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This work is licensed under a Creative Commons Attribution 4.0 International License.
Carbonaceous Materials-Based Electric Double Layer Capacitors with Improved Electrochemical Performance
Corresponding Author(s) : Won-Chun Oh
Asian Journal of Chemistry,
Vol. 27 No. 3 (2015): Vol 27 Issue 3
Abstract
In this study, the fabrication of working electrodes was carried out as follows. Briefly, the electrodes were composed of graphene as an active material, Ketjen black and activated carbon fiber as an electric conductor and polytetrafluoroethylene [(C2F4)n, PTFE] as a binder. The prepared electrodes were characterized by X-ray diffraction and scanning electron microscopy. Finally, the electrochemical performances of carbon materials in the electrolyte solution of tetraethylammonium tetrafluoroborate [(C2H5)4NBF4, TEABF4] in propylene carbonate were examined. The graphene nanosheets electrode in the work exhibited a good rate of capability and reversibility at high scan rates in electrochemical performances.
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- A. Burke, J. Power Sources, 91, 37 (2000); doi:10.1016/S0378-7753(00)00485-7.
- M. Winter and R.J. Brodd, Chem. Rev., 104, 4245 (2004); doi:10.1021/cr020730k.
- B.E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Kluwer Academic/Plenum Publishers, New York, edn. 1 (1999).
- C. Ashtiani, R. Wright and G. Hunt, J. Power Sources, 154, 561 (2006); doi:10.1016/j.jpowsour.2005.10.082.
- M.D. Stoller, S. Park, Y. Zhu, J. An and R.S. Ruoff, Nano Lett., 8, 3498 (2008); doi:10.1021/nl802558y.
- A.K. Geim and K.S. Novoselov, Nat. Mater., 6, 183 (2007); doi:10.1038/nmat1849.
- J.C. Meyer, A.K. Geim, M.I. Katsnelson, K.S. Novoselov, T.J. Booth and S. Roth, Nature, 446, 60 (2007); doi:10.1038/nature05545.
- A.K. Geim and K.S. Novoselov, Nat. Mater., 6, 183 (2007); doi:10.1038/nmat1849.
- D.A. Areshkin, D. Gunlycke and C.T. White, Nano Lett., 7, 204 (2007); doi:10.1021/nl062132h.
- J. Schindall, IEEE Power Electron. Soc. Newslett., 20, 32 (2007).
- J. Schindall, The Charge of the Ultra-Capacitors, IEEE Spectrum. IEEE (2007); http://www.spectrum.ieee.org/nov07/5636.
- S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen and R.S. Ruoff, Carbon, 45, 1558 (2007); doi:10.1016/j.carbon.2007.02.034.
- W.C. Oh and F.J. Zhang, Asian J. Chem., 23, 875 (2011).
- K. Gotoh, T. Kinumoto, E. Fujii, A. Yamamoto, H. Hashimoto, T. Ohkubo, A. Itadani, Y. Kuroda and H. Ishida, Carbon, 49, 1118 (2011); doi:10.1016/j.carbon.2010.11.017.
- W.C. Oh, F.J. Zhang and M.L. Chen, J. Ind. Eng. Chem., 16, 321 (2010); doi:10.1016/j.jiec.2010.01.032.
- Y.G. Wang, H.Q. Li and Y.Y. Xia, Adv. Mater., 18, 2619 (2006); doi:10.1002/adma.200600445.
- B. Fang, Y.Z. Wei, K. Suzuki and M. Kumagai, Electrochim. Acta, 50, 3616 (2005); doi:10.1016/j.electacta.2004.12.032.
- X.H. Xia, L. Shi, H.B. Liu, L. Yang and Y.D. He, J. Phys. Chem. Solids, 73, 385 (2012); doi:10.1016/j.jpcs.2011.10.028.
- L. Li, H. Song and X. Chen, Electrochim. Acta, 51, 5715 (2006); doi:10.1016/j.electacta.2006.03.005.
- F. Li, J. Song, H. Yang, S. Gan, Q. Zhang, D. Han, A. Ivaska and L. Niu, Nanotechnology, 20, 455602 (2009); doi:10.1088/0957-4484/20/45/455602.
- H. Li, H. Xi, S. Zhu, Z. Wen and R. Wang, Microporous Mesoporous Mater., 96, 357 (2006); doi:10.1016/j.micromeso.2006.07.021.
- J.H. Han, K.W. Cho, K.H. Lee and H. Kim, Carbon, 36, 1801 (1998); doi:10.1016/S0008-6223(98)00150-X.
- A.C. Ferrari and J. Robertson, Phys. Rev. B, 61, 14095 (2000); doi:10.1103/PhysRevB.61.14095.
