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This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis, Structure and Antioxidant Properties of Nickel(II) Complex with bis(Benzimidazol-2-ylmethyl)allylamine
Corresponding Author(s) : Huilu Wu
Asian Journal of Chemistry,
Vol. 27 No. 6 (2015): Vol 27 Issue 6
Abstract
A complex of nickel(II) picrate (pic) with bis(benzimidazol-2-ylmethyl)allylamine (AIDB), with composition [Ni(AIDB)2(pic)2], was synthesized in high yields and characterized by elemental analyses, molar conductivities, UV-visible spectra and IR spectra. X-ray crystallographic investigation of Ni(II) complex is distorted octahedral coordination geometry. The antioxidant activity of the complex was determined by the superoxide and hydroxyl radical scavenging methods in vitro, which indicate that it is a scavenger for OH• and O2–• radicals.
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D.A. Horton, G.T. Bourne and M.L. Smythe, Chem. Rev., 103, 893 (2003); doi:10.1021/cr020033s.
H.P. Berends and D.W. Stephan, Inorg. Chim. Acta, 93, 173 (1984); doi:10.1016/S0020-1693(00)88159-1.
SMART, SAINT, Area Detector Control and Integration Software, Bruker Analytical X-ray Instruments Inc., Madison, Wisconsin USA (2000).
G.M. Sheldrick, SHELXTL, Siemens Analytical X-ray Instruments Inc.,Madison, Wisconsin USA (1996).
G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.
H.L. Wu, K.T. Wang, F. Jia, B. Liu, F. Kou, J.K. Yuan and J. Kong, J. Coord. Chem., 63, 4113 (2010); doi:10.1080/00958972.2010.529903.
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S. Satyanarayana, J.C. Dabrowiak and J.B. Chaires, Biochemistry, 32, 2573 (1993); doi:10.1021/bi00061a015.
C.P. Tan, J. Liu, L.M. Chen, S. Shi and L.N. Ji, J. Inorg. Biochem., 102, 1644 (2008); doi:10.1016/j.jinorgbio.2008.03.005.
G.L. Pan, Y.C. Bai, H. Wang, J. Kong, F.R. Shi, Y.H. Zhang, X.L. Wang and H.L. Wu, Z. Naturforsch., 68b, 257 (2013); doi:10.5560/ZNB.2013-2339.
S. Satyanarayana, J.C. Dabrowiak and J.B. Chaires, Biochemistry, 31, 9319 (1992); doi:10.1021/bi00154a001.
T.R. Li, Z.Y. Yang, B.D. Wang and D.D. Qin, Eur. J. Med. Chem., 43, 1688 (2008); doi:10.1016/j.ejmech.2007.10.006.
Q.H. Luo, Q. Lu, A.B. Dai and L.G. Huang, J. Inorg. Biochem., 51, 655 (1993); doi:10.1016/0162-0134(93)85037-9.