Novel Method for Fabrication of Super-Hydrophobic Film on Magnesium Alloy and Consequent Anticorrosion Performance

Liyuan Min; Runhu Zhang

doi:10.14233/ajchem.2015.17385

Issue

Vol. 27 No. 3 (2015): Vol 27 Issue 3

Issue Published : January 19, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Novel Method for Fabrication of Super-Hydrophobic Film on Magnesium Alloy and Consequent Anticorrosion Performance

https://doi.org/10.14233/ajchem.2015.17385

Liyuan Min

Department of Chemical Engineering, Kunming Metallurgy College, Kunming 650033, P.R. China

Runhu Zhang

Department of Chemical Engineering, Kunming Metallurgy College, Kunming 650033, P.R. China

Corresponding Author(s) : Liyuan Min

minliyuan_kmc@163.com

Asian Journal of Chemistry, Vol. 27 No. 3 (2015): Vol 27 Issue 3
Article Published : January 18, 2015

Abstract

A novel two-step dipping method has been proposed to fabricate super-hydrophobic film on magnesium alloy with hexamethylene-diisocyanate trimer (HDI trimer) and laurylamine. With this method, super-hydrophobic film, which is composed of HDI trimer-laurylamine biuret, can be fabricated on metal surface within 10 sec. The film morphologies and chemical compositions were investigated using scanning electron microscope and Fourier-transform infrared spectrophotometer. It is shown that rough micro-structure and low surface energy of biuret film confer super-hydrophobicity of resultant film. The concentrations of HDI trimer and laurylamine are investigated to determine their effects on wettability of film. Furthermore, the anticorrosion performance and mechanism of super-hydrophobic film to magnesium alloy in 3.5 % NaCl solution are studied with electrochemical measurements. It is proven that super-hydrophobic film can protect underlying magnesium alloy effectively and the air trapped in film is the main contributor for the barrier performance.

Keywords

Super-hydrophobic film Magnesium alloy Corrosion protection Polarization curve

Min, L., & Zhang, R. (2015). Novel Method for Fabrication of Super-Hydrophobic Film on Magnesium Alloy and Consequent Anticorrosion Performance. Asian Journal of Chemistry, 27(3), 889–894. https://doi.org/10.14233/ajchem.2015.17385

