Copyright (c) 2015 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Production and Characterization of Activated Carbon From Iraqi Palm Fiber
Corresponding Author(s) : Zahraa H. Athab
Asian Journal of Chemistry,
Vol. 27 No. 4 (2015): Vol 27 Issue 4
Abstract
In this work, activated carbon was prepared from Iraqi palm fiber by zinc chloride activation. Activated cabon Iraqi palm fiber (PFAC) was used as low cost adsorbent material for removal of Brilliant Cresyl Blue dye (BCB) from aqueous media using batch adsorption technique. The effect of different parameters, such as, amount of adsorbent, contact time and pH were investigated. The removal efficiency of Brilliant Cresyl Blue was found equal to 98 % by using activated cabon Iraqi palm fiber. Langmuir and Freundlich models were applied in the present study to describe the adsorption isotherm. The isotherms of adsorption were fitted to the Langmuir equation better than Freundlich equation. Three kinetic models include pseudo-first order, pseudo-second order and intra-particle diffusion were applied to analyze Brilliant Cresyl Blue adsorption process. Kinetic studies showed that the adsorption kinetics was more accurately represented by a pseudo-second order model.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- S. Sahin, C. Demir and S. Gücer, Dyes Pigments, 73, 368 (2007); doi:10.1016/j.dyepig.2006.01.045.
- V. Golob and A. Ojstrsek, Dyes Pigments, 64, 57 (2005); doi:10.1016/j.dyepig.2004.04.006.
- V. Dharmalingam, A.K. Ramasamy and V. Balasuramanian, E-J. Chem., 8(s1), 335 (2011); doi:10.1155/2011/951848.
- B. Jamshidi, M.H. Ehrampoush and M. Dehvari, J. Environ. Treat. Techniq., 1, 151 (2013).
- G.Z. Kyzas, J. Fu and K. Matis, Materials, 6, 5131 (2013); doi:10.3390/ma6115131.
- M.N.V.R. Kumar, T.R. Sridhari, K.D. Bhavani and P.K. Dutta, Colourage, 45, 25 (1998).
- Q. Sun and L. Yang, Water Res., 37, 1535 (2003); doi:10.1016/S0043-1354(02)00520-1.
- N.K.E.M. Yahay, M.F.P.M. Latiff, I. Abustan, O.S. Bello and M.A. Ahmad, Int. J. Eng. Technol., 11, 248 (2011).
- Y.S. Ho, R. Malarvizhi and N. Sulochana, J. Environ. Prot. Sci., 3, 111 (2009).
- L. Ahmad, M.M. Loh and J.A. Aziz, Dyes Pigments, 75, 263 (2007); doi:10.1016/j.dyepig.2006.05.034.
- X. Han, W. Wang and X. Ma, Chem. Eng. J., 171, 1 (2011); doi:10.1016/j.cej.2011.02.067.
- A.W. Tan, B.H. Hameed and A.L. Ahmad, Chem. Eng. J., 127, 111 (2007); doi:10.1016/j.cej.2006.09.010.
- F.C. Wu, R.L. Tseng and C.C. Hu, Micropor. Mesopor. Mater., 80, 95 (2005); doi:10.1016/j.micromeso.2004.12.005.
- A. Jumasiah, T.G. Chuah, J. Gimbon, T.S.Y. Choong and I. Azni, Desalination, 186, 57 (2005); doi:10.1016/j.desal.2005.05.015.
- I.A.W. Tan, A.L. Ahmad and B.H. Hameed, J. Hazard. Mater., 153, 709 (2008); doi:10.1016/j.jhazmat.2007.09.014.
- B.H. Hameed, A.T.M. Din and A.L. Ahmad, J. Hazard. Mater., 141, 819 (2007); doi:10.1016/j.jhazmat.2006.07.049.
- K. Santhy and P. Selvapathy, Bioresour. Technol., 97, 1329 (2006); doi:10.1016/j.biortech.2005.05.016.
- Y. Guo, S. Yang, W. Fu, J. Qi, R. Li, Z. Wang and H. Xu, Dyes Pigments, 56, 219 (2003); doi:10.1016/S0143-7208(02)00160-2.
- I.A.W. Tan, A.L. Ahmad and B.H. Hameed, Colloids Surf. A, 318, 88 (2008); doi:10.1016/j.colsurfa.2007.12.018.
- M.R. Ishak, S.M. Sapuan, Z. Leman, M.Z.A. Rahman, U.M.K. Anwar and J.P. Siregar, Carbohydr. Polym., 91, 699 (2013); doi:10.1016/j.carbpol.2012.07.073.
- F.H. Hussein, A.F. Halbus, H. A K. Hassan and W.A.K. Hussein, E-J. Chem., 7, 540 (2010); doi:10.1155/2010/719674.
- M.J. Ahmed and S.K. Dhedan, Fluid Phase Equilib., 317, 9 (2012); doi:10.1016/j.fluid.2011.12.026.
- G.E.J. Poinern, D. Parsonage, T.B. Issa, M.K. Ghosh, E. Paling and P. Singh, Int. J. Eng. Sci. Technol., 2, 13 (2010).
- J.X. Lin, S.L. Zhan, M.H. Fang and X.Q. Qian, J. Porous Mater., 14, 449 (2007); doi:10.1007/s10934-006-9039-5.
- R. Katal, M.S. Baei, H.T. Rahmati and H. Esfandian, J. Ind. Eng. Chem., 18, 295 (2012); doi:10.1016/j.jiec.2011.11.035.
