Synthesis and Potency Study of Some Dibutyltin(IV) Dinitrobenzoate Compounds as Corrosion Inhibitor for Mild Steel HRP in DMSO-HCl Solution

Sutopo Hadi; Hapin Afriyani; Wynda D. Anggraini; Hardoko I. Qudus; Tati Suhartati

doi:10.14233/ajchem.2015.18590

Issue

Vol. 27 No. 4 (2015): Vol 27 Issue 4

Issue Published : February 4, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Potency Study of Some Dibutyltin(IV) Dinitrobenzoate Compounds as Corrosion Inhibitor for Mild Steel HRP in DMSO-HCl Solution

https://doi.org/10.14233/ajchem.2015.18590

Sutopo Hadi

Department of Chemistry, University of Lampung, Bandar Lampung 35145, Indonesia

Hapin Afriyani

Department of Chemistry, University of Lampung, Bandar Lampung 35145, Indonesia

Wynda D. Anggraini

Department of Chemistry, University of Lampung, Bandar Lampung 35145, Indonesia

Hardoko I. Qudus

Department of Chemistry, University of Lampung, Bandar Lampung 35145, Indonesia

Tati Suhartati

Department of Chemistry, University of Lampung, Bandar Lampung 35145, Indonesia

Corresponding Author(s) : Sutopo Hadi

sutopo.hadi@fmipa.unila.ac.id

Asian Journal of Chemistry, Vol. 27 No. 4 (2015): Vol 27 Issue 4
Article Published : February 4, 2015

Abstract

Following our succes in the synthesis of some derivatives of organotin(IV) carboxylates, in this work we reported the corrosion inhibitor study of three dibutyltin(IV) compounds using ligands of 2-, 3- and 4-nitrobenzoic acid. All the three synthesized compounds were characterized by spectroscopy techniques and also based on the microanalytical and physical data. The corrosion inhibition was evaluated with potentiodynamic polarization technique using ER644 Integrated Potentiostat eDAQ type on mild steel hot rolled plate (HRP) in DMSO-HCl solution. The results indicated that the these compounds showed interesting inhibition activity with percentage of inhibition efficiency (% IE) of 59.3, 60.5 and 61.2 % for dibutyltin(IV) 2-nitrobenzoate, 3-nitrobenzoate and 4-nitrobenzoate, respectively. These three dibutyltin(IV) compounds have been shown promising to be potentially used as anticorrosion inhibitors.

Keywords

Inhibitor Corrosion Dibutyltin(IV) dinitrobenzoate Hot rolled plate mild steel

Hadi, S., Afriyani, H., D. Anggraini, W., I. Qudus, H., & Suhartati, T. (2015). Synthesis and Potency Study of Some Dibutyltin(IV) Dinitrobenzoate Compounds as Corrosion Inhibitor for Mild Steel HRP in DMSO-HCl Solution. Asian Journal of Chemistry, 27(4), 1509–1512. https://doi.org/10.14233/ajchem.2015.18590

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References

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References

E.R.T. Tiekink, Appl. Organomet. Chem., 5, 1 (1991); doi:10.1002/aoc.590050102.

K. Shahid, S. Ali, S. Shahzadi and Z. Akhtar, Turk. J. Chem., 27, 209 (2003).

L. Pellerito and L. Nagy, Coord. Chem. Rev., 224, 111 (2002); doi:10.1016/S0010-8545(01)00399-X.

J.J. Bonire, G.A. Ayoko, P.F. Olurinola, J.O. Ehinmidu, N.S.N. Jalil and A.A. Omachi, Met. Based Drugs, 5, 233 (1998); doi:10.1155/MBD.1998.233.

M. Gielen, J. Braz. Chem. Soc., 14, 870 (2003); doi:10.1590/S0103-50532003000600003.

A. Szorcsik, L. Nagy, K. Gajda-Schrantz, L. Pellerito, E. Nagy and F.T. Edelmann, J. Radioanal. Nucl. Chem., 252, 523 (2002); doi:10.1023/A:1015802820423.

B. Gleeson, J. Claffey, D. Ertler, M. Hogan, H. Müller-Bunz, F. Paradisi, D. Wallis and M. Tacke, Polyhedron, 27, 3619 (2008); doi:10.1016/j.poly.2008.09.009.

W. Rehman, A. Badshah, S. Khan and L.T.A. Tuyet, Eur. J. Med. Chem., 44, 3981 (2009); doi:10.1016/j.ejmech.2009.04.027.

Y. Li, Y. Li, Y. Niu, L. Jie, X. Shang, J. Guo and Q. Li, J. Inorg. Biochem., 102, 1731 (2008); doi:10.1016/j.jinorgbio.2008.05.002.

S. Hadi and M. Rilyanti, Orient. J. Chem., 26, 775 (2010).

S. Hadi, M. Rilyanti and Suharso, Indo. J. Chem., 12, 172 (2012).

S. Hadi, B. Irawan and J. Efri, Appl. Sci. Res., 4, 1521 (2008).

S. Hadi, M. Rilyanti and Nurhasanah, Modern Appl. Sci.,3, 12 (2009).

C. Hansch and R.P. Verma, Eur. J. Med. Chem., 44, 260 (2009); doi:10.1016/j.ejmech.2008.02.040.

R.B. Rastogi, M.M. Singh, K. Singh and M. Yadav, Port. Electrochim. Acta, 23, 315 (2005); doi:10.4152/pea.200502315.

R. Singh, P. Chaudhary and N.K. Kaushik, Rev. Inorg. Chem., 30, 275 (2010); doi:10.1515/REVIC.2010.30.4.275.

R.B. Rastogi, M.M. Singh, K. Singh and M. Yadav, Afr. J. Pure Appl. Chem., 5, 19 (2011).

U.R. Evans, Oxidation and Corrosion of Metals, Arnold, London, edn. 3 (1968).

M. Nath, R. Yadav, M. Gielen, H. Dalil, D. de Vos and G. Eng, Appl. Organomet. Chem., 11, 727 (1997); doi:10.1002/(SICI)1099-0739(199709)11:9<727::AID-AOC639>3.0.CO;2-X.

Sudjadi, The Structure Determination of Organic Compounds, Ghalia Publishers (1985) (In Indonesian).

Z.H. Chohan and A. Rauf, Synth. React. Inorg. Met.-Org. Chem., 26, 591 (1996); doi:10.1080/00945719608004764.

H. Gershon, J. Med. Chem., 17, 824 (1974); doi:10.1021/jm00254a009.

A.J. Crowe, in ed.: M. Gielne, The Antitumour Activity of Tin Compounds, Metal-Based Drugs, Freund Publishing House, vol. 1, p. 103 (1989).

M.G. Fontana, Corrosion Engineering, McGraw Hill Book Company, Singapore, edn. 3 (1986).

Issue

Vol. 27 No. 4 (2015): Vol 27 Issue 4

Synthesis and Potency Study of Some Dibutyltin(IV) Dinitrobenzoate Compounds as Corrosion Inhibitor for Mild Steel HRP in DMSO-HCl Solution

Corresponding Author(s) : Sutopo Hadi

Abstract

Keywords

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