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Vol. 27 No. 5 (2015): Vol 27 Issue 5

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Surface Initiated ATRP of Acrylic Acid and Acrylamide on Cellulose Acetate Fiber

https://doi.org/10.14233/ajchem.2015.17395
Jin Wang
Yunnan Academy of Tobacco Science, Kunming 650106, Yunnan Province, P.R. China; Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China
Zhihua Liu
Yunnan Academy of Tobacco Science, Kunming 650106, Yunnan Province, P.R. China
Kunmiao Wang
Yunnan Academy of Tobacco Science, Kunming 650106, Yunnan Province, P.R. China
Pei He
Yunnan Academy of Tobacco Science, Kunming 650106, Yunnan Province, P.R. China
Chunbo Liu
Yunnan Academy of Tobacco Science, Kunming 650106, Yunnan Province, P.R. China
Yongkuan Chen
Yunnan Academy of Tobacco Science, Kunming 650106, Yunnan Province, P.R. China
Chuncheng Li
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China

Corresponding Author(s) : Yongkuan Chen

ykchen@cyats.com

Asian Journal of Chemistry, Vol. 27 No. 5 (2015): Vol 27 Issue 5

Abstract

Using surface initiated atom transfer radical polymerization (ATRP) as grafting method, acrylic acid and acrylamide grafting onto cellulose acetate fiber were successfully carried out. The chemical structures and molecular weights of copolymers were characterized by XPS, 1H NMR and FTIR. The thermal stabilities and topography of copolymers were investigated by TGA and SEM. The kinetics study revealed an approximately linear increase in the graft yield of the poly(acrylic acid) and polyacrylamide with polymerization concentration, indicating that chain growth from the fiber surface was consistent with a controlled process.

Keywords

Cellulose acetate Atom transfer radical polymerization Poly(acrylic acid) Polyacrylamide
Wang, J., Liu, Z., Wang, K., He, P., Liu, C., Chen, Y., & Li, C. (2015). Surface Initiated ATRP of Acrylic Acid and Acrylamide on Cellulose Acetate Fiber. Asian Journal of Chemistry, 27(5), 1621–1625. https://doi.org/10.14233/ajchem.2015.17395
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References
  1. D. Aoki, Y. Teramoto and Y. Nishio, Biomacromolecules, 8, 3749 (2007); doi:10.1021/bm7006828.
  2. M. Bertoldo, G. Zampano, F.L. Terra, V. Villari and V. Castelvetro, Biomacromolecules, 12, 388 (2011); doi:10.1021/bm101143q.
  3. Y. Cao, J. Wu, T. Meng, J. Zhang, J. He, H. Li and Y. Zhang, Carbohydr. Polym., 69, 665 (2007); doi:10.1016/j.carbpol.2007.02.001.
  4. Y. Cao, H. Li and J. Zhang, Ind. Eng. Chem. Res., 50, 7808 (2011); doi:10.1021/ie2004362.
  5. W.J. Deng, X.P. Zhuang, K.T. Guan and B.W. Cheng, Adv. Mater. Res., 221, 85 (2011); doi:10.4028/www.scientific.net/AMR.221.85.
  6. G.A. El Seoud, G.A. Marson, G.T. Ciacco and E. Frollini, Macromol. Chem. Phys., 201, 882 (2000); doi:10.1002/(SICI)1521-3935(20000501)201:8<882::AID-MACP882>3.0.CO;2-I.
  7. Y. Enomoto-Rogers, H. Kamitakahara, T. Takano and F. Nakatsubo, Biomacromolecules, 10, 2110 (2009); doi:10.1021/bm900229g.
  8. S.C. Fox, B. Li, D. Xu and K.J. Edgar, Biomacromolecules, 12, 1956 (2011); doi:10.1021/bm200260d.
  9. K.C. Gupta, S. Sahoo and K. Khandekar, Biomacromolecules, 3, 1087 (2002); doi:10.1021/bm020060s.
  10. Y. Luan, J. Wu, M. Zhan, J. Zhang, J. Zhang and J. He, Cellulose, 20, 327 (2013); doi:10.1007/s10570-012-9818-x.
  11. M.L. Hassan, R.M. Rowell, N.A. Fadl, S.F. Yacoub and A.W. Christainsen, J. Appl. Polym. Sci., 76, 561 (2000); doi:10.1002/(SICI)1097-4628(20000425)76:4<561::AID-APP14>3.0.CO;2-J.
  12. K.J. Edgar, C.M. Buchanan, J.S. Debenham, P.A. Rundquist, B.D. Seiler, M.C. Shelton and D. Tindall, Prog. Polym. Sci., 26, 1605 (2001); doi:10.1016/S0079-6700(01)00027-2.
  13. G.S. Luo, M. Niang and P. Schaetzel, Sep. Sci. Technol., 32, 1143 (1997); doi:10.1080/01496399708000952.
  14. M. Rahman and C.S. Brazel, Prog. Polym. Sci., 29, 1223 (2004); doi:10.1016/j.progpolymsci.2004.10.001.
  15. Y. Teramoto and Y. Nishio, Biomacromolecules, 5, 407 (2004); doi:10.1021/bm034453i.
  16. Y. Teramoto and Y. Nishio, Biomacromolecules, 5, 397 (2004); doi:10.1021/bm034452q.
  17. A.Y. Sankhe, S.M. Husson and S.M. Kilbey, Macromolecules, 39, 1376 (2006); doi:10.1021/ma0519361.
  18. S. Chen, G. Wu, Y. Liu and D. Long, Macromolecules, 39, 330 (2006); doi:10.1021/ma0520500.
  19. Z. Xu, Y. Yang, Y. Jiang, Y. Sun, Y. Shen and J. Pang, Molecules, 13, 490 (2008); doi:10.3390/molecules13030490.
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