohanta, U. Florke, S.K. Dutta and K. Nag, J. Chem. Soc., Dalton Trans., 3831 (1995); doi:10.1039/dt9950003831; (d) J. McCrea, V. McKee, T. Metcalfe, S.S. Tandon and J. Wikaira, Inorg. Chim. Acta, 297, 220 (2000); doi:10.1016/S0020-1693(99)00361-8.
  3. (a) V. McKee and S.S. Tandon, J. Chem. Soc., Dalton Trans., 221 (1991); doi:10.1039/dt9910000221; (b) P.E. Kruger and V. McKee, Chem. Commun., 1341 (1997); doi:10.1039/a702788e; (c) S. Cromie, V. McKee and F. Launay, Chem. Commun., 1918 (2001); doi:10.1039/b106340p.
  4. S.M. Nelson, Pure Appl. Chem., 52, 2461 (1980); doi:10.1351/pac198052112461.
  5. D.E. Fenton, Pure Appl. Chem., 58, 1437 (1986); doi:10.1351/pac198658111437.
  6. V. McKee, W.T. Robinson, D. McDowell and J. Nelson, Tetrahedron Lett., 30, 7453 (1989); doi:10.1016/S0040-4039(00)70723-4.
  7. Y. Nishida, N. Tanaka, A. Yamazaki, T. Tokii, N. Hashimoto, K. Ide and K. Iwasawa, Inorg. Chem., 34, 3616 (1995); doi:10.1021/ic00118a008.
  8. O. Jiménez-Sandoval, D. Ramírez-Rosales, M.J. Rosales-Hoz, M.E. Sosa-Torres and R. Zamorano-Ulloa, J. Chem. Soc., Dalton Trans., 1551 (1998); doi:10.1039/a801292j.
  9. D. Zhang, H. Wang, L. Tian, J. Jiang and Z. Ni, CrystEngComm, 11, 2447 (2009); doi:10.1039/b903174j.
  10. V. Yu Kukushkin, D. Tudela, Y.A. Izotova, V.K. Belsky and A.I. Stash, Polyhedron, 17, 2455 (1998); doi:10.1016/S0277-5387(98)00041-2.
  11. A.X.S. Bruker, APEX2-Software Suite for Crystallographic Programs, Bruker AXS Inc., Madison (2009).
  12. G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.
  13. L.J. Farrugia, J. Appl. Cryst., 32, 837 (1999); doi:10.1107/S0021889899006020.
  14. G.M. Sheldrick, SADABS-Bruker AXS Scaling and Absorption Correction, Bruker AXS Inc., Madison (2008).
  15. K. Brandenburg, Diamond-Crystal and Molecular Structure Visualization, v. 3.2g. Crystal Impact GbR, Bonn (2011).
  16. J.D. Dunitz, P. Seiler and R.P. Phizackerley, Acta Crystallogr. B, 30, 2739 (1974); doi:10.1107/S0567740874007928.
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