Copyright (c) 2015 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
A Cost Effective Green Biosorbent Simarouba glauca Seed Shell for Removal of Rhodamine B from Aqueous Solutions
Corresponding Author(s) : B. Jeyagowri
Asian Journal of Chemistry,
Vol. 27 No. 6 (2015): Vol 27 Issue 6
Abstract
This study presents the potential feasibility of a low cost green biosorbent for the removal of a basic dye rhodamine B from aqueous solutions. The biosorbent were characterized by FT-IR, SEM, XRD, BET and CHNS analysis. The effect of various parameters like initial dye concentration, contact time, pH and adsorbent dose were investigated in batch mode. The equilibrium data was analyzed using Langmuir, Freundlich, Temkin and D-R isotherm models. Equilibrium data showed best fit for Langmuir isotherm with maximum adsorption capacity 11.63 mg/g. Four kinetic models pseudo first order, pseudo second order, intraparticle diffusion and Boyd model were employed to describe the adsorption mechanism. Adsorption kinetics followed pseudo second order model with the coefficient of correlation R2 = 1. The experimental results suggested that SFTS (a biosorbent) was an excellent sorbent for removal of rhodamine B from aqueous solution.
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- M.A. Ahmad and R. Alrozi, Chem. Eng. J., 171, 510 (2011); doi:10.1016/j.cej.2011.04.018.
- H.B. Senturk, D. Ozdes and C. Duran, Desalination, 252, 81 (2010); doi:10.1016/j.desal.2009.10.021.
- B.H. Hameed, J. Hazard. Mater., 162, 939 (2009); doi:10.1016/j.jhazmat.2008.05.120.
- A. Witek-Krowiak, Chem. Eng. J., 192, 13 (2012); doi:10.1016/j.cej.2012.03.075.
- T.S. Anirudhan and P.G. Radhakrishnan, Desalination, 249, 1298 (2009); doi:10.1016/j.desal.2009.06.028.
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- Z. Zhang, I.M. O’Hara, G.A. Kent and W.O.S. Doherty, Ind. Crops Prod., 42, 41 (2013); doi:10.1016/j.indcrop.2012.05.008.
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- H.M.H. Gad and A.A. El-Sayed, J. Hazard. Mater., 168, 1070 (2009); doi:10.1016/j.jhazmat.2009.02.155.
- M.E. Fernandez, G.V. Nunell, P.R. Bonelli and A.L. Cukierman, Bioresour. Technol., 101, 9500 (2010); doi:10.1016/j.biortech.2010.07.102.
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- M.E. Fernandez, G.V. Nunell, P.R. Bonelli and A.L. Cukierman, Bioresour. Technol., 106, 55 (2012); doi:10.1016/j.biortech.2011.12.003.
- X. Xue, X. He and Y. Zhao, Desalin. Water Treat., 37, 259 (2012); doi:10.1080/19443994.2012.661281.
- C. Namasivayam and R.T. Yamuna, Water Air Soil Pollut., 113, 371 (1999); doi:10.1023/A:1005080301379.
- D. Kavitha and C. Namasivayam, Bioresour. Technol., 98, 14 (2007); doi:10.1016/j.biortech.2005.12.008.
- H. El Bakouri, J. Usero, J. Morillo and A. Ouassini, Bioresour. Technol., 100, 4147 (2009); doi:10.1016/j.biortech.2009.04.003.
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- C. Namasivayam, N. Kanchana and R.T. Yamuna, Waste Manage., 13, 89 (1993); doi:10.1016/0956-053X(93)90038-X.
- C. Namasivayam, N. Muniasamy, K. Gayatri, M. Rani and K. Ranganathan, Bioresour. Technol., 57, 37 (1996); doi:10.1016/0960-8524(96)00044-2.
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- D.J. Ju, I.G. Byun, J.J. Park, C.H. Lee, G.H. Ahn and T.J. Park, Bioresour. Technol., 99, 7971 (2008); doi:10.1016/j.biortech.2008.03.061.
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- W.J. Weber and J.C. Morris, Advances in Water Pollution Research: Removal of Biologically Resistant Pollutants from Waste Waters by Adsorption. In: Proceedings of the International Conference on Water Pollution Symposium, Pergamon Press, Oxford, vol. 2 (1962).
References
M.A. Ahmad and R. Alrozi, Chem. Eng. J., 171, 510 (2011); doi:10.1016/j.cej.2011.04.018.
H.B. Senturk, D. Ozdes and C. Duran, Desalination, 252, 81 (2010); doi:10.1016/j.desal.2009.10.021.
B.H. Hameed, J. Hazard. Mater., 162, 939 (2009); doi:10.1016/j.jhazmat.2008.05.120.
A. Witek-Krowiak, Chem. Eng. J., 192, 13 (2012); doi:10.1016/j.cej.2012.03.075.
T.S. Anirudhan and P.G. Radhakrishnan, Desalination, 249, 1298 (2009); doi:10.1016/j.desal.2009.06.028.
R. Ahmad and R. Kumar, J. Environ. Manage., 91, 1032 (2010); doi:10.1016/j.jenvman.2009.12.016.
C. Namasivayam and M.V. Sureshkumar, Bioresour. Technol., 99, 2218 (2008); doi:10.1016/j.biortech.2007.05.023.
M. Asgher and H.N. Bhatti, Ecol. Eng., 38, 79 (2012); doi:10.1016/j.ecoleng.2011.10.004.
S.D. Khattri and M.K. Singh, J. Hazard. Mater., 167, 1089 (2009); doi:10.1016/j.jhazmat.2009.01.101.
