Copyright (c) 2015 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Green Synthesis of Cupric Oxide Nanoparticles Using Water Extract of Murrya koenigi and its Photocatalytic Activity
Corresponding Author(s) : N. Anusha
Asian Journal of Chemistry,
Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015
Abstract
Green synthesis of cupric oxide nanoparticles has been carried out from copper sulphate pentahydrate using the water extract of Murrya koenigi. The components present in the water extract react with copper sulphate pentahydrate to form an intermediate, which upon calcination at 300 ºC resulted in the formation of cupric oxide. The synthesized nanoparticles were spherical in shape and about 33-40 nm in size. X-Ray diffraction pattern confirmed the crystalline nature of cupric oxide. The green-synthesized cupric oxide nanoparticles possess excellent photocatalytic activity with about 80 % dye degradation in 10 min from initial concentration of 50 ppm.
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- R. Dhanya, K.S. Suganthi and K.S. Rajan, Asian J. Chem., 26, 4273 (2014); doi:10.14233/ajchem.2014.16100.
- K. Rohini Priya, K.S. Suganthi and K.S. Rajan, Int. J. Heat Mass Transf., 55, 4734 (2012); doi:10.1016/j.ijheatmasstransfer.2012.04.035.
- R. Srivastava, M.U. Anu Prathap and R. Kore, Colloids Surf. A, 392, 271 (2011); doi:10.1016/j.colsurfa.2011.10.004.
- N. Mittapelly, K. Mukkanti and B.R. Reguri, Asian J. Chem., 25, 483 (2013); doi:10.14233/ajchem.2013.13222.
- R. Sankar, P. Manikandan, V. Malarvizhi, T. Fathima, K.S. Shivashangari and V. Ravikumar, Spectrochim. Acta A, 121, 746 (2014); doi:10.1016/j.saa.2013.12.020.
- L. Hong, A.-L. Liu, G.-W. Li, W. Chen and X.-H. Lin, Biosens. Bioelectron., 43, 1 (2013); doi:10.1016/j.bios.2012.11.031.
- C. Yang, X. Su, J. Wang, X. Cao, S. Wang and L. Zhang, Sens. Actuators B, 185, 159 (2013); doi:10.1016/j.snb.2013.04.100.
- K. Gopalakrishnan, C. Ramesh, V. Ragunathan and M. Thamilselvan, Dig. J. Nanomet. Biostruct., 7, 833 (2012).
- J. Xu, C. Yao and Y. Wei, Asian J. Chem., 22, 6537 (2010).
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- M. Ahamed, H.A. Alhadlaq, M.A.M. Khan, P. Karuppiah and N.A. Al-Dhabi, J. Nanomater., 1 (2014); doi:10.1155/2014/637858.
- V.V.T. Padil and M. Cernik, Int. J. Nanomedicine, 8, 889 (2013).
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- M.B. Ningappa, B.L. Dhananjaya, R. Dinesha, R. Harsha and L. Srinivas, Food Chem., 118, 747 (2010); doi:10.1016/j.foodchem.2009.05.059.
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- S. Gupta, M. George and V. Garg, J. Adv. Pharm. Technol. Res., 1, 68 (2010).
- A. Ghasemzadeh, H.Z.E. Jaafar, A. Rahmat and T. Devarajan, Evid. Based Complement. Alternat. Med., 2014, 1 (2014); doi:10.1155/2014/873803.
- M. Malwal and R. Sarin, J. Indian Nat. Prod. Res., 2, 48 (2011).
- K.S. Rajan, S.N. Srivastava, B. Pitchumani and V. Surendiran, Int. J. Therm. Sci., 49, 182 (2010); doi:10.1016/j.ijthermalsci.2009.07.001.
- K.S. Rajan, S.N. Srivastava, B. Pitchumani and K. Dhasandhan, Appl. Therm. Eng., 28, 1932 (2008); doi:10.1016/j.applthermaleng.2007.12.004.
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References
R. Dhanya, K.S. Suganthi and K.S. Rajan, Asian J. Chem., 26, 4273 (2014); doi:10.14233/ajchem.2014.16100.
K. Rohini Priya, K.S. Suganthi and K.S. Rajan, Int. J. Heat Mass Transf., 55, 4734 (2012); doi:10.1016/j.ijheatmasstransfer.2012.04.035.
R. Srivastava, M.U. Anu Prathap and R. Kore, Colloids Surf. A, 392, 271 (2011); doi:10.1016/j.colsurfa.2011.10.004.
N. Mittapelly, K. Mukkanti and B.R. Reguri, Asian J. Chem., 25, 483 (2013); doi:10.14233/ajchem.2013.13222.
R. Sankar, P. Manikandan, V. Malarvizhi, T. Fathima, K.S. Shivashangari and V. Ravikumar, Spectrochim. Acta A, 121, 746 (2014); doi:10.1016/j.saa.2013.12.020.
