Chelation Behaviour of Aceturic Acid with Co(II), Ni(II) and Cu(II)

Umesh Kumar; Puja Singh; Shivadhar Sharma

doi:10.14233/ajchem.2015.18542

Issue

Vol. 27 No. 5 (2015): Vol 27 Issue 5

Issue Published : February 20, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Chelation Behaviour of Aceturic Acid with Co(II), Ni(II) and Cu(II)

https://doi.org/10.14233/ajchem.2015.18542

Umesh Kumar

University Department of Chemistry, Magadh University, Bodhgaya-824 234, India

Puja Singh

University Department of Chemistry, Magadh University, Bodhgaya-824 234, India

Shivadhar Sharma

University Department of Chemistry, Magadh University, Bodhgaya-824 234, India

Corresponding Author(s) : Shivadhar Sharma

sharma.shivadhar@gmail.com

Asian Journal of Chemistry, Vol. 27 No. 5 (2015): Vol 27 Issue 5
Article Published : February 20, 2015

Abstract

Aceturic acid consists of two parts e.g., peptide part i.e., CH₃CONH and -COOH part. It may act as bidentate ligand coordinating through either peptide or carboxylic acid part or both peptide as well as carboxylic acid part simultaneously forming chelates with transition metal ions. Some complexes of Co(II), Ni(II) and Cu(II) with aceturic acid have been prepared. The microanalysis and electrical conductivity of complexes revealed the formulation of complexes as ML₂X₂ where 'L' is aceturic acid and X' stands for a-picoline or pyridine. The comparison of infrared spectra of complexes with that of free ligand confirms the ligation point of the ligand through carboxylic acid and nitrogen of peptide part. Thus a 5-membered chelates are formed with Co(II), Ni(II) and Cu(II). The magnetic moment values of Co(II) complexes were found in the range of 4.90-4.93 BM at room temperature while it was in the range of 3.32-3.39 BM for Ni(II) complexes. Cu(II) complexes recorded magnetic moment 1.98-2.10 BM. These values are informative of octahedral symmetry around the metal ion which was confirmed by the electronic spectra of complexes.

Keywords

Aceturic acid 5-Membered chelate Metal(II) complexes

Kumar, U., Singh, P., & Sharma, S. (2015). Chelation Behaviour of Aceturic Acid with Co(II), Ni(II) and Cu(II). Asian Journal of Chemistry, 27(5), 1919–1922. https://doi.org/10.14233/ajchem.2015.18542

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References

T.R. Burman and G.N. Mukherjee, J. Indian Chem. Soc., 86, 1018 (2009).
N. Fujii and T. Saito, Chem. Rec., 4, 267 (2004); doi:10.1002/tcr.20020.
L.G. Korotchkina, E.M. Ciszak and M.S. Patel, Arch. Biochem. Biophys., 429, 171 (2004); doi:10.1016/j.abb.2004.06.027.
B.V. Tiwary, Rev. Soc. Quin. Peru, 76, 293 (2010).
G.H. Bindu and G.N. Rao, J. Indian Chem. Soc., 89, 1175 (2012).
P. Bhatnagar and N.K. Bhatnagar, J. Indian Chem. Soc., 89, 1273 (2012).
P. Bhushanwati, B. Veeraswamy, U. Viplavaprasad and G.N. Rao, J. Indian Chem. Soc., 90, 347 (2013).
K. Siddappa, P.C. Redd, M. Kote, T. Reddy, M. Lambe and M. Mitra, Asian J. Chem., 23, 4511 (2011).
P. Kumari, S. Prakash and D. Prakash, J. Indian Chem. Soc., 89, 19 (2012).
N.J. Leonard and F.H. Owens, J. Am. Chem. Soc., 80, 6039 (1958); doi:10.1021/ja01555a037.
D. Steele and P.F.M. Verhoeven, Vib. Spectrosc., 25, 29 (2001); doi:10.1016/S0924-2031(00)00103-X.
C.H. Bindu and G. Nageshwara Rao, J. Indian Chem. Soc., 89, 1175 (2012).
B.K. Bera, A. Mandal, P. Karmaleav, S. Mallik, S. Mandal and A.K. Ghosh, J. Indian Chem. Soc., 90, 1919 (2013).
14 M. Kaliva, T. Giannadaki, A. Salifoglou, C.P. Raptopoulou, A. Terzis and V. Tangoulis, Inorg. Chem., 40, 3711 (2001); doi:10.1021/ic000894o.
A.K. De and D. Deb, J. Indian Chem. Soc., 86, 76 (2009).
A.K. Srivastava, J. Indian Chem. Soc., 86, 281 (2009).
P. Bhatnagar and N.K. Bhatnagar, J. Indian Chem. Soc., 89, 1273 (2012).
S. Raju, K.B. Kumar Nayak, B.A. Kumar and G. Nageshwar Rao, J. Indian Chem. Soc., 89, 5 (2012).
R. Srinivasan, I. Sougandi, K. Velavan, R. Venkatesan, B. Verghese and P. Sambasiva Rao, Polyhedron, 23, 1115 (2004); doi:10.1016/j.poly.2004.01.016.
B.H. Mehta and S.D. Disala, J. Indian Chem. Soc., 89, 315 (2012).
R. Rani, R. Ranjan, N.C. Bhattacharjee, S. Sharma and A. Suriya, J. Indian Chem. Soc., 19, 331 (2013).
S. Chandra, D. Jain, A. Sarkar and Amipama, J. Indian Chem. Soc., 86, 220 (2009).
B.K. Rai and R. Kumari, Asian J. Chem., 23, 4625 (2011).
A.P. Mishra and K. Kumar, J. Indian Chem. Soc., 86, 1150 (2009).
A.K. Singh, S.P. Sinha, V. Kumar, S.S. Roy and S. Sharma, Asian J. Chem., 23, 4347 (2011).
B.N. Figgis, Introduction to Ligand Fields, Wiley Eastern Limited, New Delhi, pp. 265 (1964).
H.R.M. Bhowmik, A.K. De and R.N.D. Purkayastha, J. Indian Chem. Soc., 89, 177 (2012).
R.N. Prasad and P. Sharma, J. Indian Chem. Soc., 89, 865 (2012).
R.N. Patel, N. Chaudhary, K.K. Shukla, N. Singh and A. Singh, J. Indian Chem. Soc., 88, 789 (2011).
D. Prakash, C. Kumar, A.K. Gupta and K.R.R.P. Singh, J. Indian Chem. Soc., 86, 1257 (2009).

