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Synthesis and Structure of Cadmium Complex {[Cd(adi)0.5Cl(bimt)]·H2O}n
Corresponding Author(s) : Huai-Xia Yang
Asian Journal of Chemistry,
Vol. 27 No. 5 (2015): Vol 27 Issue 5
Abstract
The cadmium complex {[Cd(adi)0.5Cl(bimt)]·H2O}n (H2adi = adipic acid, bimt = 2-((benzoimidazol-yl)methyl)-1H-tetrazole) was prepared by reaction of CdCl2·2.5H2O, bimt and H2adip in methanol/water solution and its structure was determined by single crystal X-ray diffraction analysis. The crystals are triclinic, space group P-1 with a = 8.4863(17) Å, b = 8.5551(17) Å, c = 11.422(2) Å, a = 100.08(3)º, b = 106.33(3)º, g = 98.37(3)°, V = 766.7(3) Å3, Z = 2, F(000) = 434, Dc = 1.898 g/cm3, μ = 1.623 cm-1, the final R = 0.0252 and wR = 0.0566. A total of 8672 reflections were collected, of which 3584 were independent (Rint = 0.0216).
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- (a) B.T. Liu, R. Wang, G.H. Jin and X.R. Meng, J. Coord. Chem., 66, 1784 (2013); doi:10.1080/00958972.2013.790017; (b) L. Cheng, J.B. Lin, J.Z. Gong, A.P. Sun, B.H. Ye and X.M. Chen, Cryst. Growth Des., 6, 2739 (2006); doi:10.1021/cg060441f; (c) A. Banisafar, D.P. Martin, J.S. Lucas and R.L. LaDuca, Cryst. Growth Des., 11, 1651 (2011); doi:10.1021/cg101596y.
- (a) S.S. Chen, R. Qiao, L.Q. Sheng, Y. Zhao, S. Yang, M.M. Chen, Z.D. Liu and D.H. Wang, CrystEngComm, 15, 5713 (2013); doi:10.1039/c3ce40150b; (b) D.P. Martin, M.R. Montney, R.M. Supkowski and R.L. LaDuca, Cryst. Growth Des., 8, 3091 (2008); doi:10.1021/cg8003118; (c) X.J. Wang, Y.H. Liu, C.Y. Xu, Q.Q. Guo, H.W. Hou and Y.T. Fan, Cryst. Growth Des., 12, 2435 (2012); doi:10.1021/cg3000729; (d) T. Duangthongyou, C. Phakawatchai and S. Siripaisarnpipat, J. Mol. Struct., 987, 101 (2011); doi:10.1016/j.molstruc.2010.11.069.
- G.M. Sheldrick, SHELXS97, A Program for Crystal Structure Solution; University of Göttingen: Germany (1997).
- G.M. Sheldrick, SHELXL97, A Program for Crystal Structure Refinement; University of Göttingen: Germany (1997).
- (a) X. Su, T. Li, Y. Xiu and X.R. Meng, Z. Naturforsch., 67b, 678 (2012); doi:10.5560/ZNB.2012-0083; (b) X.X. Wang, X. Han, Y. Yang and X.R. Meng, Synth. React. Inorg. Met-Org. Nano-Met. Chem., 44, 462 (2014); doi:10.1080/15533174.2013.776603.
References
(a) B.T. Liu, R. Wang, G.H. Jin and X.R. Meng, J. Coord. Chem., 66, 1784 (2013); doi:10.1080/00958972.2013.790017; (b) L. Cheng, J.B. Lin, J.Z. Gong, A.P. Sun, B.H. Ye and X.M. Chen, Cryst. Growth Des., 6, 2739 (2006); doi:10.1021/cg060441f; (c) A. Banisafar, D.P. Martin, J.S. Lucas and R.L. LaDuca, Cryst. Growth Des., 11, 1651 (2011); doi:10.1021/cg101596y.
(a) S.S. Chen, R. Qiao, L.Q. Sheng, Y. Zhao, S. Yang, M.M. Chen, Z.D. Liu and D.H. Wang, CrystEngComm, 15, 5713 (2013); doi:10.1039/c3ce40150b; (b) D.P. Martin, M.R. Montney, R.M. Supkowski and R.L. LaDuca, Cryst. Growth Des., 8, 3091 (2008); doi:10.1021/cg8003118; (c) X.J. Wang, Y.H. Liu, C.Y. Xu, Q.Q. Guo, H.W. Hou and Y.T. Fan, Cryst. Growth Des., 12, 2435 (2012); doi:10.1021/cg3000729; (d) T. Duangthongyou, C. Phakawatchai and S. Siripaisarnpipat, J. Mol. Struct., 987, 101 (2011); doi:10.1016/j.molstruc.2010.11.069.
G.M. Sheldrick, SHELXS97, A Program for Crystal Structure Solution; University of Göttingen: Germany (1997).
G.M. Sheldrick, SHELXL97, A Program for Crystal Structure Refinement; University of Göttingen: Germany (1997).
(a) X. Su, T. Li, Y. Xiu and X.R. Meng, Z. Naturforsch., 67b, 678 (2012); doi:10.5560/ZNB.2012-0083; (b) X.X. Wang, X. Han, Y. Yang and X.R. Meng, Synth. React. Inorg. Met-Org. Nano-Met. Chem., 44, 462 (2014); doi:10.1080/15533174.2013.776603.