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Tribological Properties of Layered a-Zirconium Phosphate as Lithium Grease Additive
Corresponding Author(s) : Hong Xu
Asian Journal of Chemistry,
Vol. 27 No. 3 (2015): Vol 27 Issue 3
Abstract
Layered a-zirconium phosphate [a-Zr(HPO4)2·H2O, hereafter referred to as a-ZrP] with high crystallinity, uniform diameter and regular morphological forms was synthesized in a mild NaF-ZrO-P2O5-H2O system under hydrothermal conditions. The four-ball test results indicated that the anti-wear, load-carrying and friction reduction capacity of lithium grease were significantly improved with the addition of a-zirconium phosphate. It was also observed that a-zirconium phosphate displayed a better lubricating property than MoS2. The SEM and EDS results indicated that a protective film that was composed of Zr, P, Fe, Cr, O and C formed on the rubbing surface.
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- O. Tevet, P. Von-Huth, R. Popovitz-Biro, R. Rosentsveig, H.D. Wagner and R. Tenne, Proc. Natl. Acad. Sci. USA, 108, 19901 (2011); doi:10.1073/pnas.1106553108.
- R. Tenne, L. Rapoport, Y. Bilik, Y. Feldman, M. Homyonfer and S.R. Cohen, Nature, 387, 791 (1997); doi:10.1038/42910.
- W.O. Winer, Wear, 10, 422 (1967); doi:10.1016/0043-1648(67)90187-1.
- A. Mesgarnejad and M.M. Khonsari, Wear, 269, 547 (2010); doi:10.1016/j.wear.2010.05.010.
- P.J. Bryant, P.L. Gutshall and L.H. Taylor, Wear, 7, 118 (1964); doi:10.1016/0043-1648(64)90083-3.
- Y. Liao, R. Pourzal, M.A. Wimmer, J.J. Jacobs, A. Fischer and L.D. Marks, Science, 334, 1687 (2011); doi:10.1126/science.1213902.
- H.L. Yu, Y. Xu, P.J. Shi, H.M. Wang, Y. Zhao, B.S. Xu and Z.M. Bai, Tribol. Int., 43, 667 (2010); doi:10.1016/j.triboint.2009.10.006.
- 8 B. Zhang, Y. Xu, F. Gao, P. Shi, B. Xu and Y. Wu, Appl. Surf. Sci., 257, 2540 (2011); doi:10.1016/j.apsusc.2010.10.019 .
- L.R. Rudnick, Lubricant Additives-Chemistry and Applications, CRC Press; Boca Raton, FL, edn 2, pp. 173-194 (2009).
- A. Clearfield and G.D. Smith, Inorg. Chem., 8, 431 (1969); doi:10.1021/ic50073a005.
- J.M. Troup and A. Clearfield, Inorg. Chem., 16, 3311 (1977); doi:10.1021/ic50178a065.
- A. Clearfield, Dalton Trans., 44, 6089 (2008); doi:10.1039/b807676f.
- L. Liu, Z. Chen, H. Wei, Y. Li, Y. Fu, H. Xu, J. Li, A.M.Z. Slawin and J. Dong, Inorg. Chem., 49, 8270 (2010); doi:10.1021/ic100657a.
- Z. Chen, X. Zhang, H. Xu, J. Li and J. Dong, Tribol. Lett., 43, 197 (2011); doi:10.1007/s11249-011-9801-y.
- A. Clearfield and J.A. Stynes, J. Inorg. Nucl. Chem., 26, 117 (1964); doi:10.1016/0022-1902(64)80238-4.
- G. Alberti and E. Torracca, J. Inorg. Nucl. Chem., 30, 317 (1968); doi:10.1016/0022-1902(68)80096-X.
- W. Kraus and G. Nolze, Federal Institute for Materials Research and Testing, Rudower Chaussee 5, 12489, Berlin, Germany (2000).
- S. Wen and P. Huang. Principle of Tribology, Tsinghua University Press: Beijing, edn 2, p 2-4 (2002).
References
O. Tevet, P. Von-Huth, R. Popovitz-Biro, R. Rosentsveig, H.D. Wagner and R. Tenne, Proc. Natl. Acad. Sci. USA, 108, 19901 (2011); doi:10.1073/pnas.1106553108.
R. Tenne, L. Rapoport, Y. Bilik, Y. Feldman, M. Homyonfer and S.R. Cohen, Nature, 387, 791 (1997); doi:10.1038/42910.
W.O. Winer, Wear, 10, 422 (1967); doi:10.1016/0043-1648(67)90187-1.
A. Mesgarnejad and M.M. Khonsari, Wear, 269, 547 (2010); doi:10.1016/j.wear.2010.05.010.
P.J. Bryant, P.L. Gutshall and L.H. Taylor, Wear, 7, 118 (1964); doi:10.1016/0043-1648(64)90083-3.
Y. Liao, R. Pourzal, M.A. Wimmer, J.J. Jacobs, A. Fischer and L.D. Marks, Science, 334, 1687 (2011); doi:10.1126/science.1213902.
H.L. Yu, Y. Xu, P.J. Shi, H.M. Wang, Y. Zhao, B.S. Xu and Z.M. Bai, Tribol. Int., 43, 667 (2010); doi:10.1016/j.triboint.2009.10.006.
8 B. Zhang, Y. Xu, F. Gao, P. Shi, B. Xu and Y. Wu, Appl. Surf. Sci., 257, 2540 (2011); doi:10.1016/j.apsusc.2010.10.019 .
L.R. Rudnick, Lubricant Additives-Chemistry and Applications, CRC Press; Boca Raton, FL, edn 2, pp. 173-194 (2009).
A. Clearfield and G.D. Smith, Inorg. Chem., 8, 431 (1969); doi:10.1021/ic50073a005.
J.M. Troup and A. Clearfield, Inorg. Chem., 16, 3311 (1977); doi:10.1021/ic50178a065.
A. Clearfield, Dalton Trans., 44, 6089 (2008); doi:10.1039/b807676f.
L. Liu, Z. Chen, H. Wei, Y. Li, Y. Fu, H. Xu, J. Li, A.M.Z. Slawin and J. Dong, Inorg. Chem., 49, 8270 (2010); doi:10.1021/ic100657a.
Z. Chen, X. Zhang, H. Xu, J. Li and J. Dong, Tribol. Lett., 43, 197 (2011); doi:10.1007/s11249-011-9801-y.
A. Clearfield and J.A. Stynes, J. Inorg. Nucl. Chem., 26, 117 (1964); doi:10.1016/0022-1902(64)80238-4.
G. Alberti and E. Torracca, J. Inorg. Nucl. Chem., 30, 317 (1968); doi:10.1016/0022-1902(68)80096-X.
W. Kraus and G. Nolze, Federal Institute for Materials Research and Testing, Rudower Chaussee 5, 12489, Berlin, Germany (2000).
S. Wen and P. Huang. Principle of Tribology, Tsinghua University Press: Beijing, edn 2, p 2-4 (2002).