Thermal and Spectral Characterization of Co(II) and Cu(II) Dinonyldithiophosphates: Removal of Co(II) and Cu(II) from Aqueous Solutions

H.B. Gumgum; Nermin Biricik

doi:10.14233/ajchem.2015.18854

Issue

Vol. 27 No. 4 (2015): Vol 27 Issue 4

Issue Published : February 4, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Thermal and Spectral Characterization of Co(II) and Cu(II) Dinonyldithiophosphates: Removal of Co(II) and Cu(II) from Aqueous Solutions

https://doi.org/10.14233/ajchem.2015.18854

H.B. Gumgum

Department of Physics, Faculty of Science, Dicle University, 21280 Diyarbakir, Turkey

Nermin Biricik

Department of Chemistry, Faculty of Science, Dicle University, 21280 Diyarbakir, Turkey

Corresponding Author(s) : H.B. Gumgum

hbudakg@gmail.com

Asian Journal of Chemistry, Vol. 27 No. 4 (2015): Vol 27 Issue 4
Article Published : February 4, 2015

Abstract

Dinonyldithiophosphoric acid (HDDTP) was prepared by addition of phosphorus pentasulphide to nonyl alcohol. Dinonyldithiophosphate complexes of Co(II) and Cu(II) with general formula [M(DDTP)₂] [M = Co(II) or Cu(II)] were prepared by mixing solutions of M(II) with dinonyldithiophosphoric acid in ethanol at room temperature. The acid and its complexes were caharacterized by elemental analysis and infrared, ultraviolet-visible and inductively coupled plasma-optical emission spectrometry. The thermal behaviour of M(DNDTP)₂ was investigated by thermogravimetric analysis under a nitrogen atmosphere. Removal of Co(II) and Cu(II) from aqueous media by dinonyldithiophosphoric acid solutions were investigated. The optimum conditions for extraction, such as the organic solvent, pH of the aqueous phase, time of equilibration, concentration and effect of anions, were studied. It was found that dinonyldithiophosphoric acid is an effective substance for removing Cu(II) and Co(II) from aqueous solutions.

Keywords

Dinonyldithiophosphate Extraction Removal of Cu(II) and Co(II) Spectroscopy Thermogravimetric analysis

Gumgum, H., & Biricik, N. (2015). Thermal and Spectral Characterization of Co(II) and Cu(II) Dinonyldithiophosphates: Removal of Co(II) and Cu(II) from Aqueous Solutions. Asian Journal of Chemistry, 27(4), 1543–1546. https://doi.org/10.14233/ajchem.2015.18854

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References

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References

G. Cote and D. Bauer, Rev. Inorg. Chem., 10, 121 (1989); doi:10.1515/REVIC.1989.10.1-3.121.

A.M. Barnes, K.D. Bartle and V.R.A. Thibon, Tribol. Int., 34, 389 (2001); doi:10.1016/S0301-679X(01)00028-7.

I. Haiduc, J. Organomet. Chem., 623, 29 (2001); doi:10.1016/S0022-328X(00)00677-X.

T.H. Handley and J.A. Dean, Anal. Chem., 34, 1312 (1962); doi:10.1021/ac60190a034.

R.H. Zucal, J.A. Dean and T.H. Handley, Anal. Chem., 35, 988 (1963); doi:10.1021/ac60201a021.

V.F. Toropova, A.R. Garifzyanov and I.E. Panfilova, Talanta, 34, 211 (1987); doi:10.1016/0039-9140(87)80029-2.

K.-H. Ohrbach, G. Matuschek, A. Kettrup and A. Joachim, Thermochim. Acta, 166, 277 (1990); doi:10.1016/0040-6031(90)80188-5.

S.Y. Wu and B. Xie, Wuji Huaxue Xuebao, 15, 267 (1999).

S. Al-Malaika, M. Coker and G. Scott, Polym. Degrad. Stab., 22, 147 (1988); doi:10.1016/0141-3910(88)90038-9.

R. Schumacher and H. Zinke, Tribol. Int., 30, 199 (1997); doi:10.1016/S0301-679X(96)00043-6.

C. Keromest, J.P. Durand, M. Born, P. Gateau, M. Tessier and E. Marechal, Rev. Inst. Petrol, 52, 35 (1997).

D.R. Armstrong, E.S. Ferrari, K.J. Roberts and D. Adams, Wear, 208, 138 (1997); doi:10.1016/S0043-1648(96)07332-2.

H. Sabik and R. Jeannot, J. Chromatogr. A, 879, 73 (2000); doi:10.1016/S0021-9673(00)00169-2.

A. Aguera, M. Contreras and A.R. Fernandezalba, J. Chromatogr. A, 655, 293 (1993); doi:10.1016/0021-9673(93)83235-K.

S. Lacorte, S.B. Lartiges, P. Garrigues and D. Barcelo, Environ. Sci. Technol., 29, 431 (1995); doi:10.1021/es00002a020.

I. Persson, J. Coord. Chem., 32, 261 (1994); doi:10.1080/00958979408024252.

X. Ying and Z. Fang, J. Hazard. Mater., 137, 1636 (2006); doi:10.1016/j.jhazmat.2006.04.055.

Y. Xu, Y. Chen and Y. Feng, Environ. Technol., 34, 1411 (2013); doi:10.1080/09593330.2012.752871.

A.M. Atta, H.S. Ismail and A.M. Elsaaed, J. Appl. Polym. Sci., 123, 2500 (2012); doi:10.1002/app.34798.

P. Rudnicki, Z. Hubicki and D. Kolodynska, Chem. Eng. J., 252, 362 (2014); doi:10.1016/j.cej.2014.04.035.

T. Motsi, N.A. Rowson and M.J.H. Simmons, Int. J. Miner. Process., 101, 42 (2011); doi:10.1016/j.minpro.2011.07.004.

M. Jovanovic, Z. Grbavcic, N. Rajic and B. Obradovic, Chem. Eng. Sci., 117, 85 (2014); doi:10.1016/j.ces.2014.06.017.

S. Chowdhury and P.D. Saha, Desalination Water Treat., 51, 6038 (2013); doi:10.1080/19443994.2013.764352.

B. Singha and S.K. Das, Colloids Surf. B, 107, 97 (2013); doi:10.1016/j.colsurfb.2013.01.060.

X. Guo, J. Lu and L. Zhang, J. Taiwan Inst. Chem. Eng., 44, 630 (2013); doi:10.1016/j.jtice.2012.12.020.

H.N. Bhatti, A. Saleem and M.A. Hanif, Desalination Water Treat., 51, 3335 (2013); doi:10.1080/19443994.2012.749188.

N. Biricik and B. Gümgüm, Thermochim. Acta, 417, 43 (2004); doi:10.1016/j.tca.2004.01.005.

Issue

Vol. 27 No. 4 (2015): Vol 27 Issue 4

Thermal and Spectral Characterization of Co(II) and Cu(II) Dinonyldithiophosphates: Removal of Co(II) and Cu(II) from Aqueous Solutions

Corresponding Author(s) : H.B. Gumgum

Abstract

Keywords

Full Article

Download Citation

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