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Vol. 27 No. 4 (2015): Vol 27 Issue 4

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Hydrothermal Synthesis and Structure of Zn(II) Thiocyanate Complex of Phenanthroline

https://doi.org/10.14233/ajchem.2015.17752
Lin Wang
College of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China
Jian-Hong Bi
College of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China
Hua-Ze Dong
College of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China

Corresponding Author(s) : Jian-Hong Bi

bi010101@126.com

Asian Journal of Chemistry, Vol. 27 No. 4 (2015): Vol 27 Issue 4

Abstract

A new Zn(II) complex with m.f. C26H16N6S2Zn has been synthesized by the hydrothermal reaction of 1,10-phenanthroline (phen) with ZnSO4 and KSCN. The structure was characterized by IR spectra and single-crystal X-ray diffraction. The crystal is present in a orthorhombic system, space group Pbcn with a = 13.1988(15) Å, b = 10.0779(13) Å, c = 17.4640(19) Å, a = 90º, b = 90º, g = 90º, V = 2323.0(5)Å3, Z = 4, Mr = 541.94, Dc = 1.550 Mg/cm3, μ = 1.266 mm-1, F(000) = 1104, T = 298(2) K, R = 0.0524, wR = 0.1246 for 8916 reflections with I > 2s(I). In the molecular structure unit, Zn(II) cation is coordinated by six N atoms.

Keywords

Zn(II) complex Hydrothermal synthesis Crystal structure
Wang, L., Bi, J.-H., & Dong, H.-Z. (2015). Hydrothermal Synthesis and Structure of Zn(II) Thiocyanate Complex of Phenanthroline. Asian Journal of Chemistry, 27(4), 1563–1564. https://doi.org/10.14233/ajchem.2015.17752
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References
  1. Z.B. Cai, L.F. Liu and M. Zhou, Opt. Mater., 35, 1481 (2013); doi:10.1016/j.optmat.2013.03.009.
  2. H.Z. Xie, S.J. Huang, J. Zhou, S.P. Yu and D.Y. Wei, Transition Met. Chem., 35, 773 (2010); doi:10.1007/s11243-010-9392-8.
  3. R. Boobalan, G.H. Lee and C.P. Chen, Adv. Synth. Catal., 354, 2511 (2012); doi:10.1002/adsc.201200337.
  4. I. Warad, B. Hammouti, T.B. Hadda, A. Boshaala and S.F. Haddad, Res. Chem. Intermed., 39, 4011 (2013); doi:10.1007/s11164-012-0917-y.
  5. B.B. Xu, P. Shi, Q.Y. Guan, X. Shi and G.L. Zhao, J. Coord. Chem., 66, 2605 (2013); doi:10.1080/00958972.2013.811497.
  6. J.H. Bi, H.F. Wang, Z.X. Huang, W.T. Bi and N.L. Hu, Asian J. Chem., 20, 4966 (2008).
  7. H.Z. Dong, W.B. Tao, J.H. Bi, V. Milway, Z.Q. Xu, S.Y. Zhang, X.C. Meng, W.T. Bi, J. Li and M. Li, Nanoscale Res. Lett., 6, 484 (2011); doi:10.1186/1556-276X-6-484.
  8. J.H. Bi and H.Z. Dong, Asian J. Chem., 25, 8241 (2013).
  9. J.H. Bi, B.Z. Li, Z.X. Huang and J. Li, Asian J. Chem., 22, 7443 (2010).
  10. J.H. Bi, W.T. Bi, Z.X. Huang and N.L. Hu, Asian J. Chem., 21, 6622 (2009).
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