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Electrical and Optical Properties of Synthesized Composite Material Polyaniline-Ti(IV) Arsenophosphate
Corresponding Author(s) : Rani Bushra
Asian Journal of Chemistry,
Vol. 27 No. 3 (2015): Vol 27 Issue 3
Abstract
Nanocomposite material polyaniline-Ti(IV) arsenophosphate with varying concentration of inorganic precipitate [Ti(IV) arsenophosphate] have been synthesized by employing the sol gel method. Prepared samples were characterized by scanning electron microscopy and transmission electron microscopy. Optical absorption spectra was recorded by using UV-visible absorption spectral techniques. From the analysis of absorption spectra, observed band gap for the different samples was found to be in the range of 3.12 to 3.60 eV. Electrical conducting studies show that conductivity of nanocomposites increases with increase in temperature, which is the observed behaviour of semiconductor materials.
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References
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A. Dey, A. De and S.K. De, J. Phys.-Condens. Mat., 17, 5895 (2005); doi:10.1088/0953-8984/17/37/025.
T.K. Vishnuvardhan, V.R. Kulkarni, C. Basavaraja and S.C. Raghavendra, Bull. Mater. Sci., 29, 77 (2006); doi:10.1007/BF02709360.
S.D. Patil, S.C. Raghavendra, M. Revansiddappa, P. Narsimha and M.V.N. Ambika Prasad, Bull. Mater. Sci., 30, 89 (2007); doi:10.1007/s12034-007-0015-8.
C. Li and G. Shi, Electrochim. Acta, 56, 10737 (2011); doi:10.1016/j.electacta.2010.12.081.
Y. Chen, C. Xu, L. Cao and Y. Wang, Polym. Compos., 33, 1206 (2012); doi:10.1002/pc.22250.
G. Gustafsson, Y. Cao, G.M. Treacy, F. Klavetter, N. Colaneri and A.J. Heeger, Nature, 357, 477 (1992); doi:10.1038/357477a0.
D.Y. Godovsky, Adv. Polym. Sci., 153, 163 (2000); doi:10.1007/3-540-46414-X_4.
X.G. Li, A. Li and M.R. Huang, Chem. Eur. J., 14, 10309 (2008); doi:10.1002/chem.200801025.
A.V. Murugan, T. Muraliganth and A. Manthiram, Chem. Mater., 21, 5004 (2009); doi:10.1021/cm902413c.
O.M. Vatutsina, V.S. Soldatov, V.I. Sokolova, J. Johann, M. Bissen and A. Weissenbacher, Funct. Polym., 67, 184 (2007); doi:10.1016/j.reactfunctpolym.2006.10.009.
S.A. Nabi, M. Shahadat, R. Bushra, A.H. Shalla and F. Ahmed, Chem. Eng. J., 165, 405 (2010); doi:10.1016/j.cej.2010.08.068.
R. Bushra, M. Shahadat, A.S. Raeisssi and S.A. Nabi, Desalination, 289, 1 (2012); doi:10.1016/j.desal.2011.12.013.
O. Arrad and Y. Sasson, J. Org. Chem., 54, 4993 (1989); doi:10.1021/jo00282a008.
A.A. Khan and Inamuddin, Sens. Actuators B, 120, 10 (2006); doi:10.1016/j.snb.2006.01.033.
N.K. Raman, M.T. Anderson and C.J. Brinker, Chem. Mater., 8, 1682 (1996); doi:10.1021/cm960138+.
J.M. Kinyanjui, D.W. Hatchett, J.A. Smith and M. Josowicz, Chem. Mater., 16, 3390 (2004); doi:10.1021/cm049478i.
T.K. Sarma and A. Chattopadhyay, Langmuir, 20, 4733 (2004); doi:10.1021/la0495884.
Y.-C. Liu and T.C. Chuang, J. Phys. Chem. B, 107, 12383 (2003); doi:10.1021/jp035680h.
R.V. Kumar, Y. Mastai, Y. Diamant and A. Gedanken, J. Mater. Chem., 11, 1209 (2001); doi:10.1039/b005769j.
S. Sharma, C. Nirkhe, S. Pethkar and A.A. Athawale, Sens. Actuators B, 85, 131 (2002); doi:10.1016/S0925-4005(02)00064-3.
S. Yoda, A. Hasegawa, H. Suda, Y. Uchimaru, K. Haraya, T. Tsuji and K. Otake, Chem. Mater., 16, 2363 (2004); doi:10.1021/cm0349250.
S.W. Huang, K.G. Neoh, E.T. Kang, H.S. Han and K.L. Tan, J. Mater. Chem., 8, 1743 (1998); doi:10.1039/a802245c.
M. Hasik, E. Wenda, C. Paluszkiewicz, A. Bernasik and J. Camra, Synth. Met., 143, 341 (2004); doi:10.1016/j.synthmet.2003.12.020.
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S.A. Nabi, R. Bushra and M. Shahadat, J. Appl. Polym. Sci., 125, 3439 (2011).
S.-J. Su and N. Kuramoto, Synth. Met., 114, 147 (2000); doi:10.1016/S0379-6779(00)00238-1.
J.C. Xu, W.M. Liu and H.L. Li, Mater. Sci. Eng. C, 25, 444 (2005); doi:10.1016/j.msec.2004.11.003.
S. Gupta, D. Choudhary and A. Sarma, J. Polym. Sci., B, Polym. Phys., 38, 1589 (2000); doi:10.1002/(SICI)1099-0488(20000615)38:12<1589::AID-POLB30>3.0.CO;2-K.
P.D. Christy, N.S.N. Jothi, N. Melikechi and P. Sagayaraj, Cryst. Res. Technol., 44, 484 (2009); doi:10.1002/crat.200900001.
Y. Zhao, C.Z. Li, X.H. Liu, F. Gu, H.B. Jiang, W. Shao, L. Zhang and Y. He, Mater. Lett., 61, 79 (2007); doi:10.1016/j.matlet.2006.04.010.
J. Tauc, in ed: A. Ables, Optical Properties of Solids, North-Holland, Amsterdam (1970).
A.S. Ahmed, M. Shafeeq M., M.L. Singla, S. Tabassum, A.H. Naqvi and A. Azam, J. Lumin., 131, 1 (2011); doi:10.1016/j.jlumin.2010.07.017.
J.I. Pankov Optical Process in Semiconductors, Prentice Hall, Englewood Clips, New Jersey (1971).