Issue

Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Copyright (c) 2015 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Hydrothermal Synthesis and Crystal Structure of Ni(II) Complex with Azamacrocycle

https://doi.org/10.14233/ajchem.2015.17928
Jian-Hong Bi
College of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China
Meng Li
Pharmaceutical R & D Analytical Department, Lianhe Chemical Technology Co. Ltd., Taizhou City, Zhejiang Province, P.R. China
Hua-Ze Dong
College of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China

Corresponding Author(s) : Jian-Hong Bi

bi010101@126.com

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Abstract

A new azamacrocyclic Ni(II) complex with the m.f. C24H44N8O2Ni2 was synthesized by hydrothermal reaction and characterized by IR spectra and single-crystal X-ray diffraction. The crystal is in a Triclinic system, space group P-1 with unit cell parameters: a = 9.4238(3)Å, b = 9.44760(10) Å, c = 9.5006(3)Å, a = 77.706(2)º, b = 65.597(2)º, g = 71.132(2)º, V = 725.81(3)Å3, Z = 1, Mr = 594.09, Dc = 1.359 Mg/cm3, μ = 1.332 mm-1, F(000) = 316, T = 298(2) K, R = 0.0621, wR = 0.1534 for 3825 reflections with I > 2s(I). The crystal structure analysis shows that the nickel(II) ion was coordinated by four nitrogen atoms of the azamacrocycle.

Keywords

Ni(II) complex Azamacrocycle Hydrothermal synthesis Structure
Bi, J.-H., Li, M., & Dong, H.-Z. (2015). Hydrothermal Synthesis and Crystal Structure of Ni(II) Complex with Azamacrocycle. Asian Journal of Chemistry, 27(7), 2739–2740. https://doi.org/10.14233/ajchem.2015.17928
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. M. López-Deber, A. Aldrey, G. Castro-Justo, M.C. Fernández-Fernández, V. García-González, R. Bastida, A. Macías, P. Pérez-Lourido and L. Valencia, Polyhedron, 54, 54 (2013); doi:10.1016/j.poly.2013.01.040.
  2. R.N. Prasad and N. Sharma, J. Indian Chem. Soc., 89, 29 (2012).
  3. A. Bourdolle, M. Allali, J.C. Mulatier, B. Le Guennic, J.M. Zwier, P.L. Baldeck, J.-C.G. Bünzli, C. Andraud, L. Lamarque and O. Maury, Inorg. Chem., 50, 4987 (2011); doi:10.1021/ic200227b.
  4. J.H. Bi, B.Z. Li and H.Z. Dong, Asian J. Chem., 25, 8243 (2013); doi:10.14233/ajchem.2013.15396.
  5. J.H. Bi, W.T. Bi and N.L. Hu, Asian J. Chem., 24, 943 (2012).
  6. J.H. Bi, Asian J. Chem., 23, 5171 (2011).
  7. J.H. Bi and M. Cui, Asian J. Chem., 23, 5179 (2011).
  8. J.H. Bi and Y. Chen, Asian J. Chem., 23, 5185 (2011).
  9. J.H. Bi, Acta Crystallogr., E65, m668 (2009); doi:10.1107/S1600536809018091.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0