L. Hong, A.-L. Liu, G.-W. Li, W. Chen and X.-H. Lin, Biosens. Bioelectron., 43, 1 (2013); doi:10.1016/j.bios.2012.11.031.
C. Yang, X. Su, J. Wang, X. Cao, S. Wang and L. Zhang, Sens. Actuators B, 185, 159 (2013); doi:10.1016/j.snb.2013.04.100.
K. Gopalakrishnan, C. Ramesh, V. Ragunathan and M. Thamilselvan, Dig. J. Nanomet. Biostruct., 7, 833 (2012).
J. Xu, C. Yao and Y. Wei, Asian J. Chem., 22, 6537 (2010).
K. Phiwdang, S. Suphankij, W. Mekprasart and W. Pecharapa, Energy Procedia, 34, 740 (2013); doi:10.1016/j.egypro.2013.06.808.
M. Ahamed, H.A. Alhadlaq, M.A.M. Khan, P. Karuppiah and N.A. Al-Dhabi, J. Nanomater., 1 (2014); doi:10.1155/2014/637858.
V.V.T. Padil and M. Cernik, Int. J. Nanomedicine, 8, 889 (2013).
R. Sivaraj, P.K.S.M. Rahman, P. Rajiv, S. Narendhran and R. Venckatesh, Spectrochim. Acta A, 129, 255 (2014); doi:10.1016/j.saa.2014.03.027.
S. Gunalan, R. Sivaraj and R. Venckatesh, Spectrochim. Acta A, 97, 1140 (2012); doi:10.1016/j.saa.2012.07.096.
L.J.M. Rao, K. Ramalakshmi, B.B. Borse and B. Raghavan, Food Chem., 100, 742 (2007); doi:10.1016/j.foodchem.2005.10.033.
M.B. Ningappa, B.L. Dhananjaya, R. Dinesha, R. Harsha and L. Srinivas, Food Chem., 118, 747 (2010); doi:10.1016/j.foodchem.2009.05.059.
P. Sharma, G. Vidyasagar, A. Bhandari, S. Singh, U. Bhadoriya, S. Ghule and N. Dubey, Asian Pac. J. Trop. Dis., 2, 230 (2012); doi:10.1016/S2222-1808(12)60052-8.
S. Sathaye, Y. Bagul, S. Gupta, H. Kaur and R. Redkar, Exp. Toxicol. Pathol., 63, 587 (2011); doi:10.1016/j.etp.2010.04.012.
S. Arivoli and S. Tennyson, Asian J. Exp. Biol. Sci., 2, 721 (2011).
A.N. Kesari, R.K. Gupta and G. Watal, J. Ethnopharmacol., 97, 247 (2005); doi:10.1016/j.jep.2004.11.006.
S. Gupta, M. George and V. Garg, J. Adv. Pharm. Technol. Res., 1, 68 (2010).
A. Ghasemzadeh, H.Z.E. Jaafar, A. Rahmat and T. Devarajan, Evid. Based Complement. Alternat. Med., 2014, 1 (2014); doi:10.1155/2014/873803.
M. Malwal and R. Sarin, J. Indian Nat. Prod. Res., 2, 48 (2011).
K.S. Rajan, S.N. Srivastava, B. Pitchumani and V. Surendiran, Int. J. Therm. Sci., 49, 182 (2010); doi:10.1016/j.ijthermalsci.2009.07.001.
K.S. Rajan, S.N. Srivastava, B. Pitchumani and K. Dhasandhan, Appl. Therm. Eng., 28, 1932 (2008); doi:10.1016/j.applthermaleng.2007.12.004.
K.S. Rajan, K. Dhasandhan, S.N. Srivastava and B. Pitchumani, Int. J. Heat Mass Transf., 51, 2801 (2008); doi:10.1016/j.ijheatmasstransfer.2007.09.042.
K.S. Rajan, S.N. Srivastava, B. Pitchumani and B. Mohanty, Appl. Therm. Eng., 27, 1345 (2007); doi:10.1016/j.applthermaleng.2006.10.026.
K.S. Rajan, B. Pitchumani, S.N. Srivastava and B. Mohanty, Int. J. Heat Mass Transf., 50, 967 (2007); doi:10.1016/j.ijheatmasstransfer.2006.08.009.
A. Jain, B. Mohanty, B. Pitchumani and K.S. Rajan, J. Heat Transf., 128, 761 (2006); doi:10.1115/1.2217748.
K.S. Rajan, S.N. Srivastava, B. Pitchumani and B. Mohanty, Int. Commun. Heat Mass Transf., 33, 1234 (2006); doi:10.1016/j.icheatmasstransfer.2006.06.011.