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Synthesis and Crystal Structure of Supramolecular Copper(II) Complex Based on N2O2 Coordination Sphere
Corresponding Author(s) : L. Zhao
Asian Journal of Chemistry,
Vol. 27 No. 4 (2015): Vol 27 Issue 4
Abstract
Copper(II) complex has been synthesized via the complexation of copper(II) acetate monohydrate with 4,6-dichloro-4',6'-dibromo-2,2'-[ethylenediyldioxybis(nitrilo-methylidyne)]diphenol (H2L) in acetone/acetonitrile solution and characterized structurally by X-ray diffraction method. X-Ray crystallographic analysis reveals that the Cu(II) atom is four-coodinated by the four atoms of the donor set (N1, N2, O3 and O4) in the asymmetic Salamo-type L2- unit and Cu(II) atom approximately lie in the same plane, resulting in an almost regular distorted square-planar geometry. Each Cu(II) complex molecule links two neighboring molecules into an infinite 1D chain supramolecular structure through intermolecular C1-H1B···O3, C1-H1A···Cl1 and C2-H2A···Br1 hydrogen-bonding interactions.
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- W.K. Dong, G. Li, X. Li, C.J. Yang, M.M. Zhao and X.Y. Dong, Chinese J. Inorg. Chem., 30, 1911 (2014).
References
(a) A.K. Crane and M.J. MacLachlan, Eur. J. Inorg. Chem., 2012, 17 (2012); doi:10.1002/ejic.201100786; (b) A.D. Garnovskii, I.S. Vasichenko, D.A. Garnovskii and B.I. Kharisov, J. Coord. Chem., 62, 151 (2009); doi:10.1080/00958970802398178; (c) A.W. Kleij, Eur. J. Inorg. Chem., 193 (2009); doi:10.1002/ejic.200800936.
(a) E.M. McGarrigle and D.G. Gilheany, Chem. Rev., 105, 1563 (2005); doi:10.1021/cr0306945; (b) C. Mukherjee, T. Weyhermüller, E. Bothe and P. Chaudhuri, Inorg. Chem., 47, 11620 (2008); doi:10.1021/ic8011734.
(a) S. Akine, T. Taniguchi, W. Dong, S. Masubuchi and T. Nabeshima, J. Org. Chem., 70, 1704 (2005); doi:10.1021/jo048030y; (b) S. Akine, S. Kagiyama and T. Nabeshima, Inorg. Chem., 46, 9525 (2007); doi:10.1021/ic701585x; (c) S. Akine, S. Sunaga, T. Taniguchi, H. Miyazaki and T. Nabeshima, Inorg. Chem., 46, 2959 (2007); doi:10.1021/ic062327s; (d) S. Akine, T. Matsumoto, S. Sairenji and T. Nabeshima, Supramol. Chem., 23, 106 (2011); doi:10.1080/10610278.2010.514906.
R. Bagai and G. Christou, Chem. Soc. Rev., 38, 1011 (2009); doi:10.1039/b811963e.
M.F. Summers, L.G. Marzilli, N. Bresciani-Pahor and L. Randaccio, J. Am. Chem. Soc., 106, 4478 (1984); doi:10.1021/ja00328a030.
(a) A. Robertson and S. Shinkai, Coord. Chem. Rev., 205, 157 (2000); doi:10.1016/S0010-8545(00)00243-5; (b) P.D. Beer and E.J. Hayes, Coord. Chem. Rev., 240, 167 (2003); doi:10.1016/S0010-8545(02)00303-X.
L. Rigamonti, F. Demartin, A. Forni, S. Righetto and A. Pasini, Inorg. Chem., 45, 10976 (2006); doi:10.1021/ic0613513.
W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); doi:10.1080/00958972.2012.669038.
S. Bunce, R.J. Cross, L.J. Farrugia, S. Kunchandy, L.L. Meason, K.W. Muir, M. O’Donnell, R.D. Peacock, D. Stirling and S.J. Teat, Polyhedron, 17, 4179 (1998); doi:10.1016/S0277-5387(98)00226-5.
W.K. Dong, W. Du, X.Y. Zhang, G. Li and X.Y. Dong, Spectrochim. Acta A, 132, 588 (2014); doi:10.1016/j.saa.2014.04.168.
W.K. Dong, G. Li, X. Li, C.J. Yang, M.M. Zhao and X.Y. Dong, Chinese J. Inorg. Chem., 30, 1911 (2014).