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Vol. 27 No. 3 (2015): Vol 27 Issue 3

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(4,4'-H2bipy)4[Cu(4,4'-Hbipy)2(4,4'-bipy)(P2W18O62)2]·7H2O: A New Supramolecular Hybrid Based on 1D Cu-N Coordination Polymeric Chain and Wells-Dawson Type Polyoxometelate

https://doi.org/10.14233/ajchem.2015.18000
Rui-Lian Lin
College of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, P.R. China
Wen-Qi Sun
College of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, P.R. China
Jing-Xin Liu
College of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, P.R. China
Xiang-Feng Chu
College of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, P.R. China

Corresponding Author(s) : Wen-Qi Sun

sunwenqi@ahut.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 3 (2015): Vol 27 Issue 3

Abstract

The hydrothermal reaction of CuCl2·2H2O with K6P2W18O62·15H2O and 4,4'-bipyridine (4,4'-bipy) gave a novel inorganic-organic hybrid (4,4'-H2bipy)4[Cu(4,4'-Hbipy)2(4,4'-bipy)(P2W18O62)2]·7H2O, in which Cu(II) coordinated to [P2W18O62]6- polyanions, 4,4'-bipydine and monoprotonated 4,4'-bipyridine ligands to form a 1D polyanionic chain. The 1D polyanionic chains stacked into a 3D supramolecular architecture consisting of numerous 1D open channels, in which water molecules are encapsulated. Additionally, thermal stability of the inorganic-organic hybrid materials has also been studied.

Keywords

Polymeric chain Polyoxometelate Crystal structure Thermal analyses
Lin, R.-L., Sun, W.-Q., Liu, J.-X., & Chu, X.-F. (2015). (4,4’-H2bipy)4[Cu(4,4’-Hbipy)2(4,4’-bipy)(P2W18O62)2]·7H2O: A New Supramolecular Hybrid Based on 1D Cu-N Coordination Polymeric Chain and Wells-Dawson Type Polyoxometelate. Asian Journal of Chemistry, 27(3), 1009–1012. https://doi.org/10.14233/ajchem.2015.18000
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