- G. Asgari, B. Roshani and G. Ghanizadeh, J. Hazard. Mater., 217-218, 123 (2012); doi:10.1016/j.jhazmat.2012.03.003.
- I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); doi:10.1021/ja02242a004.
- H. Freundlich, J. Phys. Chem., 57, 387 (1985).
- A.F. Halbus, Z.H. Athab and F.H. Hussein, Int. J. Chem. Sci., 11, 1219 (2013).
- Y.S. Ho and G. McKay, Process Biochem., 34, 451 (1999); doi:10.1016/S0032-9592(98)00112-5.
- W.J.J. Weber and J.C. Morriss, J. Sanit. Eng. Div., 89, 31 (1963).
References
S. Sahin, C. Demir and S. Gücer, Dyes Pigments, 73, 368 (2007); doi:10.1016/j.dyepig.2006.01.045.
V. Golob and A. Ojstrsek, Dyes Pigments, 64, 57 (2005); doi:10.1016/j.dyepig.2004.04.006.
V. Dharmalingam, A.K. Ramasamy and V. Balasuramanian, E-J. Chem., 8(s1), 335 (2011); doi:10.1155/2011/951848.
B. Jamshidi, M.H. Ehrampoush and M. Dehvari, J. Environ. Treat. Techniq., 1, 151 (2013).
G.Z. Kyzas, J. Fu and K. Matis, Materials, 6, 5131 (2013); doi:10.3390/ma6115131.
M.N.V.R. Kumar, T.R. Sridhari, K.D. Bhavani and P.K. Dutta, Colourage, 45, 25 (1998).
Q. Sun and L. Yang, Water Res., 37, 1535 (2003); doi:10.1016/S0043-1354(02)00520-1.
N.K.E.M. Yahay, M.F.P.M. Latiff, I. Abustan, O.S. Bello and M.A. Ahmad, Int. J. Eng. Technol., 11, 248 (2011).
Y.S. Ho, R. Malarvizhi and N. Sulochana, J. Environ. Prot. Sci., 3, 111 (2009).
L. Ahmad, M.M. Loh and J.A. Aziz, Dyes Pigments, 75, 263 (2007); doi:10.1016/j.dyepig.2006.05.034.
X. Han, W. Wang and X. Ma, Chem. Eng. J., 171, 1 (2011); doi:10.1016/j.cej.2011.02.067.
A.W. Tan, B.H. Hameed and A.L. Ahmad, Chem. Eng. J., 127, 111 (2007); doi:10.1016/j.cej.2006.09.010.
F.C. Wu, R.L. Tseng and C.C. Hu, Micropor. Mesopor. Mater., 80, 95 (2005); doi:10.1016/j.micromeso.2004.12.005.
A. Jumasiah, T.G. Chuah, J. Gimbon, T.S.Y. Choong and I. Azni, Desalination, 186, 57 (2005); doi:10.1016/j.desal.2005.05.015.
I.A.W. Tan, A.L. Ahmad and B.H. Hameed, J. Hazard. Mater., 153, 709 (2008); doi:10.1016/j.jhazmat.2007.09.014.
B.H. Hameed, A.T.M. Din and A.L. Ahmad, J. Hazard. Mater., 141, 819 (2007); doi:10.1016/j.jhazmat.2006.07.049.
K. Santhy and P. Selvapathy, Bioresour. Technol., 97, 1329 (2006); doi:10.1016/j.biortech.2005.05.016.
Y. Guo, S. Yang, W. Fu, J. Qi, R. Li, Z. Wang and H. Xu, Dyes Pigments, 56, 219 (2003); doi:10.1016/S0143-7208(02)00160-2.
I.A.W. Tan, A.L. Ahmad and B.H. Hameed, Colloids Surf. A, 318, 88 (2008); doi:10.1016/j.colsurfa.2007.12.018.
M.R. Ishak, S.M. Sapuan, Z. Leman, M.Z.A. Rahman, U.M.K. Anwar and J.P. Siregar, Carbohydr. Polym., 91, 699 (2013); doi:10.1016/j.carbpol.2012.07.073.
F.H. Hussein, A.F. Halbus, H. A K. Hassan and W.A.K. Hussein, E-J. Chem., 7, 540 (2010); doi:10.1155/2010/719674.
M.J. Ahmed and S.K. Dhedan, Fluid Phase Equilib., 317, 9 (2012); doi:10.1016/j.fluid.2011.12.026.
G.E.J. Poinern, D. Parsonage, T.B. Issa, M.K. Ghosh, E. Paling and P. Singh, Int. J. Eng. Sci. Technol., 2, 13 (2010).
J.X. Lin, S.L. Zhan, M.H. Fang and X.Q. Qian, J. Porous Mater., 14, 449 (2007); doi:10.1007/s10934-006-9039-5.
R. Katal, M.S. Baei, H.T. Rahmati and H. Esfandian, J. Ind. Eng. Chem., 18, 295 (2012); doi:10.1016/j.jiec.2011.11.035.
G. Asgari, B. Roshani and G. Ghanizadeh, J. Hazard. Mater., 217-218, 123 (2012); doi:10.1016/j.jhazmat.2012.03.003.
I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); doi:10.1021/ja02242a004.
H. Freundlich, J. Phys. Chem., 57, 387 (1985).
A.F. Halbus, Z.H. Athab and F.H. Hussein, Int. J. Chem. Sci., 11, 1219 (2013).
Y.S. Ho and G. McKay, Process Biochem., 34, 451 (1999); doi:10.1016/S0032-9592(98)00112-5.
W.J.J. Weber and J.C. Morriss, J. Sanit. Eng. Div., 89, 31 (1963).