A Molecular Imprinted Polymers with b-Cyclodextrin for Adsorption of Paeoniflorin

K.K. Zhao; W. Zhang; H.D. Zhang; H. Du; Q. Li; S.Y. Wang; Y. Wang

doi:10.14233/ajchem.2015.18230

Issue

Vol. 27 No. 4 (2015): Vol 27 Issue 4

Issue Published : February 4, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

A Molecular Imprinted Polymers with b-Cyclodextrin for Adsorption of Paeoniflorin

https://doi.org/10.14233/ajchem.2015.18230

K.K. Zhao

School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, Liaoning Province, P.R. China

W. Zhang

School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, Liaoning Province, P.R. China; Center of Fine Separation, University of Science and Technology Liaoning, Anshan, Liaoning Province, P.R. China

H.D. Zhang

School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, Liaoning Province, P.R. China

H. Du

School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, Liaoning Province, P.R. China

Q. Li

School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, Liaoning Province, P.R. China

S.Y. Wang

Y. Wang

School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, Liaoning Province, P.R. China

Corresponding Author(s) : W. Zhang

askdzw@163.com

Asian Journal of Chemistry, Vol. 27 No. 4 (2015): Vol 27 Issue 4
Article Published : February 4, 2015

Abstract

b-Cyclodextrin and epichlorohydrin were respectively used as functional monomer and cross-linker to synthesize molecularly imprinted polymers microspheres (MIPs) by suspension polymerization, for adsorption of paeoniflorin (PF), named PF-MIPs. The experiment indicated the PF-MIPs have specific selectivity on paeoniflorin. The paeoniflorin binding site was found inside of PF-MIPs by Scatchard analysis, with K_d and Q_max of 0.46 mg/mL and 47.22 mg/g, respectively. The adsorption process was endothermic process, the adsorption of paeoniflorin on MIPs followed Freundlich adsorption model. The PF-MIPs can be re-used to isolation paeoniflorin at least 10 times.

Keywords

Molecularly imprinted polymers Paeoniflorin Adsorption β-Cyclodextrin

Zhao, K., Zhang, W., Zhang, H., Du, H., Li, Q., Wang, S., & Wang, Y. (2015). A Molecular Imprinted Polymers with b-Cyclodextrin for Adsorption of Paeoniflorin. Asian Journal of Chemistry, 27(4), 1435–1438. https://doi.org/10.14233/ajchem.2015.18230

Download Citation

References

G. Wulff, Angew. Chem. Int. Ed. Engl., 34, 1812 (1995); doi:10.1002/anie.199518121.
J. Steinke, D.C. Sherrington and I.R. Dunkin, Adv. Polym. Sci., 123, 81 (1995); doi:10.1007/3-540-58908-2_3.
T. Matsunaga, T.H. Hishiya and T. Takeuchi, Anal. Chim. Acta, 591, 63 (2007); doi:10.1016/j.aca.2007.02.072.
C. Fang, L. Chen, W.M. Zhang and X.R. Zhou, J. Wuhan Univ., (Nat. Sci. Ed.), 49, 689 (2003).
J. Matsui, L.A. Nicholls, I. Karube and K. Mosbach, J. Org. Chem., 61, 5414 (1996); doi:10.1021/jo9516805.
Z.H. Meng, J.F. Wang, L.M. Zhou, Q.H. Wang and D.Q. Zhu, Chinese J. Chromatogr., 17, 323 (1999).
M. Kaneda, Y. Iitaka and S. Shibata, Tetrahedron, 28, 4309 (1972); doi:10.1016/S0040-4020(01)88953-5.
S. Shibata and M. Nakahara, Chem. Pharm. Bull. (Tokyo), 11, 372 (1963); doi:10.1248/cpb.11.372.
Y.J. Tong, Y. Xin, H.L. Yang, L. Zhang, Y.R. Zhang, Y. Chen, X.L. Xia and W. Wang, Chromatographia, 74, 443 (2011); doi:10.1007/s10337-011-2089-0.
M.H. Fan and S.Y. Xu, Sep. Purif. Technol., 61, 211 (2008); doi:10.1016/j.seppur.2007.07.046.
Y.J. Fu, Y.G. Zu, W. Liu, C.L. Hou, L.Y. Chen, S.M. Li, X.G. Shi and M.H. Tong, J. Chromatogr. A, 1139, 206 (2007); doi:10.1016/j.chroma.2006.11.015.
X.Z. Shi, A.B. Wu, G.R. Qu, R.X. Li and D.B. Zhang, Biomaterials, 28, 3741 (2007); doi:10.1016/j.biomaterials.2007.04.036.
M.L. Yang and X.G. Chu, Anal. Lett., 43, 2390 (2010); doi:10.1080/00032711003717380.
L.A. de Barros, I. Martins and S. Rath, Anal. Bioanal. Chem., 397, 1355 (2010); doi:10.1007/s00216-010-3629-4.

References

G. Wulff, Angew. Chem. Int. Ed. Engl., 34, 1812 (1995); doi:10.1002/anie.199518121.

J. Steinke, D.C. Sherrington and I.R. Dunkin, Adv. Polym. Sci., 123, 81 (1995); doi:10.1007/3-540-58908-2_3.

T. Matsunaga, T.H. Hishiya and T. Takeuchi, Anal. Chim. Acta, 591, 63 (2007); doi:10.1016/j.aca.2007.02.072.

C. Fang, L. Chen, W.M. Zhang and X.R. Zhou, J. Wuhan Univ., (Nat. Sci. Ed.), 49, 689 (2003).

J. Matsui, L.A. Nicholls, I. Karube and K. Mosbach, J. Org. Chem., 61, 5414 (1996); doi:10.1021/jo9516805.

Z.H. Meng, J.F. Wang, L.M. Zhou, Q.H. Wang and D.Q. Zhu, Chinese J. Chromatogr., 17, 323 (1999).

M. Kaneda, Y. Iitaka and S. Shibata, Tetrahedron, 28, 4309 (1972); doi:10.1016/S0040-4020(01)88953-5.

S. Shibata and M. Nakahara, Chem. Pharm. Bull. (Tokyo), 11, 372 (1963); doi:10.1248/cpb.11.372.

Y.J. Tong, Y. Xin, H.L. Yang, L. Zhang, Y.R. Zhang, Y. Chen, X.L. Xia and W. Wang, Chromatographia, 74, 443 (2011); doi:10.1007/s10337-011-2089-0.

M.H. Fan and S.Y. Xu, Sep. Purif. Technol., 61, 211 (2008); doi:10.1016/j.seppur.2007.07.046.

Y.J. Fu, Y.G. Zu, W. Liu, C.L. Hou, L.Y. Chen, S.M. Li, X.G. Shi and M.H. Tong, J. Chromatogr. A, 1139, 206 (2007); doi:10.1016/j.chroma.2006.11.015.

X.Z. Shi, A.B. Wu, G.R. Qu, R.X. Li and D.B. Zhang, Biomaterials, 28, 3741 (2007); doi:10.1016/j.biomaterials.2007.04.036.

M.L. Yang and X.G. Chu, Anal. Lett., 43, 2390 (2010); doi:10.1080/00032711003717380.

L.A. de Barros, I. Martins and S. Rath, Anal. Bioanal. Chem., 397, 1355 (2010); doi:10.1007/s00216-010-3629-4.

Issue

Vol. 27 No. 4 (2015): Vol 27 Issue 4

A Molecular Imprinted Polymers with b-Cyclodextrin for Adsorption of Paeoniflorin

Corresponding Author(s) : W. Zhang

Abstract

Keywords

Full Article

Download Citation

References

Table Of Contents