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References

Z. Wang, Q. Li, Z. She, F. Chen, L. Li, X. Zhang and P. Zhang, Appl. Surf. Sci., 271, 182 (2013); doi:10.1016/j.apsusc.2013.01.158.
X. Lu, Y. Zuo, X. Zhao, Y. Tang and X. Feng, Corros. Sci., 53, 153 (2011); doi:10.1016/j.corsci.2010.09.008.
A. Abdal-hay, M. Dewidar and J.K. Lim, Appl. Surf. Sci., 261, 536 (2012); doi:10.1016/j.apsusc.2012.08.051.
X. Ye, S. Cai, Y. Dou, G. Xu, K. Huang, M. Ren and X. Wang, Appl. Surf. Sci., 259, 799 (2012); doi:10.1016/j.apsusc.2012.07.127.
Y. Chen, B.L. Luan, G.L. Song, Q. Yang, D.M. Kingston and F. Bensebaa, Surf. Coat. Technol., 210, 156 (2012); doi:10.1016/j.surfcoat.2012.09.009.
G.L. Song, Electrochim. Acta, 55, 2258 (2010); doi:10.1016/j.electacta.2009.11.078.
A. Pardo, S. Merino, M.C. Merino, I. Barroso, M. Mohedano, R. Arrabal and F. Viejo, Corros. Sci., 51, 841 (2009); doi:10.1016/j.corsci.2009.01.024.
Y. Zhang, Y. Shao, T. Zhang, G. Meng and F. Wang, Prog. Org. Coat., 76, 804 (2013); doi:10.1016/j.porgcoat.2013.01.008.
H. Wang, R. Akid and M. Gobara, Corros. Sci., 52, 2565 (2010); doi:10.1016/j.corsci.2010.04.002.
A.S. Hamdy and D.P. Butt, Electrochim. Acta, 108, 852 (2013); doi:10.1016/j.electacta.2013.07.043.
Y. Zhao, M.I. Jamesh, W.K. Li, G. Wu, C. Wang, Y. Zheng, K.W.K. Yeung and P.K. Chu, Acta Biomater., 10, 544 (2014); doi:10.1016/j.actbio.2013.10.012.
T. Ishizaki, Y. Masuda and K. Teshima, Surf. Coat. Technol., 217, 76 (2013); doi:10.1016/j.surfcoat.2012.11.076.
F. Brusciotti, D.V. Snihirova, H. Xue, M.F. Montemor, S.V. Lamaka and M.G.S. Ferreira, Corros. Sci., 67, 82 (2013); doi:10.1016/j.corsci.2012.10.013.
X. Guo, K. Du, Q. Guo, Y. Wang, F. Wang and F. Wang, Corros. Sci., 76, 129 (2013); doi:10.1016/j.corsci.2013.06.036.
I.A. Kartsonakis, A.C. Balaskas, E.P. Koumoulos, C.A. Charitidis and G. Kordas, Corros. Sci., 65, 481 (2012); doi:10.1016/j.corsci.2012.08.052.
R. Qiu, D. Zhang and P. Wang, Corros. Sci., 66, 350 (2013); doi:10.1016/j.corsci.2012.09.041.
P. Wang, D. Zhang, R. Qiu and B. Hou, Corros. Sci., 53, 2080 (2011); doi:10.1016/j.corsci.2011.02.025.
P. Wang, D. Zhang, R. Qiu, J. Wu and Y. Wan, Corros. Sci., 69, 23 (2013); doi:10.1016/j.corsci.2012.10.025.
X. Feng, L. Feng, M. Jin, J. Zhai, L. Jiang and D. Zhu, J. Am. Chem. Soc., 126, 62 (2004); doi:10.1021/ja038636o.
T. Sun, G. Wang, L. Feng, B. Liu, Y. Ma, L. Jiang and D. Zhu, Angew. Chem. Int. Ed., 43, 357 (2004); doi:10.1002/anie.200352565.
M.E. Yazdanshenas and M. Shateri-Khalilabad, Ind. Eng. Chem. Res., 52, 12846 (2013); doi:10.1021/ie401133q.
H.J. Choi, S. Choo, J.H. Shin, K.I. Kim and H. Lee, J. Phys. Chem. C, 117, 24354 (2013); doi:10.1021/jp4070399.
S.G. Lee, D.S. Ham, D.Y. Lee, H. Bong and K. Cho, Langmuir, 29, 15051 (2013); doi:10.1021/la404005b.
J. Ou, W. Hu, M. Xue, F. Wang and W. Li, ACS Appl. Mater. Interfaces, 5, 3101 (2013); doi:10.1021/am4000134.
G. Fonder, F. Laffineur, J. Delhalle and Z. Mekhalif, J. Colloid Interf. Sci., 326, 333 (2008); doi:10.1016/j.jcis.2008.06.038.
M.W. Tsao, J.F. Rabolt, H. Schönherr and D.G. Castner, Langmuir, 16, 1734 (2000); doi:10.1021/la9906931.
X.J. Feng and L. Jiang, Adv. Mater., 18, 3063 (2006); doi:10.1002/adma.200501961.
P. Wang, R. Qiu, D. Zhang, Z. Lin and B. Hou, Electrochim. Acta, 56, 517 (2010); doi:10.1016/j.electacta.2010.09.017.
M. Schem, T. Schmidt, J. Gerwann, M. Wittmar, M. Veith, G.E. Thompson, I.S. Molchan, T. Hashimoto, P. Skeldon, A.R. Phani, S. Santucci and M.L. Zheludkevich, Corros. Sci., 51, 2304 (2009); doi:10.1016/j.corsci.2009.06.007.
Z. Cui, Q. Wang, Y. Xiao, C. Su and Q. Chen, Appl. Surf. Sci., 254, 2911 (2008); doi:10.1016/j.apsusc.2007.09.062.
X.F. Gao, X. Yao and L. Jiang, Langmuir, 23, 4886 (2007); doi:10.1021/la0630357.
P. Wang, D. Zhang and R. Qiu, Corros. Sci., 54, 77 (2012); doi:10.1016/j.corsci.2011.08.050.

References

Z. Wang, Q. Li, Z. She, F. Chen, L. Li, X. Zhang and P. Zhang, Appl. Surf. Sci., 271, 182 (2013); doi:10.1016/j.apsusc.2013.01.158.

X. Lu, Y. Zuo, X. Zhao, Y. Tang and X. Feng, Corros. Sci., 53, 153 (2011); doi:10.1016/j.corsci.2010.09.008.

A. Abdal-hay, M. Dewidar and J.K. Lim, Appl. Surf. Sci., 261, 536 (2012); doi:10.1016/j.apsusc.2012.08.051.

X. Ye, S. Cai, Y. Dou, G. Xu, K. Huang, M. Ren and X. Wang, Appl. Surf. Sci., 259, 799 (2012); doi:10.1016/j.apsusc.2012.07.127.

Y. Chen, B.L. Luan, G.L. Song, Q. Yang, D.M. Kingston and F. Bensebaa, Surf. Coat. Technol., 210, 156 (2012); doi:10.1016/j.surfcoat.2012.09.009.

G.L. Song, Electrochim. Acta, 55, 2258 (2010); doi:10.1016/j.electacta.2009.11.078.

A. Pardo, S. Merino, M.C. Merino, I. Barroso, M. Mohedano, R. Arrabal and F. Viejo, Corros. Sci., 51, 841 (2009); doi:10.1016/j.corsci.2009.01.024.

