Synthesis and Characterization of Potassium Manganese Nickel Sulphate Hexahydrate: A Potential UV Filter

Vanitha Duraikkan; Sultan Asath Bahadur; Shunmuganarayanan Athimoolam

doi:10.14233/ajchem.2016.19267

Issue

Vol. 28 No. 1 (2016): Vol 28 Issue 1

Issue Published : October 5, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Potassium Manganese Nickel Sulphate Hexahydrate: A Potential UV Filter

https://doi.org/10.14233/ajchem.2016.19267

Vanitha Duraikkan

International Research Centre, Department of Physics, Kalasalingam University, Krishnankoil-626 126, India

Sultan Asath Bahadur

International Research Centre, Department of Physics, Kalasalingam University, Krishnankoil-626 126, India

Shunmuganarayanan Athimoolam

Department of Physics, University College of Engineering, Anna University of Technology, Thirunelveli-627 007, India

Corresponding Author(s) : Vanitha Duraikkan

vanibala2003@gmail.com

Asian Journal of Chemistry, Vol. 28 No. 1 (2016): Vol 28 Issue 1
Article Published : October 6, 2015

Abstract

Single crystals of potassium manganese nickel sulphate hexahydrate were crystallized by the slow evaporation technique from aqueous solutions. Crystals obtained have been analyzed by powder XRD, single crystal XRD, SEM-EDX, FTIR, UV transmission, atomic absorption spectral analysis and TG-DTA. The lattice parameters were calculated from the XRD data. Atomic absorption spectral analysis showed that the Mn atoms were present in the mixed crystals and it is confirmed by EDX. Scanning electron microscopic studies used to understand the morphology of the calculi. The thermal analysis, TGA and DTA showed that the mixed crystals have higher thermal stability than the potassium nickel sulphate hexahydrate crystals. UV-visible spectral studies confirmed that the grown crystal is transmissive in the ultraviolet region.

Keywords

Ultraviolet filter Potassium manganese nickel sulphate hexahydrate Transmission spectrum Thermal stability

Duraikkan, V., Bahadur, S. A., & Athimoolam, S. (2015). Synthesis and Characterization of Potassium Manganese Nickel Sulphate Hexahydrate: A Potential UV Filter. Asian Journal of Chemistry, 28(1), 121–125. https://doi.org/10.14233/ajchem.2016.19267

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References

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References

S. Livneh, S. Selin, I. Zwieback and W. Ruderman, Ammonium Nickel Sulfate Crystals, US Patent 6,452,189 (2002).

G.B. Su, X.X. Zhuang, Y.P. He and G.Z. Zheng, Opt. Mater., 30, 916 (2008); doi:10.1016/j.optmat.2007.04.002.

G.B. Su, Y.P. He, Z.D. Li, R.H. Jiang, C.W. Zhu and S.F. Yang, J. Cryst. Growth, 213, 99 (2000); doi:10.1016/S0022-0248(00)00304-3.

Z. Xinxin, G. Su, Y. He, Z. Li, G. Li and J. Ma, J. Cryst. Growth, 244, 359 (2002); doi:10.1016/S0022-0248(02)01682-2.

M. Hemmati and H. Rezagholipour Dizaji, Cryst. Res. Technol., 47, 703 (2012); doi:10.1002/crat.201200011.

N.L. Sizova, V.L. Manomenova, E.B. Rudneva and A.E. Voloshin, Crystallogr. Rep., 52, 884 (2007); doi:10.1134/S1063774507050185.

Y. He, J. Chen, G. Su, X. Zhuang, G. Lee and R. Jiang, J. Cryst. Growth, 233, 809 (2001); doi:10.1016/S0022-0248(01)01564-0.

G. Su, X. Zhuang, Y. He, Z. Li, G. Li, J. Ma, G. Wang and Z. Huang, Cryst. Res. Technol., 38, 1087 (2003); doi:10.1002/crat.200310141.

N.B. Singh, W.D. Partlow, S. Strauch, A.M. Stewart, J.F. Jackovitz and D.W. Coffey, Crystals for Ultraviolet Light Filters, US Patent 5788765 (1998).

R. Kanagadurai, R. Durairajan, R. Sankar, G. Sivanesan, S.P. Elangovan and R. Jayavel, E-J. Chem., 6, 871 (2009); doi:10.1155/2009/459656.

C. Ilamaran, M. Sethuram, M. Dhandapani and G. Amirthaganesan, Pramana J. Phys., 78, 791 (2012); doi:10.1007/s12043-012-0274-9.

S.J. Hug, J. Colloid Interf. Sci., 188, 415 (1997); doi:10.1006/jcis.1996.4755.

G. Sivanesan, P. Kolandaivel and S.S. Pandian, Mater. Chem. Phys., 34, 73 (1993); doi:10.1016/0254-0584(93)90123-4.

Issue

Vol. 28 No. 1 (2016): Vol 28 Issue 1

Synthesis and Characterization of Potassium Manganese Nickel Sulphate Hexahydrate: A Potential UV Filter

Corresponding Author(s) : Vanitha Duraikkan

Abstract

Keywords

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