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Vol. 27 No. 4 (2015): Vol 27 Issue 4

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Synthesis and Structural Characterization of Diiron Azadithiolate Complex [(μ-SCH2)2NCH2CO2Me]Fe2(CO)4(CN-tert-Bu)2

https://doi.org/10.14233/ajchem.2015.17168
Hui Li
Department of Applied Chemistry, Yuncheng University, Yuncheng 044000, Shanxi Province, P.R. China
Qiaojuan Gong
Department of Applied Chemistry, Yuncheng University, Yuncheng 044000, Shanxi Province, P.R. China
Xiaochuan Chai
Department of Applied Chemistry, Yuncheng University, Yuncheng 044000, Shanxi Province, P.R. China
Chenzhong Yao
Department of Applied Chemistry, Yuncheng University, Yuncheng 044000, Shanxi Province, P.R. China
Qiuping Han
Department of Applied Chemistry, Yuncheng University, Yuncheng 044000, Shanxi Province, P.R. China

Corresponding Author(s) : Hui Li

lihuiwangf@163.com

Asian Journal of Chemistry, Vol. 27 No. 4 (2015): Vol 27 Issue 4

Abstract

A diiron azadithiolate complex [(μ-SCH2)2NCH2CO2Me]Fe2(CO)4(CN-tert-Bu)2 (1), as the active site of [FeFe]-hydrogenases, has been prepared by carbonyl substitution and structurally characterized. The title complex was prepared by reaction of [(μ-SCH2)2NCH2CO2Me]Fe2(CO)6 (A) with tert-BuNC in CH2Cl2 in 46 % yield. The new complex was characterized by IR, 1H NMR and 13C NMR spectroscopy.

Keywords

Diiron azadithiolate Isocyanide
Li, H., Gong, Q., Chai, X., Yao, C., & Han, Q. (2015). Synthesis and Structural Characterization of Diiron Azadithiolate Complex [(μ-SCH2)2NCH2CO2Me]Fe2(CO)4(CN-tert-Bu)2. Asian Journal of Chemistry, 27(4), 1555–1556. https://doi.org/10.14233/ajchem.2015.17168
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