Issue

Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Copyright (c) 2015 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Structural Characterization of 4-Hydroxyanilinium 3,4,5,6-Tetrabromo-2-(methoxycarbonyl)benzoate Methanol Monosolvate

https://doi.org/10.14233/ajchem.2015.17995
Liang Zu Pei
College of Chemistry, Chemical and Environmental Engineering, Weifang University, Weifang 261061, P.R. China
Li Jian
College of Chemistry, Chemical and Environmental Engineering, Weifang University, Weifang 261061, P.R. China
Pan Xiao Ru
College of Chemistry, Chemical and Environmental Engineering, Weifang University, Weifang 261061, P.R. China

Corresponding Author(s) : Li Jian

lzpwfu@163.com

Asian Journal of Chemistry, Vol. 27 No. 7 (2015): Vol 27 Issue 7, 2015

Abstract

The compound, 4-hydroxyanilinium 3,4,5,6-tetrabromo-2-(methoxycarbonyl)benzoate methanol monosolvate (C16H15NO6Br4, Mr = 636.93) was synthesized and characterized by single crystal X-ray diffraction. The crystal belongs to triclinic, space group P-1, with a = 7.0403(9), b = 10.8695(12), c = 13.9844(16) Å, b = 82.852(2)°, V = 1033.4(2) Å3, Z = 2, Dc = 2.047 g/cm3. The final refinement gave R = 0.1051, wR(F2) = 0.2658 for 3,482 observed reflections with I > 2s(I). The asymmetric unit of the title compound contains one 4-hydroxyanilinium cation, one 3,4,5,6-tetrabromo-2-(methoxycarbonyl)benzoate anion and one methanol molecule. In the anion, the mean planes of the methoxycarbonyl and carboxylate groups form dihedral angles of 66.8 (3) and 88.8 (3)°, respectively with the benzene ring. In the crystal, intermolecular N---H...O and O---H...O hydrogen bonds connect the components of the structure to form a network.

Keywords

4-Hydroxyanilinium 3 4 5 6-tetrabromo-2-(methoxycarbonyl)benzoate Synthesis X-Ray diffraction
Zu Pei, L., Jian, L., & Xiao Ru, P. (2015). Synthesis and Structural Characterization of 4-Hydroxyanilinium 3,4,5,6-Tetrabromo-2-(methoxycarbonyl)benzoate Methanol Monosolvate. Asian Journal of Chemistry, 27(7), 2743–2744. https://doi.org/10.14233/ajchem.2015.17995
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. J.W. Roos and R.M. Moore, US Patent 5076970 (1991).
  2. J. Li, Acta Crystallogr., E67, o842 (2011); doi:10.1107/S1600536811008531.
  3. J. Li, Acta Crystallogr., E67, o200 (2011); doi:10.1107/S1600536810052591.
  4. J. Li, Acta Crystallogr., E67, o1356 (2011); doi:10.1107/S1600536811016850.
  5. J. Li, Acta Crystallogr., E67, o900 (2011); doi:10.1107/S1600536811008543.
  6. Z.P. Liang, Acta Crystallogr., E64, o2416 (2008); doi:10.1107/S1600536808038166.
  7. G. M. Sheldrick, SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Gottingen, Germany (1996).
  8. G.M. Sheldrick, SHELXTL V 5.1 Software Reference Manual, Bruker AXS, Inc., Madison, Wisconsin, USA (1997).
  9. Siemens, SMART and SAINT, Area Detector Control and Integration Software. Siemens Analytical X-Ray Systems, Inc., Madison, Wisconsin, USA (1996).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0