Voltammetric Studies and Micro Level Determination of Arsenic in Aqueous Matrices

Rajni Bais; Parul Rathore; Mukesh Tiwari

doi:10.14233/ajchem.2015.18041

Issue

Vol. 27 No. 6 (2015): Vol 27 Issue 6

Issue Published : March 17, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Voltammetric Studies and Micro Level Determination of Arsenic in Aqueous Matrices

https://doi.org/10.14233/ajchem.2015.18041

Rajni Bais

Electroanalytical Laboratory, Department of Chemistry, Jai Narayan Vyas University, Jodhpur-342 005, India

Parul Rathore

Electroanalytical Laboratory, Department of Chemistry, Jai Narayan Vyas University, Jodhpur-342 005, India

Mukesh Tiwari

Electroanalytical Laboratory, Department of Chemistry, Jai Narayan Vyas University, Jodhpur-342 005, India

Corresponding Author(s) : Rajni Bais

rajni.c31@gmail.com

Asian Journal of Chemistry, Vol. 27 No. 6 (2015): Vol 27 Issue 6
Article Published : March 18, 2015

Abstract

A differential pulse polarographic method for the trace determination of arsenic is presented. The preliminary investigations have indicated the suitability of a complexing media of 0.01 M citric acid in 0.01 M sodium acetate, where As(III) showed a sharp DP reduction peak at -0.93V vs SCE. Linearity of the calibration curve was achieved upto 8.5 ppm with a detection limit of 0.009 μg/mL. The coexisting metal ions such as Cu(II), Pb(II), Cd(II) and Zn(II) did not interfere. The differential pulse polarogram method has been applied successfully for the determination of arsenic contents in industrial wastes analysis.

Keywords

Arsenic Differential pulse polarogram Industrial wastes analysis

Bais, R., Rathore, P., & Tiwari, M. (2015). Voltammetric Studies and Micro Level Determination of Arsenic in Aqueous Matrices. Asian Journal of Chemistry, 27(6), 2181–2183. https://doi.org/10.14233/ajchem.2015.18041

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References

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References

D.E. Mays and A. Hussam, Anal. Chim. Acta, 646, 6 (2009); doi:10.1016/j.aca.2009.05.006.

S. Ahuja, Handbook of Water Purity and Quality, pp. 17-38 (2009).

S.S. Brown and J. Savory, Clinical Toxicology and Clinical Chemistry of Metals; Academic Press, London (1993).

S. Kamsonlian, C. Balomajumder and S. Chand, Res. J. Chem. Sci., 1, 73 (2011).

T.M.N. Dang, Q.T. Tran and K.V. Vu, Toxicol. Lett., 108, 179 (1999); doi:10.1016/S0378-4274(99)00087-9.

G.T. Macarovscha, G.G. Bortoleto and S. Cadore, Talanta, 71, 1150 (2007); doi:10.1016/j.talanta.2006.06.006.

A.N. Anthemidis and E.K. Martavaltzoglou, Anal. Chim. Acta, 573-574, 413 (2006); doi:10.1016/j.aca.2005.12.055.

A.Q. Shah, T.G. Kazi, J.A. Baig, M.B. Arain, H.I. Afridi, G.A. Kandhro, S.K. Wadhwa and N.F. Kolachi, Food Chem., 119, 840 (2010); doi:10.1016/j.foodchem.2009.08.041.

I.N. Pasias, N.S. Thomaidis and E.A. Piperaki, Microchem. J., 108, 1 (2013); doi:10.1016/j.microc.2012.11.008.

K. Jitmanee, M. Oshima and S. Motomizu, Talanta, 66, 529 (2005); doi:10.1016/j.talanta.2004.09.024.

T. Narukawa, K. Inagaki, T. Kuroiwa and K. Chiba, Talanta, 77, 427 (2008); doi:10.1016/j.talanta.2008.07.005.

P. Salaûn, B. Planer-Friedrich and C.M.G. van den Berg, Anal. Chim. Acta, 585, 312 (2007); doi:10.1016/j.aca.2006.12.048.

Y. Song and G.M. Swain, Anal. Chim. Acta, 593, 7 (2007); doi:10.1016/j.aca.2007.04.033.

D. Yamada, T.A. Ivandini, M. Komatsu, A. Fujishima and Y. Einaga, J. Electroanal. Chem., 615, 145 (2008); doi:10.1016/j.jelechem.2007.12.004.

S. Prakash, T. Chakrabarty, A.K. Singh and V.K. Shahi, Electrochim. Acta, 72, 157 (2012); doi:10.1016/j.electacta.2012.04.025.

L. Xiao, G.G. Wildgoose and R.G. Compton, Anal. Chim. Acta, 620, 44 (2008); doi:10.1016/j.aca.2008.05.015.

A. Salimi, H. Mamkhezri, R. Hallaj and S. Soltanian, Sens. Actuators B, 129, 246 (2008); doi:10.1016/j.snb.2007.08.017.

A. Giacomino, O. Abollino, M. Lazzara, M. Malandrino and E. Mentasti, Talanta, 83, 1428 (2011); doi:10.1016/j.talanta.2010.11.033.

G. Somer and Z. Almas, J. Electroanal. Chem., 593, 179 (2006); doi:10.1016/j.jelechem.2006.03.047.

N.G. Elenkova and R.A. Tsoneva, Talanta, 22, 480 (1975); doi:10.1016/0039-9140(75)80102-0.

P.L. Buldini, D. Ferri and P. Lanza, Anal. Chim. Acta, 113, 171 (1980); doi:10.1016/S0003-2670(01)85127-8.

F. Brusciotti and P. Duby, Electrochim. Acta, 52, 6644 (2007); doi:10.1016/j.electacta.2007.04.071.

P. Sharma, C. Rawat and S. Vyas, J. Indian Chem. Soc., 76, 114 (1999).

P. Sharma, S. Sanganeria and C. Rawat, Chem. Environ. Res., 2, 95 (1993).

P. Sharma, Anal. Sci., 11, 261 (1995); doi:10.2116/analsci.11.261.

P. Sharma, S. Vyas and S. Sanganeria, Indian J. Chem., 37A, 371 (1998).

V. Kherwa and S. Dubey, Res. J. Recent Sci., 2, 51 (2013).

S. Dubey and V. Kherwa, Res. J. Recent Sci., 2, 47 (2013).

R.C. Kapoor and B.S. Agarwal, Principles of Polarography, Wiley Eastern Ltd., New Delhi (1991).

Issue

Vol. 27 No. 6 (2015): Vol 27 Issue 6

Voltammetric Studies and Micro Level Determination of Arsenic in Aqueous Matrices

Corresponding Author(s) : Rajni Bais

Abstract

Keywords

Full Article

Download Citation

References

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