- L.G. Cancado, M.A. Pimenta, B.R.A. Neves, M.S.S. Dantas and A. Jorio, Phys. Rev. Lett., 93, 247401 (2004); doi:10.1103/PhysRevLett.93.247401.
- M.L. Chen, C.Y. Park, Z.D. Meng, L. Zhu, J.G. Choi, T. Ghosh, L.J. Kim, S. Yang, M.K. Bae, F.J. Zhang and W.C. Oh, Fullerenes, Nanotubes, Carbon Nanostruct., 21, 525 (2013); doi:10.1080/1536383X.2011.643420.
References
A. Burke, J. Power Sources, 91, 37 (2000); doi:10.1016/S0378-7753(00)00485-7.
M. Winter and R.J. Brodd, Chem. Rev., 104, 4245 (2004); doi:10.1021/cr020730k.
B.E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Kluwer Academic/Plenum Publishers, New York, edn. 1 (1999).
C. Ashtiani, R. Wright and G. Hunt, J. Power Sources, 154, 561 (2006); doi:10.1016/j.jpowsour.2005.10.082.
M.D. Stoller, S. Park, Y. Zhu, J. An and R.S. Ruoff, Nano Lett., 8, 3498 (2008); doi:10.1021/nl802558y.
A.K. Geim and K.S. Novoselov, Nat. Mater., 6, 183 (2007); doi:10.1038/nmat1849.
J.C. Meyer, A.K. Geim, M.I. Katsnelson, K.S. Novoselov, T.J. Booth and S. Roth, Nature, 446, 60 (2007); doi:10.1038/nature05545.
A.K. Geim and K.S. Novoselov, Nat. Mater., 6, 183 (2007); doi:10.1038/nmat1849.
D.A. Areshkin, D. Gunlycke and C.T. White, Nano Lett., 7, 204 (2007); doi:10.1021/nl062132h.
J. Schindall, IEEE Power Electron. Soc. Newslett., 20, 32 (2007).
J. Schindall, The Charge of the Ultra-Capacitors, IEEE Spectrum. IEEE (2007); http://www.spectrum.ieee.org/nov07/5636.
S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen and R.S. Ruoff, Carbon, 45, 1558 (2007); doi:10.1016/j.carbon.2007.02.034.
W.C. Oh and F.J. Zhang, Asian J. Chem., 23, 875 (2011).
K. Gotoh, T. Kinumoto, E. Fujii, A. Yamamoto, H. Hashimoto, T. Ohkubo, A. Itadani, Y. Kuroda and H. Ishida, Carbon, 49, 1118 (2011); doi:10.1016/j.carbon.2010.11.017.
W.C. Oh, F.J. Zhang and M.L. Chen, J. Ind. Eng. Chem., 16, 321 (2010); doi:10.1016/j.jiec.2010.01.032.
Y.G. Wang, H.Q. Li and Y.Y. Xia, Adv. Mater., 18, 2619 (2006); doi:10.1002/adma.200600445.
B. Fang, Y.Z. Wei, K. Suzuki and M. Kumagai, Electrochim. Acta, 50, 3616 (2005); doi:10.1016/j.electacta.2004.12.032.
X.H. Xia, L. Shi, H.B. Liu, L. Yang and Y.D. He, J. Phys. Chem. Solids, 73, 385 (2012); doi:10.1016/j.jpcs.2011.10.028.
L. Li, H. Song and X. Chen, Electrochim. Acta, 51, 5715 (2006); doi:10.1016/j.electacta.2006.03.005.
F. Li, J. Song, H. Yang, S. Gan, Q. Zhang, D. Han, A. Ivaska and L. Niu, Nanotechnology, 20, 455602 (2009); doi:10.1088/0957-4484/20/45/455602.
H. Li, H. Xi, S. Zhu, Z. Wen and R. Wang, Microporous Mesoporous Mater., 96, 357 (2006); doi:10.1016/j.micromeso.2006.07.021.
J.H. Han, K.W. Cho, K.H. Lee and H. Kim, Carbon, 36, 1801 (1998); doi:10.1016/S0008-6223(98)00150-X.
A.C. Ferrari and J. Robertson, Phys. Rev. B, 61, 14095 (2000); doi:10.1103/PhysRevB.61.14095.
L.G. Cancado, M.A. Pimenta, B.R.A. Neves, M.S.S. Dantas and A. Jorio, Phys. Rev. Lett., 93, 247401 (2004); doi:10.1103/PhysRevLett.93.247401.
M.L. Chen, C.Y. Park, Z.D. Meng, L. Zhu, J.G. Choi, T. Ghosh, L.J. Kim, S. Yang, M.K. Bae, F.J. Zhang and W.C. Oh, Fullerenes, Nanotubes, Carbon Nanostruct., 21, 525 (2013); doi:10.1080/1536383X.2011.643420.