Synthesis and Structure of Two Supramolecular Compounds Based on Macrocyclic Nickel(II) Complex and [Mo8O26]4-

Zhong-Wen Huang; Ze-Yi Pan; Dong-Lai Zhou; Guang-Chuan Ou

doi:10.14233/ajchem.2015.18347

Issue

Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Issue Published : March 29, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Structure of Two Supramolecular Compounds Based on Macrocyclic Nickel(II) Complex and [Mo8O26]4-

https://doi.org/10.14233/ajchem.2015.18347

Zhong-Wen Huang

Department of Biology and Chemistry, Hunan University of Science and Engineering, 425199 Yongzhou, Hunan, P.R. China

Ze-Yi Pan

Department of Biology and Chemistry, Hunan University of Science and Engineering, 425199 Yongzhou, Hunan, P.R. China

Dong-Lai Zhou

Department of Biology and Chemistry, Hunan University of Science and Engineering, 425199 Yongzhou, Hunan, P.R. China

Guang-Chuan Ou

Department of Biology and Chemistry, Hunan University of Science and Engineering, 425199 Yongzhou, Hunan, P.R. China; Key Laboratory of Functional Organometallic Materials of Hunan Province College, Hengyang Normal University, 421008 Hengyang, Hunan, P.R. China

Corresponding Author(s) : Guang-Chuan Ou

ogcouguangchuan@163.com

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015
Article Published : March 30, 2015

Abstract

Two supramolecular structures with the formula [NiL]₂[Mo₈O₂₆]·2H₂O (1) and [NiL][Na₂Mo₈O₂₆] (2) (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) were synthesized and characterized by elemental analyses and IR spectra. The crystal structures were determined by the X-ray diffraction. The crystal of complex 1 is orthorhombic: space group Pbca, a = 17.812 (2), b = 15.942 (2), c = 19.295 (3) Å, V = 5478.8(12) Å³, Z = 4. The crystal of complex 2 is triclinic: space group P-1, a = 10.022(19), b = 10.717(2), c = 11.110(2) Å, a = 87.930(3)°, b = 72.115(3)°, g = 62.383(3)°, V = 998.2(3) Å³, Z = 1. In both complexes, the [NiL]²⁺ and [Mo₈O₂₆]^4- monomers are connected through intermolecular hydrogen bonding to generate two-dimensional sheets.

Keywords

Macrocyclic nickel(II) complexes Molybdenum cluster Hydrogen bonding

Huang, Z.-W., Pan, Z.-Y., Zhou, D.-L., & Ou, G.-C. (2015). Synthesis and Structure of Two Supramolecular Compounds Based on Macrocyclic Nickel(II) Complex and [Mo8O26]4-. Asian Journal of Chemistry, 27(7), 2579–2582. https://doi.org/10.14233/ajchem.2015.18347

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References

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A.K. Cheetham, G. Férey and T. Loiseau, Angew. Chem. Int. Ed., 38, 3268 (1999); doi:10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO;2-U.

A. Tripathi, T. Hughbanks and A. Clearfield, J. Am. Chem. Soc., 125, 10528 (2003); doi:10.1021/ja0365173.

D.E. Katsoulis, Chem. Rev., 98, 359 (1998); doi:10.1021/cr960398a.

D. Hagrman, P.J. Zapf and J. Zubieta, Chem. Commun., 1998, 1283 (1998); doi:10.1039/a801742e.

L.M. Zheng, Y.S. Wang, X.Q. Wang, J.D. Korp and A.J. Jacobson, Inorg. Chem., 40, 1380 (2001); doi:10.1021/ic0011967.

A.X. Tian, X.J. Liu, G.Y. Liu, J. Ying and X.L. Wang, Z. Anorg. Allg. Chem., 638, 141 (2012); doi:10.1002/zaac.201100376.

H.-J. Du, S. Zun-Zhe, Y.-Y. Niu, L.-S. Song and Y. Zhu, J. Solid State Chem., 190, 296 (2012); doi:10.1016/j.jssc.2012.02.050.

B.X. Dong and Q. Xu, Inorg. Chem., 48, 5861 (2009); doi:10.1021/ic900128t.

J.Q. Sha, Y.H. Zhang, L.Y. Liang, H.B. Qiu and M.Y. Liu, J. Coord. Chem., 65, 3264 (2012); doi:10.1080/00958972.2012.713101.

G.C. Ou, L. Jiang, X.L. Feng and T.B. Lu, Dalton Trans., 2009, 71 (2009); doi:10.1039/b810802a.

G.C. Ou, L. Jiang, X.L. Feng and T.B. Lu, Sci. China Ser. Biol. Chem., 52, 465 (2009); doi:10.1007/s11426-009-0043-x.

G.C. Ou, X.Y. Yuan and Z.Z. Li, Transition. Met. Chem., 37, 705 (2012); doi:10.1007/s11243-012-9641-0.

G.C. Ou, X.Y. Yuan and Z.Z. Li, Chin. J. Struct. Chem., 32, 375 (2013).

G.C. Ou, X.Y. Yuan, Z.Z. Li and M.H. Ding, J. Coord. Chem., 66, 2065 (2013); doi:10.1080/00958972.2013.796510.

G.C. Ou, Z.W. Huang, Z.Y. Pan, D.L. Zhou, Z.Z. Li and X.Y. Yuan, Wuji Huaxue Xuebao, 30, 419 (2014).

G.C. Ou, Z.W. Huang, Z.Y. Pan, D.L. Zhou and X.Y. Yuan, Chin. J. Struct. Chem., 33, 903 (2014).

N.F. Curtis, Y.M. Curtis and E.J.K. Powell, J. Chem. Soc. A, 1015 (1966); doi:10.1039/j19660001015.

A.M. Tait, D.H. Busch and N.F. Curtis, Inorg. Synth., 18, 10 (1978); doi:10.1002/9780470132494.ch2.

G.M. Sheldrick, SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen: Göttingen (1996).

G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.

M.L. Niven, J.J. Cruywagen and J.B.B. Heyns, J. Chem. Soc., Dalton Trans., 2007 (1991); doi:10.1039/dt9910002007.

Issue

Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Synthesis and Structure of Two Supramolecular Compounds Based on Macrocyclic Nickel(II) Complex and [Mo8O26]4-

Corresponding Author(s) : Guang-Chuan Ou

Abstract

Keywords

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