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Synthesis, Crystal Structures and Magnetic Properties of Two Lanthanide Coordination Polymers with 3-Carboxyphenoxyacetatic Acid
Corresponding Author(s) : Wen-Bin Li
Asian Journal of Chemistry,
Vol. 27 No. 5 (2015): Vol 27 Issue 5
Abstract
Two lanthanide(III) coordination polymers: [Ln(3-CPOA)1.5(phen)]n (Ln = Ce (1), Pr (2), 3-H2CPOA = 3-carboxyphenoxyacetatic acid, phen = 1,10-phenanthroline) have been hydrothermally synthesized and characterized by single crystal X-ray diffraction and magnetic measurements. Both polymers are isostructrural and crystallize in monoclinic space group P21/c. Single-crystal X-ray diffraction studies show that two complexes possess 3D framework structures based on a binuclear unit. Magnetic studies for two complexes show a stronger magnetic coupling between the lanthanide ions. (CCDC: 895012 for 1; 895013 for 2).
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- M. Kurmoo, Chem. Soc. Rev., 38, 1353 (2009); doi:10.1039/b804757j.
- J.Y. Lee, O.K. Farha, J. Roberts, K.A. Scheidt, S.B.T. Nguyen and J.T. Hupp, Chem. Soc. Rev., 38, 1450 (2009); doi:10.1039/b807080f.
- S.Q. Su, S. Wang, X.Z. Song, S.Y. Song, C. Qin, M. Zhu, Z.M. Hao, S.N. Zhao and H.J. Zhang, Dalton Trans., 41, 4772 (2012); doi:10.1039/c2dt12346k.
- J.Z. Gu, Z.Q. Gao and Y. Tang, Cryst. Growth Des., 12, 3312 (2012); doi:10.1021/cg300442b.
- I. Rodrigues, I. Mihalcea, C. Volkringer, T. Loiseau and M. Visseaux, Inorg. Chem., 51, 483 (2012); doi:10.1021/ic2019346.
- J.Z. Gu, J. Wu, D.Y. Lv, Y. Tang, K.Y. Zhu and J.C. Wu, Dalton Trans., 42, 4822 (2013); doi:10.1039/c2dt32674d.
- W.G. Lu, L. Jiang, X.L. Feng and T.B. Lu, Inorg. Chem., 48, 6997 (2009); doi:10.1021/ic900506z.
- Z.R. Pan, J. Xu, X.Q. Yao, Y.Z. Li, Z.J. Guo and H.G. Zheng, CrystEngComm, 13, 1617 (2011); doi:10.1039/c0ce00490a.
- Z.P. Deng, L.H. Huo, S. Gao and H.Z. Zhao, Anorg. Allg. Chem, 636, 835 (2010); doi:10.1002/zaac.200900374.
- S. Gao, C.S. Gu, H. Zhao and J.G. Zhao, Chinese J. Inorg. Chem., 20, 1437 (2004).
- G.M. Sheldrick, SHELXL NT Version 5.1, Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany (1997).
References
M. Kurmoo, Chem. Soc. Rev., 38, 1353 (2009); doi:10.1039/b804757j.
J.Y. Lee, O.K. Farha, J. Roberts, K.A. Scheidt, S.B.T. Nguyen and J.T. Hupp, Chem. Soc. Rev., 38, 1450 (2009); doi:10.1039/b807080f.
S.Q. Su, S. Wang, X.Z. Song, S.Y. Song, C. Qin, M. Zhu, Z.M. Hao, S.N. Zhao and H.J. Zhang, Dalton Trans., 41, 4772 (2012); doi:10.1039/c2dt12346k.
J.Z. Gu, Z.Q. Gao and Y. Tang, Cryst. Growth Des., 12, 3312 (2012); doi:10.1021/cg300442b.
I. Rodrigues, I. Mihalcea, C. Volkringer, T. Loiseau and M. Visseaux, Inorg. Chem., 51, 483 (2012); doi:10.1021/ic2019346.
J.Z. Gu, J. Wu, D.Y. Lv, Y. Tang, K.Y. Zhu and J.C. Wu, Dalton Trans., 42, 4822 (2013); doi:10.1039/c2dt32674d.
W.G. Lu, L. Jiang, X.L. Feng and T.B. Lu, Inorg. Chem., 48, 6997 (2009); doi:10.1021/ic900506z.
Z.R. Pan, J. Xu, X.Q. Yao, Y.Z. Li, Z.J. Guo and H.G. Zheng, CrystEngComm, 13, 1617 (2011); doi:10.1039/c0ce00490a.
Z.P. Deng, L.H. Huo, S. Gao and H.Z. Zhao, Anorg. Allg. Chem, 636, 835 (2010); doi:10.1002/zaac.200900374.
S. Gao, C.S. Gu, H. Zhao and J.G. Zhao, Chinese J. Inorg. Chem., 20, 1437 (2004).
G.M. Sheldrick, SHELXL NT Version 5.1, Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany (1997).