G.C. Panda, S.K. Das and A.K. Guha, J. Hazard. Mater., 164, 374 (2009); doi:10.1016/j.jhazmat.2008.08.015.
R. Dod, G. Banerjee and S. Saini, Biotechnol. Bioprocess Eng., 17, 862 (2012); doi:10.1007/s12257-011-0614-5.
Z. Zhang, I.M. O’Hara, G.A. Kent and W.O.S. Doherty, Ind. Crops Prod., 42, 41 (2013); doi:10.1016/j.indcrop.2012.05.008.
N. Gupta, A.K. Kushwaha and M.C. Chattopadhyaya, J. Taiwan Inst. Chem. Eng., 43, 604 (2012); doi:10.1016/j.jtice.2012.01.008.
M. Dogan, H. Abak and M. Alkan, J. Hazard. Mater., 164, 172 (2009); doi:10.1016/j.jhazmat.2008.07.155.
D.G. Kinniburgh, J.K. Syers and M.L. Jackson, Soil Sci. Soc. Am. Proc., 39, 464 (1975); doi:10.2136/sssaj1975.03615995003900030027x.
S. Benyoucef and M. Amrani, Desalination, 275, 231 (2011); doi:10.1016/j.desal.2011.03.004.
K.A. Krishnan and A. Haridas, J. Hazard. Mater., 152, 527 (2008); doi:10.1016/j.jhazmat.2007.07.015.
L. Wang, J. Zhang, R. Zhao, C. Li, Y. Li and C. Zhang, Desalination, 254, 68 (2010); doi:10.1016/j.desal.2009.12.012.
H.M.H. Gad and A.A. El-Sayed, J. Hazard. Mater., 168, 1070 (2009); doi:10.1016/j.jhazmat.2009.02.155.
M.E. Fernandez, G.V. Nunell, P.R. Bonelli and A.L. Cukierman, Bioresour. Technol., 101, 9500 (2010); doi:10.1016/j.biortech.2010.07.102.
S.-L. Hii, S.-Y. Yong and C.-L. Wong, J. Appl. Phycol., 21, 625 (2009); doi:10.1007/s10811-009-9448-3.
M.E. Fernandez, G.V. Nunell, P.R. Bonelli and A.L. Cukierman, Bioresour. Technol., 106, 55 (2012); doi:10.1016/j.biortech.2011.12.003.
X. Xue, X. He and Y. Zhao, Desalin. Water Treat., 37, 259 (2012); doi:10.1080/19443994.2012.661281.
C. Namasivayam and R.T. Yamuna, Water Air Soil Pollut., 113, 371 (1999); doi:10.1023/A:1005080301379.
D. Kavitha and C. Namasivayam, Bioresour. Technol., 98, 14 (2007); doi:10.1016/j.biortech.2005.12.008.
H. El Bakouri, J. Usero, J. Morillo and A. Ouassini, Bioresour. Technol., 100, 4147 (2009); doi:10.1016/j.biortech.2009.04.003.
V.K. Gupta, M.R. Ganjali, A. Nayak, B. Bhushan and S. Agarwal, Chem. Eng. J., 197, 330 (2012);doi:10.1016/j.cej.2012.04.104.
C. Namasivayam, K.D. Kumar, R. Selvi, T.A. Begum, T. Vanathi and R.T. Yamuna, Biomass Bioenergy, 21, 477 (2001); doi:10.1016/S0961-9534(01)00052-6.
C. Namasivayam, R. Radhika and S. Suba, Waste Manage., 21, 381 (2001); doi:10.1016/S0956-053X(00)00081-7.
K. Kadirvelu, C. Karthika, N. Vennilamani and S. Pattabhi, Chemosphere, 60, 1009 (2005); doi:10.1016/j.chemosphere.2005.01.047.
H. Lata, V.K. Garg and R.K. Gupta, Desalination, 219, 250 (2008);doi:10.1016/j.desal.2007.05.018.
C. Namasivayam, N. Kanchana and R.T. Yamuna, Waste Manage., 13, 89 (1993); doi:10.1016/0956-053X(93)90038-X.
C. Namasivayam, N. Muniasamy, K. Gayatri, M. Rani and K. Ranganathan, Bioresour. Technol., 57, 37 (1996); doi:10.1016/0960-8524(96)00044-2.
J. Anandkumar and B. Mandal, J. Hazard. Mater., 186, 1088 (2011); doi:10.1016/j.jhazmat.2010.11.104.
D.J. Ju, I.G. Byun, J.J. Park, C.H. Lee, G.H. Ahn and T.J. Park, Bioresour. Technol., 99, 7971 (2008); doi:10.1016/j.biortech.2008.03.061.
P.P. Selvam, S. Preethi, P. Basakaralingam, N. Thinakaran, A. Sivasamy and S. Sivanesan, J. Hazard. Mater., 155, 39 (2008); doi:10.1016/j.jhazmat.2007.11.025.
M.V. Sureshkumar and C. Namasivayam, Colloids Surf. A, 317, 277 (2008); doi:10.1016/j.colsurfa.2007.10.026.
W.J. Weber and J.C. Morris, Advances in Water Pollution Research: Removal of Biologically Resistant Pollutants from Waste Waters by Adsorption. In: Proceedings of the International Conference on Water Pollution Symposium, Pergamon Press, Oxford, vol. 2 (1962).