Excess Molar Volumes, Theoretical Viscosities and Ultrasonic Speeds of Binary Mixtures at 298.15 K and 303.15 K

Firdosa Nabi; Maqsood Ahmad Malik; Shaeel Ahmed Al-Thabaiti; Yau Ching Koon; Christopher G. Jesudason

doi:10.14233/ajchem.2015.17959

Issue

Vol. 27 No. 5 (2015): Vol 27 Issue 5

Issue Published : February 20, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Excess Molar Volumes, Theoretical Viscosities and Ultrasonic Speeds of Binary Mixtures at 298.15 K and 303.15 K

https://doi.org/10.14233/ajchem.2015.17959

Firdosa Nabi

Department of Chemistry, University of Malaya, Kuala Lumpur 50603, Malaysia

Maqsood Ahmad Malik

Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia

Shaeel Ahmed Al-Thabaiti

Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia

Yau Ching Koon

Department of Chemistry, University of Malaya, Kuala Lumpur 50603, Malaysia

Christopher G. Jesudason

Department of Chemistry, University of Malaya, Kuala Lumpur 50603, Malaysia

Corresponding Author(s) : Firdosa Nabi

firdosachem@gmail.com

Asian Journal of Chemistry, Vol. 27 No. 5 (2015): Vol 27 Issue 5
Article Published : February 20, 2015

Abstract

Excess molar volumes (Vh^E) deviations in entropies (DS^*) deviations in enthalpies (DH^*) of activation of viscous flow, theoretical viscosities (h_theo) and theoretical ultrasonic speeds (u_theo) of the binary mixtures of benzene with methyl acrylate, ethyl acrylate, butyl acrylate and styrene are reported. These parameters were calculated by using experimental viscosity and ultrasonic speed data and different empirical relations and theories were used to calculate the theoretical parameters. The results were discussed in terms of average deviations experimentally and theoretically calculated values. The sign and magnitude of these parameters were found to be sensitive towards intermolecular interactions prevailing in the studied systems. The predicted properties show a good accuracy in comparison with the experimental derived properties.

Keywords

Excess molar volumes Excess enthalpies Excess entropies Theoretical predictions Binary mixtures Molecular interactions

Nabi, F., Ahmad Malik, M., Ahmed Al-Thabaiti, S., Ching Koon, Y., & G. Jesudason, C. (2015). Excess Molar Volumes, Theoretical Viscosities and Ultrasonic Speeds of Binary Mixtures at 298.15 K and 303.15 K. Asian Journal of Chemistry, 27(5), 1815–1822. https://doi.org/10.14233/ajchem.2015.17959

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References

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References

B. Garcia, R. Alcalde, S. Aparicio and J.M. Leal, Phys. Chem. Chem. Phys., 4, 1170 (2002); doi:10.1039/b109709c.

B. Sinha, Phys. Chem. Liq., 48, 183 (2010); doi:10.1080/00319100802706691.

J.A. Al-Kandary, A.S. Al-Jimaz and A.H.M. Abdul-Latif, J. Chem. Thermodyn., 38, 1351 (2006); doi:10.1016/j.jct.2006.02.001.

F. Nabi, C.G. Jesudason, M.A. Malik and S.A. Al-Thabaiti, Chem. Eng. Commun., 200, 77 (2013); doi:10.1080/00986445.2012.691920.

A.K. Mehrotra, W.D. Monnery and W.Y. Svrcek, Fluid Phase Equilib., 117, 344 (1996); doi:10.1016/0378-3812(95)02971-0.

A. Ali and F. Nabi, J. Dispers. Sci. Technol., 31, 1326 (2010); doi:10.1080/01932690903227469.

F. Nabi, M.A. Malik and C.G. Jesudason, Asian J. Chem., 23, 3898 (2011).

A. Ali and F. Nabi, Acta Phys. Chim. Sin., 24, 47 (2008); doi:10.1016/S1872-1508(08)60005-4.

A. Ali, F. Nabi and M. Tariq, Int. J. Thermophys., 30, 464 (2009); doi:10.1007/s10765-009-0562-x.

A.J. Treszczanowicz, O. Kiyohara and G.C. Benson, J. Chem. Thermodyn., 13, 253 (1981); doi:10.1016/0021-9614(81)90125-7.

P.P. Singh, Indian J. Chem., 27A, 469 (1988).

H. Eyring and M.S. John, Significant Liquid Structures, John Wiley & Sons, New York (1969).

H. Eyring, J. Chem. Phys., 4, 283 (1936); doi:10.1063/1.1749836.

F. Corradini, L. Marcheselli, A. Marchetti, M. Tagliazucchi, L. Tassi and G. Tosi, Bull. Chem. Soc., 65, 503 (1992); doi:10.1246/bcsj.65.503.

L. Grunberg and A.H. Nissan, Nature, 164, 799 (1949); doi:10.1038/164799b0.

P.K. Katti and M.M. Chaudhri, J. Chem. Eng. Data, 9, 442 (1964); doi:10.1021/je60022a047.

R.K. Hind, E. McLaughlin and A.R. Ubbelohde, Trans. Faraday Soc., 56, 328 (1960); doi:10.1039/tf9605600328.

C.R. Wilke, J. Chem. Phys., 18, 517 (1950); doi:10.1063/1.1747673.

O. Nomoto, Phys. Soc. Jpn., 13, 1528 (1958); doi:10.1143/JPSJ.13.1528.

P.J. Flory, J. Am. Chem. Soc., 87, 1833 (1965); doi:10.1021/ja01087a002.

B. Jacobson, E. Halonen and C. Faurholt, Acta Chem. Scand., 6, 1485 (1952); doi:10.3891/acta.chem.scand.06-1485.

W. Van Deal and E. Vangeel, Ist. Int. Conf. on Calorimetry thermodynamics, Warsaw, p. 555 (1969).

S.S. Mathur, P.N. Gupta and S.C. Sinha, J. Phys. A: Gen. Phys., 4, 434 (1971); doi:10.1088/0305-4470/4/3/021.

Issue

Vol. 27 No. 5 (2015): Vol 27 Issue 5

Excess Molar Volumes, Theoretical Viscosities and Ultrasonic Speeds of Binary Mixtures at 298.15 K and 303.15 K

Corresponding Author(s) : Firdosa Nabi

Abstract

Keywords

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