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Hydrothermal Synthesis and Structure of 1,10-Phenanthroline Nickel(II) Complex
Corresponding Author(s) : Jian-Hong Bi
Asian Journal of Chemistry,
Vol. 27 No. 4 (2015): Vol 27 Issue 4
Abstract
A new nickel(II) complex with molecular formula C26H16N6S2Ni has been synthesized by the reaction of 1,10-phenanthroline (phen) with NiOAc2 and KSCN. The structure was characterized by IR spectra and single-crystal X-ray diffraction. The crystal is in a orthorhombic system, space group Pbcn with a =13.0276(14)Å, b = 10.1210(10)Å, c = 17.4717(19)Å, a = 90º, b = 90º, g = 90º, V = 2303.7(4)Å3, Z = 4, Mr = 535.28, Dc = 1.543 Mg/cm3, μ = 1.052 mm-1, F(000) = 1096, T = 298(2) K, R = 0.0428, wR = 0.0658 for 9652 reflections with I > 2s(I). In the molecular structure unit, nickel(II) cation is coordinated by six donor atoms.
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- H.Z. Dong, W.B. Tao, J.H. Bi, V. Milway, Z. Xu, S. Zhang, X. Meng, W. Bi, J. Li and M. Li, Nanoscale Res. Lett., 6, 484 (2011); doi:10.1186/1556-276X-6-484.
- H.Z. Xie, S.J. Huang, J. Zhou, S.-P. Yu and D.-Y. Wei, Transition Met. Chem., 35, 773 (2010); doi:10.1007/s11243-010-9392-8.
- J.H. Bi, H.F. Wang, Z.X. Huang, W.-T. Bi and N.-L. Hu, Asian J. Chem., 20, 4966 (2008).
- S.M. Islam, M. Mobarok, P. Mondal, A.S. Roy, S. Mondal and D. Hossain, J. Appl. Polym. Sci., 123, 3789 (2012); doi:10.1002/app.34871.
- R. Boobalan, G.-H. Lee and C.P. Chen, Adv. Synth. Catal., 354, 2511 (2012); doi:10.1002/adsc.201200337.
- O. Ismail, A.S. Kipcak and S. Piskin, Res. Chem. Intermed., 39, 907 (2013); doi:10.1007/s11164-012-0604-z.
- B. Hu, F. Xu, S. Fu, T. Tao, Y. Wang and W. Huang, Inorg. Chim. Acta, 363, 1348 (2010); doi:10.1016/j.ica.2009.12.055.
- B.B. Xu, P. Shi, Q.Y. Guan, X. Shi and G.-L. Zhao, J. Coord. Chem., 66, 2605 (2013); doi:10.1080/00958972.2013.811497.
- N. Shahabadi and A. Fatahi, J. Mol. Struct., 970, 90 (2010); doi:10.1016/j.molstruc.2010.02.048.
References
H.Z. Dong, W.B. Tao, J.H. Bi, V. Milway, Z. Xu, S. Zhang, X. Meng, W. Bi, J. Li and M. Li, Nanoscale Res. Lett., 6, 484 (2011); doi:10.1186/1556-276X-6-484.
H.Z. Xie, S.J. Huang, J. Zhou, S.-P. Yu and D.-Y. Wei, Transition Met. Chem., 35, 773 (2010); doi:10.1007/s11243-010-9392-8.
J.H. Bi, H.F. Wang, Z.X. Huang, W.-T. Bi and N.-L. Hu, Asian J. Chem., 20, 4966 (2008).
S.M. Islam, M. Mobarok, P. Mondal, A.S. Roy, S. Mondal and D. Hossain, J. Appl. Polym. Sci., 123, 3789 (2012); doi:10.1002/app.34871.
R. Boobalan, G.-H. Lee and C.P. Chen, Adv. Synth. Catal., 354, 2511 (2012); doi:10.1002/adsc.201200337.
O. Ismail, A.S. Kipcak and S. Piskin, Res. Chem. Intermed., 39, 907 (2013); doi:10.1007/s11164-012-0604-z.
B. Hu, F. Xu, S. Fu, T. Tao, Y. Wang and W. Huang, Inorg. Chim. Acta, 363, 1348 (2010); doi:10.1016/j.ica.2009.12.055.
B.B. Xu, P. Shi, Q.Y. Guan, X. Shi and G.-L. Zhao, J. Coord. Chem., 66, 2605 (2013); doi:10.1080/00958972.2013.811497.
N. Shahabadi and A. Fatahi, J. Mol. Struct., 970, 90 (2010); doi:10.1016/j.molstruc.2010.02.048.