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Vol. 27 No. 3 (2015): Vol 27 Issue 3

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Synthesis of Template-Free ZSM-5 Catalysis for Cyclohexene Hydration

https://doi.org/10.14233/ajchem.2015.17852
Baohe Wang
Key Laboratory for Green Chemical Technology of Ministry of Education, Research and Development Center of Petrochemical Technology, Tianjin University, Tianjin 300072, P.R. China
Jinxue He
Key Laboratory for Green Chemical Technology of Ministry of Education, Research and Development Center of Petrochemical Technology, Tianjin University, Tianjin 300072, P.R. China
Shuang Chen
Key Laboratory for Green Chemical Technology of Ministry of Education, Research and Development Center of Petrochemical Technology, Tianjin University, Tianjin 300072, P.R. China
Jing Zhu
Key Laboratory for Green Chemical Technology of Ministry of Education, Research and Development Center of Petrochemical Technology, Tianjin University, Tianjin 300072, P.R. China
Hao Sun
Key Laboratory for Green Chemical Technology of Ministry of Education, Research and Development Center of Petrochemical Technology, Tianjin University, Tianjin 300072, P.R. China

Corresponding Author(s) : Jinxue He

Asian Journal of Chemistry, Vol. 27 No. 3 (2015): Vol 27 Issue 3

Abstract

Template-free ZSM-5 zeolites were synthesized in the tetraethyl orthosilicate, sodium metasilicate and silica sol systems, respectively. Moreover, detailed analysis on the two different synthesis routes with sodium metasilicate as silica source were carried out. Catalytic performance in the cyclohexene hydration reaction was also investigated. The crystallinity, particle size, surface area and acidity varied of products were characterized by X-ray powder diffraction, scanning electron microscope, nitrogen adsorption, Fourier transform infrared spectroscopy, temperature-programmed desorption of ammonia (NH3-TRD) and thermogravimetric. Remarkable performance in the cyclohexene hydration reaction can be attained by using Na2SiO3 as silica source. It was shown that the improved Na2SiO3 synthesis route is the most suitable for synthesis of ZSM-5 catalysts.

Keywords

ZSM-5 Silica source Synthesis route Template-free Cyclohexene
Wang, B., He, J., Chen, S., Zhu, J., & Sun, H. (2015). Synthesis of Template-Free ZSM-5 Catalysis for Cyclohexene Hydration. Asian Journal of Chemistry, 27(3), 995–1000. https://doi.org/10.14233/ajchem.2015.17852
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