Synthesis and Characterization of Novel Nitride Phosphors Ca5Si2N6: Eu2+/Ce3+

Jinzhao Huang; Tao Jiang; Nannan Yao; Honglin Li; Xijin Xu

doi:10.14233/ajchem.2015.17668

Issue

Vol. 27 No. 3 (2015): Vol 27 Issue 3

Issue Published : January 19, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Novel Nitride Phosphors Ca5Si2N6: Eu2+/Ce3+

https://doi.org/10.14233/ajchem.2015.17668

Jinzhao Huang

School of Physics and Technology, University of Jinan, Jinan 250022, Shandong Province, P.R. China

Tao Jiang

School of Physics and Technology, University of Jinan, Jinan 250022, Shandong Province, P.R. China

Nannan Yao

School of Physics and Technology, University of Jinan, Jinan 250022, Shandong Province, P.R. China

Honglin Li

School of Physics and Technology, University of Jinan, Jinan 250022, Shandong Province, P.R. China

Xijin Xu

School of Physics and Technology, University of Jinan, Jinan 250022, Shandong Province, P.R. China

Corresponding Author(s) : Jinzhao Huang

jzhuangjz@hotmail.com

Asian Journal of Chemistry, Vol. 27 No. 3 (2015): Vol 27 Issue 3
Article Published : January 18, 2015

Abstract

The novel nitride phosphor Ca₅Si₂N₆: Eu²⁺/Ce³⁺ were successfully synthesized at 1450 °C via a solid-state reaction method under a nitrogen atmosphere. The photoluminescence of Ca₅Si₂N₆: Eu²⁺/Ce³⁺ shows that the phosphors have the main emission peak at 609 and 470 nm, respectively. The phosphor Ca₅Si₂N₆: Eu²⁺ can be excited in the range from 350 to 480 nm, which makes it the attractive candidate phosphors for the application in phosphor-converted light-emitting diodes as red phosphors. The Ca₅Si₂N₆:Ce³⁺ can be effectively excited by near ultraviolet. Moreover, the effect of doping concentration on the luminescence property is investigated.

Keywords

Silicon oxynitride Phosphors Photoluminescence Energy transfer

Huang, J., Jiang, T., Yao, N., Li, H., & Xu, X. (2015). Synthesis and Characterization of Novel Nitride Phosphors Ca5Si2N6: Eu2+/Ce3+. Asian Journal of Chemistry, 27(3), 938–940. https://doi.org/10.14233/ajchem.2015.17668

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C.Y. Liu, Z.G. Xia, Z.P. Lian, J. Zhou and Q.F. Yan, J. Mater. Chem. C, 1, 7139 (2013); doi:10.1039/c3tc31423e.

X. Zhang, Z. Zhao, X. Zhang, A. Marathe, D.B. Cordes, B. Weeks and J. Chaudhuri, J. Mater. Chem. C, 1, 7202 (2013); doi:10.1039/c3tc31200c.

R.J. Xie and N. Hirosaki, Sci. Technol. Adv. Mater., 8, 588 (2007); doi:10.1016/j.stam.2007.08.005.

S. F.X. Ye, F. Xiao, Y.X. Pan, Y.Y. Ma and Q.Y. Zhang, Mater. Sci. Eng. Rep., 71, 1 (2010); doi:10.1016/j.mser.2010.07.001.

P.F. Smet, K. Van den Eeckhout, A.J.J. Bos, E. van der Kolk and P. Dorenbos, J. Lumin., 132, 682 (2012); doi:10.1016/j.jlumin.2011.10.022.

J.Y. Tang, C. Zhan, L.X. Yang, L.Y. Hao, X. Xu and A. Simeon, Mater. Chem. Phys., 132, 1089 (2012); doi:10.1016/j.matchemphys.2011.12.073.

T. Suehiro, N. Hirosaki and R.-J. Xie, ACS Appl. Mater. Interfaces, 3, 811 (2011); doi:10.1021/am101160e.

M. Seibald, T. Rosenthal, O. Oeckler, C. Maak, A. Tücks, P.J. Schmidt, D. Wiechert and W. Schnick, Chem. Mater., 25, 1852 (2013); doi:10.1021/cm400461v.

X.F. Song, H. He, R.L. Fu, D.L. Wang, X.R. Zhao and Z.W. Pan, J. Phys. D Appl. Phys., 42, 065409 (2009); doi:10.1088/0022-3727/42/6/065409.

Y.A. Zhang, X.T. Liu, B.F. Lei, H.E. Wang and Q.M. Sun, Energy Procedia, 16, 391 (2012); doi:10.1016/j.egypro.2012.01.064.

Y. Fang, Y.Q. Li, R.J. Xie, N. Hirosaki, T. Takade, X.Y. Li and T. Qiu, J. Solid State Chem., 184, 1405 (2011); doi:10.1016/j.jssc.2011.03.048.

K.Y. Jung and J.H. Seo, Electrochem. Solid. State, 11, J64 (2008); doi:10.1149/1.2917584.

J.K. Park, J.M. Kim, E.S. Oh and C.H. Kim, Electrochem. Solid. State, 8, H6 (2005); doi:10.1149/1.1836113.

H.A. Hoppe, H. Lutz, P. Morys, W. Schnick and A. Seilmeier, J. Phys. Chem. Solids, 61, 2001 (2000); doi:10.1016/S0022-3697(00)00194-3.

Y. Kaneko and T. Koda, J. Cryst. Growth, 86, 72 (1990); doi:10.1016/0022-0248(90)90701-L.

Y.Q. Li, N. Hirosaki, R.J. Xie, T. Takeda and M. Mitomo, Chem. Mater., 20, 6704 (2008); doi:10.1021/cm801669x.

C.J. Duan, X.J. Wang, W.M. Otten, A.C.A. Delsing, J.T. Zhao and H.T. Hintzen, Chem. Mater., 20, 1597 (2008); doi:10.1021/cm701875e.

Issue

Vol. 27 No. 3 (2015): Vol 27 Issue 3

Synthesis and Characterization of Novel Nitride Phosphors Ca5Si2N6: Eu2+/Ce3+

Corresponding Author(s) : Jinzhao Huang

Abstract

Keywords

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