Y. Zhang, Y. Shao, T. Zhang, G. Meng and F. Wang, Prog. Org. Coat., 76, 804 (2013); doi:10.1016/j.porgcoat.2013.01.008.

H. Wang, R. Akid and M. Gobara, Corros. Sci., 52, 2565 (2010); doi:10.1016/j.corsci.2010.04.002.

A.S. Hamdy and D.P. Butt, Electrochim. Acta, 108, 852 (2013); doi:10.1016/j.electacta.2013.07.043.

Y. Zhao, M.I. Jamesh, W.K. Li, G. Wu, C. Wang, Y. Zheng, K.W.K. Yeung and P.K. Chu, Acta Biomater., 10, 544 (2014); doi:10.1016/j.actbio.2013.10.012.

T. Ishizaki, Y. Masuda and K. Teshima, Surf. Coat. Technol., 217, 76 (2013); doi:10.1016/j.surfcoat.2012.11.076.

F. Brusciotti, D.V. Snihirova, H. Xue, M.F. Montemor, S.V. Lamaka and M.G.S. Ferreira, Corros. Sci., 67, 82 (2013); doi:10.1016/j.corsci.2012.10.013.

X. Guo, K. Du, Q. Guo, Y. Wang, F. Wang and F. Wang, Corros. Sci., 76, 129 (2013); doi:10.1016/j.corsci.2013.06.036.

I.A. Kartsonakis, A.C. Balaskas, E.P. Koumoulos, C.A. Charitidis and G. Kordas, Corros. Sci., 65, 481 (2012); doi:10.1016/j.corsci.2012.08.052.

R. Qiu, D. Zhang and P. Wang, Corros. Sci., 66, 350 (2013); doi:10.1016/j.corsci.2012.09.041.

P. Wang, D. Zhang, R. Qiu and B. Hou, Corros. Sci., 53, 2080 (2011); doi:10.1016/j.corsci.2011.02.025.

P. Wang, D. Zhang, R. Qiu, J. Wu and Y. Wan, Corros. Sci., 69, 23 (2013); doi:10.1016/j.corsci.2012.10.025.

X. Feng, L. Feng, M. Jin, J. Zhai, L. Jiang and D. Zhu, J. Am. Chem. Soc., 126, 62 (2004); doi:10.1021/ja038636o.

T. Sun, G. Wang, L. Feng, B. Liu, Y. Ma, L. Jiang and D. Zhu, Angew. Chem. Int. Ed., 43, 357 (2004); doi:10.1002/anie.200352565.

M.E. Yazdanshenas and M. Shateri-Khalilabad, Ind. Eng. Chem. Res., 52, 12846 (2013); doi:10.1021/ie401133q.

H.J. Choi, S. Choo, J.H. Shin, K.I. Kim and H. Lee, J. Phys. Chem. C, 117, 24354 (2013); doi:10.1021/jp4070399.

S.G. Lee, D.S. Ham, D.Y. Lee, H. Bong and K. Cho, Langmuir, 29, 15051 (2013); doi:10.1021/la404005b.

J. Ou, W. Hu, M. Xue, F. Wang and W. Li, ACS Appl. Mater. Interfaces, 5, 3101 (2013); doi:10.1021/am4000134.

G. Fonder, F. Laffineur, J. Delhalle and Z. Mekhalif, J. Colloid Interf. Sci., 326, 333 (2008); doi:10.1016/j.jcis.2008.06.038.

M.W. Tsao, J.F. Rabolt, H. Schönherr and D.G. Castner, Langmuir, 16, 1734 (2000); doi:10.1021/la9906931.

X.J. Feng and L. Jiang, Adv. Mater., 18, 3063 (2006); doi:10.1002/adma.200501961.

P. Wang, R. Qiu, D. Zhang, Z. Lin and B. Hou, Electrochim. Acta, 56, 517 (2010); doi:10.1016/j.electacta.2010.09.017.

M. Schem, T. Schmidt, J. Gerwann, M. Wittmar, M. Veith, G.E. Thompson, I.S. Molchan, T. Hashimoto, P. Skeldon, A.R. Phani, S. Santucci and M.L. Zheludkevich, Corros. Sci., 51, 2304 (2009); doi:10.1016/j.corsci.2009.06.007.

Z. Cui, Q. Wang, Y. Xiao, C. Su and Q. Chen, Appl. Surf. Sci., 254, 2911 (2008); doi:10.1016/j.apsusc.2007.09.062.

X.F. Gao, X. Yao and L. Jiang, Langmuir, 23, 4886 (2007); doi:10.1021/la0630357.

P. Wang, D. Zhang and R. Qiu, Corros. Sci., 54, 77 (2012); doi:10.1016/j.corsci.2011.08.050.

Issue

Vol. 27 No. 3 (2015): Vol 27 Issue 3

Novel Method for Fabrication of Super-Hydrophobic Film on Magnesium Alloy and Consequent Anticorrosion Performance

Corresponding Author(s) : Liyuan Min

Abstract

Keywords

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