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Hydrothermal Synthesis and Crystal Structure of Cobalt(II) Complex with Imidazole Ligand
Corresponding Author(s) : Jian-Hong Bi
Asian Journal of Chemistry,
Vol. 27 No. 6 (2015): Vol 27 Issue 6
Abstract
A new cobalt(II) complex with m.f. C40H50N12O4Co has been synthesized by the hydrothermal reaction of imidazole with Co(NO3)2 and sodium tert-butylbenzoate. The structure was characterized by IR and X-ray single crystal structure analysis. The crystal is in a monoclinic system, space group P2(1)/n with a =10.4215 (11) Å, b = 15.5263 (15) Å, c = 13.5857(12)Å, a = 90º, b = 106.8790 (10)º, g = 90º, V = 2103.6 (4) Å3, Z = 2, Mr = 821.85, Dc = 1.298 Mg/cm3, μ = 0.463 mm-1, F(000) = 866, T = 298(2) K, R = 0.0393, wR = 0.0955 for 10488 reflections with I>2s (I). In the molecular structure unit, metal ion octahedral geometry coordinated by six N atoms from six imidazole molecules.
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- J. Godlewska, J. Jezierska, K. Baranowska, E. Augustin and A. Dołęga, Polyhedron, 65, 288 (2013); doi:10.1016/j.poly.2013.08.039.
- A. Gogoi, G. Sarmah, A. Dewan and U. Bora, Tetrahedron Lett., 55, 31 (2014); doi:10.1016/j.tetlet.2013.10.084.
- S. Saha Halder, S. Roy, T. Kumar Mondal, R. Saha and C. Sinha, Z. Anorg. Allg. Chem., 639, 1861 (2013); doi:10.1002/zaac.201300173.
- A.C. Gonçalves, T.S. Morais, M.P. Robalo, F. Marques, F. Avecilla, C.P. Matos, I. Santos, A.I. Tomaz and M.H. Garcia, J. Inorg. Biochem., 129, 1 (2013); doi:10.1016/j.jinorgbio.2013.07.033.
- J.J. Gu, X.Y. Chen, H.L. Xin, X. Fang and X. Sha, Int. J. Pharm., 461, 559 (2014); doi:10.1016/j.ijpharm.2013.12.029.
- V.M. Manikandamathavan and B. Unni Nair, Eur. J. Med. Chem., 68, 244 (2013); doi:10.1016/j.ejmech.2013.07.051.
- A.A. Soayed, H.M. Refaat and D.A. Noor El-Din, Inorg. Chim. Acta, 406, 230 (2013); doi:10.1016/j.ica.2013.04.040.
References
J. Godlewska, J. Jezierska, K. Baranowska, E. Augustin and A. Dołęga, Polyhedron, 65, 288 (2013); doi:10.1016/j.poly.2013.08.039.
A. Gogoi, G. Sarmah, A. Dewan and U. Bora, Tetrahedron Lett., 55, 31 (2014); doi:10.1016/j.tetlet.2013.10.084.
S. Saha Halder, S. Roy, T. Kumar Mondal, R. Saha and C. Sinha, Z. Anorg. Allg. Chem., 639, 1861 (2013); doi:10.1002/zaac.201300173.
A.C. Gonçalves, T.S. Morais, M.P. Robalo, F. Marques, F. Avecilla, C.P. Matos, I. Santos, A.I. Tomaz and M.H. Garcia, J. Inorg. Biochem., 129, 1 (2013); doi:10.1016/j.jinorgbio.2013.07.033.
J.J. Gu, X.Y. Chen, H.L. Xin, X. Fang and X. Sha, Int. J. Pharm., 461, 559 (2014); doi:10.1016/j.ijpharm.2013.12.029.
V.M. Manikandamathavan and B. Unni Nair, Eur. J. Med. Chem., 68, 244 (2013); doi:10.1016/j.ejmech.2013.07.051.
A.A. Soayed, H.M. Refaat and D.A. Noor El-Din, Inorg. Chim. Acta, 406, 230 (2013); doi:10.1016/j.ica.2013.04.040.