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Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

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Hydrothermal Synthesis and Structure of Tetraazamacrocyclic Copper Complex

https://doi.org/10.14233/ajchem.2015.17890
Lin Wang
College of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China
Bai-Zhong Li
Key Laboratory of Materials for High Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, P.R. China
Jian-Hong Bi
College of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China
Hua-Ze Dong
College of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China

Corresponding Author(s) : Jian-Hong Bi

bi010101@126.com

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Abstract

A new tetraazamacrocycle copper(II) complex with the m.f. C24H40N8S4Cu2 was synthesized by hydrothermal reaction and characterized by IR spectra and single-crystal X-ray diffraction. The crystal is in a triclinic system, space group P-1 with unit cell parameters: a = 8.861(3)Å, b = 18.832(7)Å, c = 20.826(6)Å, a = 74.194(12)º, b = 80.025(13)º, g = 79.714(9)º, V = 3261.5(19)Å3, Z = 4, Mr = 695.96, Dc = 1.417 Mg/cm3, μ = 1.588 mm-1, F(000) = 1448, T = 298(2) K, R = 0.0695, wR = 0.1584 for 11405 reflections with I > 2s(I). The crystal structure analysis shows that the Cu(II) ion was coordinated by four nitrogen atoms of the tetraazamacrocycle.

Keywords

Copper complex Tetraazamacrocycle Hydrothermal synthesis Crystal structure
Wang, L., Li, B.-Z., Bi, J.-H., & Dong, H.-Z. (2015). Hydrothermal Synthesis and Structure of Tetraazamacrocyclic Copper Complex. Asian Journal of Chemistry, 27(7), 2735–2736. https://doi.org/10.14233/ajchem.2015.17890
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