References

T.R. Burman and G.N. Mukherjee, J. Indian Chem. Soc., 86, 1018 (2009).

N. Fujii and T. Saito, Chem. Rec., 4, 267 (2004); doi:10.1002/tcr.20020.

L.G. Korotchkina, E.M. Ciszak and M.S. Patel, Arch. Biochem. Biophys., 429, 171 (2004); doi:10.1016/j.abb.2004.06.027.

B.V. Tiwary, Rev. Soc. Quin. Peru, 76, 293 (2010).

G.H. Bindu and G.N. Rao, J. Indian Chem. Soc., 89, 1175 (2012).

P. Bhatnagar and N.K. Bhatnagar, J. Indian Chem. Soc., 89, 1273 (2012).

P. Bhushanwati, B. Veeraswamy, U. Viplavaprasad and G.N. Rao, J. Indian Chem. Soc., 90, 347 (2013).

K. Siddappa, P.C. Redd, M. Kote, T. Reddy, M. Lambe and M. Mitra, Asian J. Chem., 23, 4511 (2011).

P. Kumari, S. Prakash and D. Prakash, J. Indian Chem. Soc., 89, 19 (2012).

N.J. Leonard and F.H. Owens, J. Am. Chem. Soc., 80, 6039 (1958); doi:10.1021/ja01555a037.

D. Steele and P.F.M. Verhoeven, Vib. Spectrosc., 25, 29 (2001); doi:10.1016/S0924-2031(00)00103-X.

C.H. Bindu and G. Nageshwara Rao, J. Indian Chem. Soc., 89, 1175 (2012).

B.K. Bera, A. Mandal, P. Karmaleav, S. Mallik, S. Mandal and A.K. Ghosh, J. Indian Chem. Soc., 90, 1919 (2013).

14 M. Kaliva, T. Giannadaki, A. Salifoglou, C.P. Raptopoulou, A. Terzis and V. Tangoulis, Inorg. Chem., 40, 3711 (2001); doi:10.1021/ic000894o.

A.K. De and D. Deb, J. Indian Chem. Soc., 86, 76 (2009).

A.K. Srivastava, J. Indian Chem. Soc., 86, 281 (2009).

P. Bhatnagar and N.K. Bhatnagar, J. Indian Chem. Soc., 89, 1273 (2012).

S. Raju, K.B. Kumar Nayak, B.A. Kumar and G. Nageshwar Rao, J. Indian Chem. Soc., 89, 5 (2012).

R. Srinivasan, I. Sougandi, K. Velavan, R. Venkatesan, B. Verghese and P. Sambasiva Rao, Polyhedron, 23, 1115 (2004); doi:10.1016/j.poly.2004.01.016.

B.H. Mehta and S.D. Disala, J. Indian Chem. Soc., 89, 315 (2012).

R. Rani, R. Ranjan, N.C. Bhattacharjee, S. Sharma and A. Suriya, J. Indian Chem. Soc., 19, 331 (2013).

S. Chandra, D. Jain, A. Sarkar and Amipama, J. Indian Chem. Soc., 86, 220 (2009).

B.K. Rai and R. Kumari, Asian J. Chem., 23, 4625 (2011).

A.P. Mishra and K. Kumar, J. Indian Chem. Soc., 86, 1150 (2009).

A.K. Singh, S.P. Sinha, V. Kumar, S.S. Roy and S. Sharma, Asian J. Chem., 23, 4347 (2011).

B.N. Figgis, Introduction to Ligand Fields, Wiley Eastern Limited, New Delhi, pp. 265 (1964).

H.R.M. Bhowmik, A.K. De and R.N.D. Purkayastha, J. Indian Chem. Soc., 89, 177 (2012).

R.N. Prasad and P. Sharma, J. Indian Chem. Soc., 89, 865 (2012).

R.N. Patel, N. Chaudhary, K.K. Shukla, N. Singh and A. Singh, J. Indian Chem. Soc., 88, 789 (2011).

D. Prakash, C. Kumar, A.K. Gupta and K.R.R.P. Singh, J. Indian Chem. Soc., 86, 1257 (2009).

Issue

Vol. 27 No. 5 (2015): Vol 27 Issue 5

Chelation Behaviour of Aceturic Acid with Co(II), Ni(II) and Cu(II)

Corresponding Author(s) : Shivadhar Sharma

Abstract

Keywords

Full Article

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