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Vol. 27 No. 5 (2015): Vol 27 Issue 5

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Synthesis, Characterization and Crystal Structure of New 3-D Supramolecular Metal-Organic Framework Structure of Bis(1,10-phenanthroline-k2N,N')-(isonicotinate-k2O,O')-(nitrate-k2O,O')diaqua-neodymium(III) Isonicotinate

https://doi.org/10.14233/ajchem.2015.18095
Zhu Zhang
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Ming-Wei Hong
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Li Song
Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, P.R. China
Xiao-Jiong Chen
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Jia-Feng Sun
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Hong-Sheng Shi
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Lai-Shun Qin
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Kang-Ying Shu
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Wen-Xiang Chai
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian Province, P.R. China

Corresponding Author(s) : Wen-Xiang Chai

wxchai@cjlu.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 5 (2015): Vol 27 Issue 5

Abstract

For exploring the novel rare earth ions contained luminescent materials, aromatic ligands of isonicotinic acid (HIN) and 1,10-phenanthroline (phen) were used as antenna groups to construct luminescent molecule. This research lead to the synthesis and the structure determination of the title compound, Nd(IN)(NO3)(phen)2(H2O)2·(IN) (1), which was obtained by a solution reaction at room temperature. Two phen and one IN– anion ligands both chelated on the center Nd3+ ion, while the other IN– anion is dissociative from the coordinated molecule. The Nd3+ ion exhibits a 10-coordinated NdO6N4 geometry consisting of two O atoms derived from a IN– ligand, two atoms from NO3–, another two O atoms from two coordinated water molecules and four N atoms from two phen ligands. This mono-nuclear molecule and discrete isonicotinate anion are connected each other with O-H···N hydrgen bonds and p-p stacking interactions to form the 3-D metal-organic framworks.

Keywords

Crystal structure p-p Stacking interaction Hydrgen bond Metal organic frameworks Supramolecular framwork
Zhang, Z., Hong, M.-W., Song, L., Chen, X.-J., Sun, J.-F., Shi, H.-S., … Chai, W.-X. (2015). Synthesis, Characterization and Crystal Structure of New 3-D Supramolecular Metal-Organic Framework Structure of Bis(1,10-phenanthroline-k2N,N’)-(isonicotinate-k2O,O’)-(nitrate-k2O,O’)diaqua-neodymium(III) Isonicotinate. Asian Journal of Chemistry, 27(5), 1851–1853. https://doi.org/10.14233/ajchem.2015.18095
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