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Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

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A New Type of Organic Ferroelectric N-Dehydroabietyl-4-bromobenzamide

https://doi.org/10.14233/ajchem.2015.18628
Rong-Hua Hu
College of Chemistry and Chemical Engineering, The Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Yan Sui
College of Chemistry and Chemical Engineering, The Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Ji-Wu Wen
College of Chemistry and Chemical Engineering, The Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Zhi-Gang Luo
College of Chemistry and Chemical Engineering, The Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Long-Jin Zhong
College of Chemistry and Chemical Engineering, The Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China

Corresponding Author(s) : Yan Sui

ysui@163.com

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Abstract

A new organic low-molecular-mass compound N-dehydroabietyl-4-bromobenzamide (1) was synthesized using natural biomass dehydro-abietylamine and 4-bromobenzoic acid. Single crystal structure analysis revealed that compound 1 crystallized in a chiral and polar space group P21 and adjacent molecules were hold together by almost straight line N-H···O hydrogen bond chain. Compound 1 exhibits good second-order nonlinear optical and ferroelectric properties. The results indicated a new type organic ferroelectric material derived from natural biomass dehydroabietylamine.

Keywords

N-Dehydroabietyl-4-bromobenzamide Ferroelectric Nonlinear optical Dielectric
Hu, R.-H., Sui, Y., Wen, J.-W., Luo, Z.-G., & Zhong, L.-J. (2015). A New Type of Organic Ferroelectric N-Dehydroabietyl-4-bromobenzamide. Asian Journal of Chemistry, 27(7), 2627–2629. https://doi.org/10.14233/ajchem.2015.18628
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